Enabling a Durable Electrochemical Interface via an Artificial Amorphous Cathode Electrolyte Interphase for Hybrid Solid/Liquid Lithium‐Metal Batteries

Liang Jia‐Yan; Zhang Xu‐Dong; Zeng Xian‐Xiang; Yan Min; Yin Ya‐Xia; Xin Sen; Wang Wen‐Peng; Wu Xiong‐Wei; Shi Ji‐Lei; Wan Li‐Jun; Guo Yu‐Guo

摘要

Abstract >A hybrid solid/liquid electrolyte with superior security facilitates the implementation of high‐energy‐density storage devices, but it suffers from inferior chemical compatibility with cathodes. Herein, an optimal lithium difluoro(oxalato)borate salt was introduced to build in?situ an amorphous cathode electrolyte interphase (CEI) between Ni‐rich cathodes and hybrid electrolyte. The CEI preserves the surface structure with high compatibility, leading to enhanced interfacial stability. Meanwhile, the space‐charge layer can be prominently mitigated at the solid/solid interface via harmonized chemical potentials, acquiring promoted interfacial dynamics as revealed by COMSOL simulation. Consequently, the amorphous CEI integrates the bifunctionality to provide an excellent cycling stability, high Coulombic efficiency, and favorable rate capability in high‐voltage Li‐metal batteries, innovating the design philosophy of functional CEI strategy for future high‐energy‐density batteries. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> >具有优异安全性的杂化固体/液体电解质有助于实现高能密度存储装置，但它遭受与阴极差的化学兼容性。这里，引入了最佳锂二氟（奥沙粉酸盐）硼酸盐盐，以构建在富含Ni的阴极和杂合电解质之间的非晶阴极电解质间（CEI）。 CEI保留具有高相容性的表面结构，导致界面稳定性增强。同时，可以通过协调的化学电位在固体/固体界面下突出地减轻空间电荷层，获得COMSOL模拟所揭示的促进的界面动态。因此，无定形CEI集成了双功能性，在高压Li-Metal电池中提供了优异的循环稳定性，高库仑效率和有利的速率能力，为未来的高能密度电池进行了功能性CEI战略的设计理念。< / p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-19011/'>《Angewandte Chemie》</a> <b style="margin: 0 2px;">|</b><span>2020年第16期</span><b style="margin: 0 2px;">|</b><span>共5页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Liang Jia‐Yan&option=202" target="_blank" rel="nofollow">Liang Jia‐Yan;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhang Xu‐Dong&option=202" target="_blank" rel="nofollow">Zhang Xu‐Dong;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zeng Xian‐Xiang&option=202" target="_blank" rel="nofollow">Zeng Xian‐Xiang;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yan Min&option=202" target="_blank" rel="nofollow">Yan Min;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yin Ya‐Xia&option=202" target="_blank" rel="nofollow">Yin Ya‐Xia;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Xin Sen&option=202" target="_blank" rel="nofollow">Xin Sen;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wang Wen‐Peng&option=202" target="_blank" rel="nofollow">Wang Wen‐Peng;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wu Xiong‐Wei&option=202" target="_blank" rel="nofollow">Wu Xiong‐Wei;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Shi Ji‐Lei&option=202" target="_blank" rel="nofollow">Shi Ji‐Lei;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wan Li‐Jun&option=202" target="_blank" rel="nofollow">Wan Li‐Jun;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Guo Yu‐Guo&option=202" target="_blank" rel="nofollow">Guo Yu‐Guo;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>CAS Key Laboratory of Molecular Nanostructure and NanotechnologyChinese Academy of Sciences (CAS)Beijing 100190 P. R. China;</p> <p>CAS Key Laboratory of Molecular Nanostructure and NanotechnologyChinese Academy of Sciences (CAS)Beijing 100190 P. R. China;</p> <p>School of Chemistry and Materials ScienceHunan Agricultural UniversityChangsha 410128 P. R. China;</p> <p>CAS Key Laboratory of Molecular Nanostructure and NanotechnologyChinese Academy of Sciences (CAS)Beijing 100190 P. R. China;</p> <p>CAS Key Laboratory of Molecular Nanostructure and NanotechnologyChinese Academy of Sciences (CAS)Beijing 100190 P. R. China;</p> <p>CAS Key Laboratory of Molecular Nanostructure and NanotechnologyChinese Academy of Sciences (CAS)Beijing 100190 P. R. China;</p> <p>CAS Key Laboratory of Molecular Nanostructure and NanotechnologyChinese Academy of Sciences (CAS)Beijing 100190 P. R. China;</p> <p>School of Chemistry and Materials ScienceHunan Agricultural UniversityChangsha 410128 P. R. China;</p> <p>CAS Key Laboratory of Molecular Nanostructure and NanotechnologyChinese Academy of Sciences (CAS)Beijing 100190 P. R. China;</p> <p>CAS Key Laboratory of Molecular Nanostructure and NanotechnologyChinese Academy of Sciences (CAS)Beijing 100190 P. R. China;</p> <p>CAS Key Laboratory of Molecular Nanostructure and NanotechnologyChinese Academy of Sciences (CAS)Beijing 100190 P. R. China;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1188.html" title="应用化学">应用化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=amorphous phases&option=203" rel="nofollow">amorphous phases;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=cathode electrolyte interphase&option=203" rel="nofollow">cathode electrolyte interphase;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=hybrid solid/liquid batteries&option=203" rel="nofollow">hybrid solid/liquid batteries;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=interfacial electrochemistry&option=203" rel="nofollow">interfacial electrochemistry;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=interfacial stability&option=203" rel="nofollow">interfacial stability;</a> </p> <div class="translation"> 机译：无定形阶段;阴极电解质相互作用;混合固体/液体电池;界面电化学;界面稳定性; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704028162749.html">Enabling a Durable Electrochemical 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break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：用于保护二次电池阴极的固态电解质界面，该二次电池包括氨基官能化还原的氧化石墨烯薄膜，其制造方法以及包括相同成分的锂金属二次电池 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130400779817.html">- artificial solid electrolyte interphase for protecting anode of rechargeable battery preparation method thereof and lithium metal battery comprising the same</a> <b>[P]</b> . <span> 外国专利：  KR20200012169A </span> <span> . 2020-02-05</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：-用于保护可再充电电池阳极的人造固体电解质中间相及其制备方法和包括该中间相的锂金属电池 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon 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