Oxidative Addition of Alkenyl and Alkynyl Iodides to a AuI Complex

Cadge Jamie A.; Sparkes Hazel A.; Bower John F.; Russell Christopher A.

摘要

Abstract > The first isolated examples of intermolecular oxidative addition of alkenyl and alkynyl iodides to Au I are reported. Using a 5,5′‐difluoro‐2,2′‐bipyridyl ligated complex, oxidative addition of geometrically defined alkenyl iodides occurs readily, reversibly and stereospecifically to give alkenyl‐Au III complexes. Conversely, reversible alkynyl iodide oxidative addition generates bimetallic complexes containing both Au III and Au I centers. Stoichiometric studies show that both new initiation modes can form the basis for the development of C?C bond forming cross‐couplings. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 第一个分子氧化链烯基和炔基碘化物的分子氧化和Au i </ sup> 据报道。使用5,5'-二氟-2,2'-双吡啶连接复合物，容易地，可逆地和立体化地发生几何定义的链烯基碘的氧化添加以得到链烯基-α iii </ sup> 复合物。相反，可逆炔基碘化物氧化添加产生含有Au的双金属复合物 iii </ sup> 和au. i </ sup> 中心。化学计量研究表明，两种新的启动模式都可以形成C 2 C键形成交叉联轴器的基础。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-19011/'>《Angewandte Chemie》</a> <b style="margin: 0 2px;">|</b><span>2020年第16期</span><b style="margin: 0 2px;">|</b><span>共5页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Cadge Jamie A.&option=202" target="_blank" rel="nofollow">Cadge Jamie A.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Sparkes Hazel A.&option=202" target="_blank" rel="nofollow">Sparkes Hazel A.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Bower John F.&option=202" target="_blank" rel="nofollow">Bower John F.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Russell Christopher A.&option=202" target="_blank" rel="nofollow">Russell Christopher A.;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>School of ChemistryUniversity of BristolCantock's Close BS8 1TS UK;</p> <p>School of ChemistryUniversity of BristolCantock's Close BS8 1TS UK;</p> <p>School of ChemistryUniversity of BristolCantock's Close BS8 1TS UK;</p> <p>School of ChemistryUniversity of BristolCantock's Close BS8 1TS UK;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1188.html" title="应用化学">应用化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=alkenyl iodide&option=203" rel="nofollow">alkenyl iodide;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=alkynyl iodide&option=203" rel="nofollow">alkynyl iodide;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=bipyridyl&option=203" rel="nofollow">bipyridyl;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=gold&option=203" rel="nofollow">gold;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=oxidative addition&option=203" rel="nofollow">oxidative addition;</a> </p> <div class="translation"> 机译：链烯基碘;炔基碘;双吡啶基;金;氧化添加; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li 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href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=张翔&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 张翔</a> <span> . 2017</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/061201581305.html">(E)-苯乙烯基-炔基取代的硅化合物和获得(E)-苯乙烯基-炔基取代的硅化合物的方法</a> <b>[P]</b> . <span> 中国专利： CN102482298B </span> <span> . 2015.03.11</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/061201389367.html">2-取代的-6-氨基-5-烷基、烯基或炔基-嘧啶-4-羧酸和6-取代的-4-氨基-3-烷基、烯基或炔基吡啶-2-羧酸以及它们作为除草剂的用途</a> <b>[P]</b> . <span> 中国专利： CN101883759B </span> <span> . 2014.05.21</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130448211588.html">Preparation of bis(alkynyl)bis(phosphano)platinum complex, useful as e.g. cure catalyst for organopolysiloxane elastomer, involves reacting bis(phosphano)platinum dihalide and alkyne in presence of amine, alcohol and copper(I) iodide</a> <b>[P]</b> . <span> 外国专利：  DE19943102A1 </span> <span> . 2001-03-15</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：双（炔基）双（膦基）铂配合物的制备，例如用作有机聚硅氧烷弹性体的固化催化剂，涉及在胺，醇和碘化铜（I）存在下使双（膦）铂二卤化物与炔烃反应 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130489921815.html">Platinum-olefin complex catalyzed addition of hydrogen- and alkenyl-substituted siloxanes</a> <b>[P]</b> . <span> 外国专利：  US3159601A </span> <span> . 1964-12-01</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：铂-烯烃络合物催化氢和烯基取代的硅氧烷的加成 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130476202385.html">OXIDATIVE COUPLING OF PHENOLIC MONOMERS BY THE PROGRAMMED ADDITION OF COMPLEXED CATALYSTS</a> <b>[P]</b> . <span> 外国专利：  GB2002011B </span> <span> . 1982-01-27</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：程序化添加的复杂催化剂对酚类单体的氧化偶联 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" onclick="ywcd('0704028162742','4',7,2,1,'',this,24)" class="delivery" prompt="010401" title="通过人工服务将文献原文发送至邮箱" >获取原文</div> <div class="journalsub-pop-up" style="display: none"> <div class="journal-sub"> <h2>期刊订阅</h2> <img 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