An Illumination‐Assisted Flexible Self‐Powered Energy System Based on a Li–O2 Battery

摘要

Abstract > The flexible Li‐O <sub>2</sub> battery is suitable to satisfy the requirements of a self‐powered energy system, thanks to environmental friendliness, low cost, and high theoretical energy density. Herein, a flexible porous bifunctional electrode with both electrocatalytic and photocatalytic activity was synthesized and introduced as a cathode to assemble a high‐performance Li‐O <sub>2</sub> battery that achieved an overpotential of 0.19?V by charging with the aid of solar energy. As a proof‐of‐concept application, a flexible Li‐O <sub>2</sub> battery was constructed and integrated with a solar cell via a scalable encapsulate method to fabricate a flexible self‐powered energy system with excellent flexibility and mechanical stability. Moreover, by exploring the evolution of the electrode morphology and discharge products (Li <sub>2</sub> O <sub>2</sub> ), the charging process of the Li‐O <sub>2</sub> battery powered by solar energy and solar cell was demonstrated. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 灵活的li-o <sub> 2 </ sub> 由于环境友好，低成本和高理论能量密度，电池适用于满足自动能源系统的要求。这里，合成具有电催化和光催化活性的柔性多孔双官能电极，并作为阴极引入，以组装高性能LI-O. <sub> 2 </ sub> 通过借助太阳能充电实现了0.19Ωv的电池。作为概念验证应用，一个灵活的LI-O. <sub> 2 </ sub> 通过可伸缩的封装方法构造并与太阳能电池构造并整体，以制造具有优异的柔韧性和机械稳定性的柔性自动能量系统。此外，通过探索电极形态和放电产品的演变（李 <sub> 2 </ sub> O. <sub> 2 </ sub> ），LI-O的充电过程 <sub> 2 </ sub> 通过太阳能和太阳能电池供电的电池。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-19011/'>《Angewandte Chemie》</a> <b style="margin: 0 2px;">|</b><span>2019年第46期</span><b style="margin: 0 2px;">|</b><span>共5页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1188.html" title="应用化学">应用化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=bifunctional electrodes&option=203" rel="nofollow">bifunctional electrodes;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=flexible batteries&option=203" rel="nofollow">flexible batteries;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Li-O2 batteries&option=203" rel="nofollow">Li-O2 batteries;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=solar energy conversion&option=203" rel="nofollow">solar energy conversion;</a> </p> <div class="translation"> 机译：双功能电极;柔性电池;LI-O2电池;太阳能转换; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704028164444.html">An Illumination‐Assisted Flexible Self‐Powered Energy System Based on a Li–O2 Battery</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> </a> <a href="/journal-foreign-19011/" target="_blank" rel="nofollow" class="tuijian_authcolor">Angewandte Chemie .</a> <span>2019</span><span>,第46期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: 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WANG Xiao-Chen</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王晓晨&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,王晓晨</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王英明&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,王英明</a> <span> <a href="/conference-cn-1823/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 《物理化学学报》创刊三十周年纪念大会暨第四届编委会会议 </a> <span> <span> . 2015</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020312135404.html">钛纳米线阵列和多孔钛的制备及其在Li-O2电池中的性能研究</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=牛艳宁&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 牛艳宁</a> <span> . 2015</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06120101345401.html">一种基于辅助能源系统的氢能汽车燃料电池能量管理系统</a> <b>[P]</b> . <span> 中国专利： CN110576755A </span> <span> . 2019-12-17</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/061204738128.html">柔性电池及其制备方法和包含柔性电池的辅助电池</a> <b>[P]</b> . <span> 中国专利： CN108922992B </span> <span> . 2021.10.26</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130426689963.html">Flag supporting device, has solar heat receivers coupled to electrical energy storage battery and to ambient illumination sensor, and LEDs supplied with power by storage battery, where power is less than ambient illumination threshold</a> <b>[P]</b> . <span> 外国专利：  FR2931286A1 </span> <span> . 2009-11-20</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：旗帜支持装置，具有耦合到电能存储电池和环境照明传感器的太阳热能接收器，以及功率小于环境照明阈值的由蓄电池供电的LED </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130438003126.html">System and method for converting ambient light energy into a digitized electrical output signal for controlling display and keypad illumination on a battery powered system</a> <b>[P]</b> . <span> 外国专利：  US7109465B2 </span> <span> . 2006-09-19</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：用于将环境光能转换为数字化电输出信号以控制电池供电系统上的显示和键盘照明的系统和方法 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130403531800.html">2kw to 20kw Hybrid Power Systems for Recreational and Special Vehicles. This innovation relates to electrical power systems in recreational and special vehicles that don't use electrical power exclusively for locomotion. It introduces in-vehicle power generation greater than 2kw used in conjunction with renewable power sources to charge Lithium Batteries on an independent subsidiary electrical system at 48VDC with conversion to 12VDC network of appliances and energy consumers on an independent network with a battery and with conversion to 110-240V A/C network of appliances and energy consumers</a> <b>[P]</b> . <span> 外国专利：  AU2019100177A4 </span> <span> . 2019-03-28</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：用于娱乐和特种车辆的2kw至20kw混合动力系统。这项创新涉及休闲和特种车辆中的电力系统，这些系统不仅仅将电力用于运动。它引入了大于2kw的车载发电，并与可再生能源结合使用，以48VDC的独立辅助电气系统上的锂电池充电，并转换为具有电池的独立网络上的家用电器和能源消耗者的12VDC网络，并转换为110-240V电器和能源消耗器的A / C网络 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> 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