Hard‐Sphere Random Close‐Packed Au47Cd2(TBBT)31 Nanoclusters with a Faradaic Efficiency of Up to 96?% for Electrocatalytic CO2 Reduction to CO

Zhuang Shengli; Chen Dong; Liao Lingwen; Zhao Yan; Xia Nan; Zhang Wenhao; Wang Chengming; Yang Jun; Wu Zhikun

摘要

Abstract > Metal nanoclusters have recently attracted considerable attention, not only because of their special size range but also because of their well‐defined compositions and structures. However, subtly tailoring the compositions and structures of metal nanoclusters for potential applications remains challenging. Now, a two‐phase anti‐galvanic reduction (AGR) method is presented for precisely tailoring Au <sub>44</sub> (TBBT) <sub>28</sub> to produce Au <sub>47</sub> Cd <sub>2</sub> (TBBT) <sub>31</sub> nanoclusters with a hard‐sphere random close‐packed structure, exhibiting Faradaic efficiencies of up to 96?% at ?0.57?V for the electrocatalytic reduction of CO <sub>2</sub> to CO. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 金属纳米团最近引起了相当大的关注，而不仅仅是因为它们的特殊尺寸范围，而且因其定义明确的组合物和结构。然而，微小地定制金属纳米能器的组合物和结构，用于潜在应用仍然具有挑战性。现在，提出了一种两相抗电抗（AGR）方法，以精确定制AU <sub> 44 </ sub> （TBBT） <sub> 28 </ sub> 生产au. <sub> 47 </ sub> 光盘 <sub> 2 </ sub> （TBBT） <sub> 31 </ sub> 纳米团簇具有硬球随机近填充结构，在电催化还原CO的电催化还原时，射击效率高达96Ω％ <sub> 2 </ sub> 合作。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-19011/'>《Angewandte Chemie》</a> <b style="margin: 0 2px;">|</b><span>2020年第8期</span><b style="margin: 0 2px;">|</b><span>共5页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhuang Shengli&option=202" target="_blank" rel="nofollow">Zhuang Shengli;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Chen Dong&option=202" target="_blank" rel="nofollow">Chen Dong;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Liao Lingwen&option=202" target="_blank" rel="nofollow">Liao Lingwen;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhao Yan&option=202" target="_blank" rel="nofollow">Zhao Yan;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Xia Nan&option=202" target="_blank" rel="nofollow">Xia Nan;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhang Wenhao&option=202" target="_blank" rel="nofollow">Zhang Wenhao;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wang Chengming&option=202" target="_blank" rel="nofollow">Wang Chengming;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yang Jun&option=202" target="_blank" rel="nofollow">Yang Jun;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wu Zhikun&option=202" target="_blank" rel="nofollow">Wu Zhikun;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Key Laboratory of Materials PhysicsChinese Academy of SciencesHefei 230031 P. R. China;</p> <p>State Key Laboratory of Multiphase Complex SystemsChinese Academy of SciencesBeijing 100190 P. R. China;</p> <p>Key Laboratory of Materials PhysicsChinese Academy of SciencesHefei 230031 P. R. China;</p> <p>Key Laboratory of Materials PhysicsChinese Academy of SciencesHefei 230031 P. R. China;</p> <p>Key Laboratory of Materials PhysicsChinese Academy of SciencesHefei 230031 P. R. China;</p> <p>Key Laboratory of Materials PhysicsChinese Academy of SciencesHefei 230031 P. R. China;</p> <p>Hefei National Laboratory for Physical Sciences at the MicroscaleUniversity of Science and Technology of ChinaHefei Anhui 230026 P. R. China;</p> <p>State Key Laboratory of Multiphase Complex SystemsChinese Academy of SciencesBeijing 100190 P. R. China;</p> <p>Key Laboratory of Materials PhysicsChinese Academy of SciencesHefei 230031 P. R. China;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1188.html" title="应用化学">应用化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=cadmium&option=203" rel="nofollow">cadmium;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=CO2 reduction&option=203" rel="nofollow">CO2 reduction;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=electrocatalysis&option=203" rel="nofollow">electrocatalysis;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=gold nanoclusters&option=203" rel="nofollow">gold nanoclusters;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=two-phase anti-galvanic reduction&option=203" rel="nofollow">two-phase anti-galvanic reduction;</a> </p> <div class="translation"> 机译：镉;减少二氧化碳;电催化;金纳米能器;两相抗电抗; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704028162829.html">Hard‐Sphere Random Close‐Packed Au47Cd2(TBBT)31 Nanoclusters with a Faradaic Efficiency of Up to 96?% for Electrocatalytic CO2 Reduction to CO</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhuang Shengli&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Zhuang Shengli,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Chen Dong&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Chen Dong,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Liao Lingwen&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Liao Lingwen,</a> <a href="/journal-foreign-19011/" target="_blank" rel="nofollow" class="tuijian_authcolor">Angewandte Chemie .</a> <span>2020</span><span>,第8期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：硬球随机近填充AU47CD2（TBBT）31个纳米能器，具有额外效率高达96Ω％的电催化二氧化碳减少到CO</span> </p> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704014780743.html">Highly oriented MOF thin film-based electrocatalytic device for the reduction of CO2 to CO exhibiting high faradaic efficiency</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ye Lu&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Ye Lu,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Liu Jinxuan&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Liu Jinxuan,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Gao Yan&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Gao Yan,</a> <a href="/journal-foreign-35176/" target="_blank" rel="nofollow" class="tuijian_authcolor">Journal of Materials Chemistry, A. 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