Synthesis of a Hemispherical Geodesic Phenine Framework by a Polygon Assembling Strategy

Mio Tatsuru; Ikemoto Koki; Sato Sota; Isobe Hiroyuki

摘要

Abstract > A synthetic strategy to construct large geodesic structures of phenine (1,3,5‐trisubstituted benzene) was devised. In this strategy, five pentagons were assembled on an omphalos pentagon, and bridging peripheral pentagons furnished five additional hexagons. Thirty phenine units were synthetically assembled to afford a large C <sub>220</sub> H <sub>180</sub> molecule with a phenine framework isoreticular to a hemispherical, bisected segment of C <sub>60</sub> . Although a hemispherical structure of the phenine framework was suggested by solution‐phase NMR spectra, crystallographic analysis revealed an oval‐like deformation of the molecular shape. In‐depth structural analyses, including theoretical calculations, showed that structural fluctuations observed as variations in the biaryl torsion angles allowed structural deformations and, at the same time, that the dynamic fluctuations resulted in the spectroscopic observation of a hemisphere as a time‐averaged structure. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 制定了构建诸如苯胺（1,3,5-三取代苯）的大型测地结构的合成策略。在这一策略中，五个五角星在奥普洛斯五角大楼上组装，桥梁外围五角星提供了五个额外的六边形。合成组装了30个素食单位以提供大C <sub> 220 </ sub> H <sub> 180 </ sub> 分子用脂肪框架定理到半球形，二分割的c <sub> 60 </ sub> 。尽管通过溶液 - 相NMR光谱提出了加入素框架的半球形结构，但结晶分析显示了分子形状的椭圆形变形。在内的深度结构分析，包括理论计算，表明，观察到的结构波动作为静脉扭转角度的变化允许结构变形，并且同时，动态波动导致半球的光谱观察为时间平均结构。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-19011/'>《Angewandte Chemie》</a> <b style="margin: 0 2px;">|</b><span>2020年第16期</span><b style="margin: 0 2px;">|</b><span>共5页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Mio Tatsuru&option=202" target="_blank" rel="nofollow">Mio Tatsuru;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ikemoto Koki&option=202" target="_blank" rel="nofollow">Ikemoto Koki;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Sato Sota&option=202" target="_blank" rel="nofollow">Sato Sota;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Isobe Hiroyuki&option=202" target="_blank" rel="nofollow">Isobe Hiroyuki;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Department of ChemistryThe University of TokyoHongo Bunkyo-ku Tokyo 113-0033 Japan;</p> <p>Department of ChemistryThe University of TokyoHongo Bunkyo-ku Tokyo 113-0033 Japan;</p> <p>Department of ChemistryThe University of TokyoHongo Bunkyo-ku Tokyo 113-0033 Japan;</p> <p>Department of ChemistryThe University of TokyoHongo Bunkyo-ku Tokyo 113-0033 Japan;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1188.html" title="应用化学">应用化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=conformation analysis&option=203" rel="nofollow">conformation analysis;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=geodesic frameworks&option=203" rel="nofollow">geodesic frameworks;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=hemispheres&option=203" rel="nofollow">hemispheres;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=macrocycles&option=203" rel="nofollow">macrocycles;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=polygons&option=203" rel="nofollow">polygons;</a> </p> <div class="translation"> 机译：构象分析;测地框架;半球形;宏观文字;多边形; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704028162755.html">Synthesis of a Hemispherical Geodesic Phenine Framework by a Polygon Assembling Strategy</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Mio Tatsuru&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Mio Tatsuru,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ikemoto Koki&option=202" target="_blank" rel="nofollow" class="tuijian_auth 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