Transfer and Amplification of Chirality Within the “Ring of Fire” Observed in Resonance Raman Optical Activity Experiments

摘要

Abstract >We report extremely strong chirality transfer from a chiral nickel complex to solvent molecules detected as Raman optical activity (ROA). Electronic energies of the complex were in resonance with the excitation‐laser light. The phenomenon was observed for a wide range of achiral and chiral solvents. For chiral 2‐butanol, the induced ROA was even stronger than the natural one. The observations were related to so‐called quantum (molecular) plasmons that enable a strong chiral Rayleigh scattering of the resonating complex. According to a model presented here, the maximal induced ROA intensity occurs at a certain distance from the solute, in a three‐dimensional “ring of fire”, even after rotational averaging. Most experimental ROA signs and relative intensities could be reproduced. The effect might significantly increase the potential of ROA spectroscopy in bioimaging and sensitive detection of chiral molecules. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> >我们报告从手性镍复合物转移到被检测为拉曼光学活性（ROA）的溶剂分子中的极强的手性转移。复合物的电子能量与激光激光亮起的共振。观察到该现象是广泛的成立和手性溶剂。对于手性2-丁醇，诱导的ROA甚至比自然均更强大。观察结果与所谓的量子（分子）等离子体有关，其能够对共振复合物的强手性瑞利散射。根据这里呈现的模型，即使在旋转平均在旋转平均之后，在旋转的三维“火环”中，最大诱导的ROA强度发生在一定距离。可以再现大多数实验ROA标志和相对强度。该效果可能显着增加了对手性分子的生物分析和敏感检测中ROA光谱的潜力。</ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-19011/'>《Angewandte Chemie》</a> <b style="margin: 0 2px;">|</b><span>2019年第46期</span><b style="margin: 0 2px;">|</b><span>共4页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1188.html" title="应用化学">应用化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=chirality transfer&option=203" rel="nofollow">chirality transfer;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=light scattering&option=203" rel="nofollow">light scattering;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=nickel complexes&option=203" rel="nofollow">nickel complexes;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=quantum plasmons&option=203" rel="nofollow">quantum plasmons;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=resonance Raman optical activity&option=203" rel="nofollow">resonance Raman optical activity;</a> </p> <div class="translation"> 机译：手性转移;光散射;镍复合物;量子等级;共振拉曼光学活动; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704028165175.html">Transfer and Amplification of Chirality Within the “Ring of Fire” Observed in Resonance Raman Optical Activity Experiments</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> </a> <a href="/journal-foreign-19011/" target="_blank" rel="nofollow" class="tuijian_authcolor">Angewandte Chemie .</a> <span>2019</span><span>,第46期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：在共振拉曼光学活性实验中观察到“火环”中的手性的转移和放大</span> </p> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704019166259.html">Resonance Raman Optical Activity and Surface Enhanced Resonance Raman Optical Activity Analysis of Cytochrome c</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Christian Johannessen&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Christian Johannessen,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Peter C.White&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Peter C.White,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Salim Abdali&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Salim Abdali </a> <a href="/journal-foreign-30975/" target="_blank" rel="nofollow" class="tuijian_authcolor">The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory .</a> <span>2007</span><span>,第32期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：细胞色素c的共振拉曼光学活性和表面增强共振拉曼光学活性分析</span> </p> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704019180700.html">Resonance Raman Optical Activity of Single Walled Chiral Carbon Nanotubes</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Nagy Peter R.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Nagy Peter R.,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Koltai Janos&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Koltai Janos,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Surjan Peter R.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Surjan Peter R.,</a> <a href="/journal-foreign-30975/" target="_blank" rel="nofollow" class="tuijian_authcolor">The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory .</a> <span>2016</span><span>,第28期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：单壁手性碳纳米管的共振拉曼光学活性</span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-conference-foreign_meeting-247186_thesis/0705010564710.html">Observation Of Resonance Electronic And Non- Resonance Enhanced Vibrational Natural Raman Optical Activity</a> <b>[C]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Christian Merten&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Christian Merten,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Honggang Li&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Honggang Li,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Xuefang Lu&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Xuefang Lu,</a> <a href="/conference-foreign-247186/" target="_blank" rel="nofollow" class="tuijian_authcolor">International Conference on Raman Spectroscopy .</a> <span>2010</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：观察谐振电子和非共振增强振动自然拉曼光学活性</span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-degree-foreign_mphd_thesis/02061201730.html">Development of "core-suction" technique for fabrication of highly doped fibers for optical amplification and characterization of optical fibers for Raman amplification.</a> <b>[D] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Goel, Nitin Kumar.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Goel, Nitin Kumar. </a> <span>2005</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：开发“芯吸”技术以制造用于光放大的高掺杂光纤以及表征用于拉曼放大的光纤。</span> </p> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-journal-foreign-pmc_detail_thesis/040007070967.html">On Raman optical activity sign-switching between the ground and excited states leading to an unusual resonance ROA induced chirality</a> <b>[O] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ewa Machalska&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Ewa Machalska,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Grzegorz Zajac&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Grzegorz Zajac,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Malgorzata Baranska&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Malgorzata Baranska,</a> <span>2021</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：关于拉曼光学活性签署地面和兴奋状态导致不寻常的共振ROA引起的手性</span> </p> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/open-access_resources_thesis/0100091648733.html">Resonance Raman Optical Activity and Surface Enhanced Resonance Raman Optical Activity analysis of Cytochrome C</a> <b>[O] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Johannessen Christian&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Johannessen Christian,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Abdali Salim&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Abdali Salim,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=White Peter C.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">White Peter C. </a> <span>2007</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：细胞色素C的共振拉曼光学活性和表面增强共振拉曼光学活性分析</span> </p> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/academic-journal-cn_spectroscopy-spectral-analysis_thesis/0201232996078.html">邻苯二甲酰肼的表面增强拉曼光谱：观察到正常拉曼光谱中禁阻的...</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=戚积纬&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 戚积纬</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=吴国祯&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,吴国祯</a> <span> <a href="/journal-cn-11127/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 光谱学与光谱分析 </a> </span> <span> . 1989</span><span>,第003期</span> </span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/academic-journal-cn_journal-graduate-school-chinese-academy-sciences_thesis/0201233970365.html">对《手性环酯的螺旋结构和光学活性之间关系的研究》一文的评论</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=尹玉英&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 尹玉英</a> <span> <a href="/journal-cn-3816/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 中国科学院研究生院学报 </a> </span> <span> . 1999</span><span>,第002期</span> </span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/academic-journal-cn_rock-mineral-analysis_thesis/0201216516910.html">手性污染物六溴环十二烷在食物链传递中的选择性及生物放大作用研究进展</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=田芹&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 田芹</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=佟玲&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,佟玲</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=宋淑玲&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,宋淑玲</a> <span> <a href="/journal-cn-7819/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 岩矿测试 </a> </span> <span> . 2016</span><span>,第006期</span> </span> </div> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-journal-cn_chinese-journal-synthetic-chemistry_thesis/0201234497092.html">二类手性铜催化剂的合成及其在光学活性菊酸合成中的应用研究</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=徐明华&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 徐明华</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=陈良&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,陈良</a> <span> <a href="/journal-cn-11569/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 合成化学 </a> </span> <span> . 1998</span><span>,第003期</span> </span> </div> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-journal-cn_university-chemistry_thesis/0201229529803.html">不对称合成中手性杂环配体的结构与催化活性</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=孟庆林&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 孟庆林</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=何琰&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,何琰</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=关烨第&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,关烨第</a> <span> <a href="/journal-cn-10553/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 大学化学 </a> </span> <span> . 2000</span><span>,第001期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-29080_thesis/020222132948.html">采用光纤环消偏器的宽带拉曼放大器实验研究</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李巨浩&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 李巨浩</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=朱晓宇&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,朱晓宇</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=郑磊&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,郑磊</a> <span> <a href="/conference-cn-29080/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 全国第十一次光纤通信暨十二届集成光学学术会议(OFCIO'2003) </a> <span> <span> . 2003</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020314639578.html">表面增强拉曼活性基底的光学表征和四环素类药物的表面增强拉曼光谱研究</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=焦玉芬&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 焦玉芬</a> <span> . 2007</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06120106816754.html">取代基中α-碳上带活性官能团的手性五元环亚硫酸酯的制备方法</a> <b>[P]</b> . <span> 中国专利： CN102603705A </span> <span> . 2012-07-25</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120111859322.html">一种手性配体及其在催化制备光学活性二级醇中的应用</a> <b>[P]</b> . <span> 中国专利： CN111807998A </span> <span> . 2020-10-23</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130434146780.html">Raman amplification of optical signals used in wavelength division multiplexing (WDM) transmission system involves rectifying distorted amplification profile of Raman amplification to compensate distortion in Raman-amplified optical signals</a> <b>[P]</b> . <span> 外国专利：  DE102005028357A1 </span> <span> . 2006-12-21</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：在波分复用（WDM）传输系统中使用的光信号的拉曼放大涉及校正拉曼放大的失真放大曲线，以补偿拉曼放大的光信号中的失真 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130423775673.html">Design method as well as the Raman amplification optical fiber and Raman amplifier of Raman amplification optical fiber</a> <b>[P]</b> . <span> 外国专利：  JP4913706B2 </span> <span> . 2012-04-11</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：拉曼放大光纤的设计方法以及拉曼放大光纤和拉曼放大器 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130431247589.html">METHOD OF DESIGNING RAMAN AMPLIFYING OPTICAL FIBER, RAMAN AMPLIFYING OPTICAL FIBER AND RAMAN AMPLIFIER</a> <b>[P]</b> . <span> 外国专利：  JP2009116010A </span> <span> . 2009-05-28</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：设计拉曼光纤，拉曼光纤和拉曼的方法 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" onclick="ywcd('0704028165175','4',7,2,1,'',this,24)" class="delivery" prompt="010401" title="通过人工服务将文献原文发送至邮箱" >获取原文</div> <div class="journalsub-pop-up" style="display: none"> <div class="journal-sub"> <h2>期刊订阅</h2> <img src="https://cdn.zhangqiaokeyan.com/img/loginclose.png" alt="关闭" onclick="$('.journalsub-pop-up').hide()"> <p class="pardon">抱歉，该期刊暂不可订阅，敬请期待！</p> <p class="current">目前支持订阅全部北京大学中文核心（2020）期刊目录。</p> <div style="display: flex;margin-top: 69px;justify-content: space-between;"> <div class="no-sub" onclick="$('.journalsub-pop-up').hide()">暂不订阅</div> <div class="other-sub" onclick="continueSub('from=pc-detail')">继续订阅其他期刊</div> </div> </div> </div> <div class="right_btn"> <ul> <li class="gouwuche">  </li> <li class="yijian"> <a href="javascript:void(0);" onclick="link_analysis('/mycenter/auth/complaint.html',this)" title="意见反馈">意见反馈</a> </li> <li class="top"> <a href="javascript:scrollTo(0,0);" title="回到顶部">回到顶部</a> </li> <li class="shouye"> <a href="/" title="首页">回到首页</a> </li> </ul> </div> <div class="xllindexfooter"> <div class="xllindexfootercenter"> <div class="xllindexfooterleft left" > <div class="xllindexfooterleftli"> <ul> <li><a href="/about.html" title="关于掌桥">关于掌桥</a></li> <li><a href="/help/helpmap.html" title="资源导航">资源导航</a></li> <li><a href="/help/helpguide.html" title="新手指南">新手指南</a></li> <li><a href="/help/helpcenter.html" title="常见问题">常见问题</a></li> <li><a href="/sitemap.html" title="网站地图">网站地图</a></li> <li><a href="/help/helpcenter.html?type=9" title="版权声明">版权声明</a></li> </ul> </div> <div class="xllindexfooterleft"> <p class="xllindexfooterlefteamil">客服邮箱：kefu@zhangqiaokeyan.com</p> <div class="xllindexfooterlefttcp"> <div class="xllindexfooterpoliceiimg"></div> <div class="xllindexfooterpoliceispan"> <span>京公网安备：11010802029741号 </span> <span>ICP备案号：<a href="https://beian.miit.gov.cn" rel="nofollow" target="_blank" title="ICP备案号">京ICP备15016152号-6</a></span> <span>六维联合信息科技 (北京) 有限公司©版权所有</span> </div> </div> </div> </div> <div class="xllindexfooterright left"> <ul> <li> <p style="font-weight: bold;">客服微信</p> <div></div> </li> <li> <p style="font-weight: bold;">服务号</p> <div></div> </li> </ul> </div> </div> </div> <span id="0704028165175down" data-source="7," data-out-id="0uMuuucdBpf4ZMZBKqR4gng35SiktdS7ckQv9iepT5/aPTiY+4adWWbFlq7pBjab," data-f-source-id="7" data-title="Transfer and Amplification of Chirality Within the “Ring of Fire” Observed in Resonance Raman Optical Activity Experiments" data-price="20" data-site-name="" data-transnum="24" style="display:none;"></span> <input type="hidden" value="4" id="sourcetype"> <input type="hidden" value="19011" id="journalid"> <input type="hidden" value="1" id="inyn_provide_service_level"> <input type="hidden" value="https://cdn.zhangqiaokeyan.com" id="imgcdn"> <input type="hidden" value="1" id="isdeatail"> <input type="hidden" value="" id="syyn_indexed_database"> <input type="hidden" value="" id="servicetype"> <input type="hidden" id="pagename" value="Transfer and Amplification of Chirality Within the “Ring of Fire” Observed in Resonance Raman Optical Activity Experiments"/> <input type="hidden" value="thesis_get_original" id="pageIdentification"> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/jquery-1.12.4.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/lwlh_ajax.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/zq.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/common.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/jquery.cookie.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/top.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/tip.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/login.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/down.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/search.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/newmail.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/searchtype.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/user/regist.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/zxs_solor/detail.js?v=5.7.8"></script> <script type="text/javascript" src="https://www.zhangqiaokeyan.com/statistics/static/pagecollection.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/tj.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/sse.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/pushbaidu.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/history.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/util/cookie.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/weipu/weipu.js?v=5.7.8"></script> </body> <script> $(function(){ var weiPuStatus = getCookie('WeiPuStatus'); if(weiPuStatus){ tipWeiPuStatus(weiPuStatus); delCookie('WeiPuStatus'); } getFacetKeywordVoInId(); var sourcetype = $("#sourcetype").val(); var inyn_provide_service_level = $("#inyn_provide_service_level").val(); if((sourcetype ==1||sourcetype==4)&&inyn_provide_service_level!=4){ getJournal(); } }) </script> </html>