C?H Oxygenation Reactions Enabled by Dual Catalysis with Electrogenerated Hypervalent Iodine Species and Ruthenium Complexes

Massignan Leonardo; Tan Xuefeng; Meyer Tjark H.; Kuniyil Rositha; Messinis Antonis M.; Ackermann Lutz

摘要

Abstract > The catalytic generation of hypervalent iodine(III) reagents by anodic electrooxidation was orchestrated towards an unprecedented electrocatalytic C?H oxygenation of weakly coordinating aromatic amides and ketones. Thus, catalytic quantities of iodoarenes in concert with catalytic amounts of ruthenium(II) complexes set the stage for versatile C?H activations with ample scope and high functional group tolerance. Detailed mechanistic studies by experiment and computation substantiate the role of the iodoarene as the electrochemically relevant species towards C?H oxygenations with electricity as a sustainable oxidant and molecular hydrogen as the sole by‐product. para ‐Selective C?H oxygenations likewise proved viable in the absence of directing groups. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 通过阳极电氧化的阳性电氧化催化生成阳性电氧化的催化产生朝向前所未有的电催化剂C-H氧合的弱协调芳族酰胺和酮。因此，具有催化量的钌（II）络合物的催化量碘化物与含有充足的范围和高官能团耐受性的通用C·H激活的阶段。通过实验和计算进行详细的机械研究，证实了碘芳烃作为电化学相关物种朝向C 2 H氧的作用，作为可持续氧化剂和作为唯一副产物的可持续氧化剂和分子氢。 para </ i> - 在没有指导基团的情况下，同样证明了同样证明的C'H氧。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-19011/'>《Angewandte Chemie》</a> <b style="margin: 0 2px;">|</b><span>2020年第8期</span><b style="margin: 0 2px;">|</b><span>共6页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Massignan Leonardo&option=202" target="_blank" rel="nofollow">Massignan Leonardo;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Tan Xuefeng&option=202" target="_blank" rel="nofollow">Tan Xuefeng;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Meyer Tjark H.&option=202" target="_blank" rel="nofollow">Meyer Tjark H.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Kuniyil Rositha&option=202" target="_blank" rel="nofollow">Kuniyil Rositha;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Messinis Antonis M.&option=202" target="_blank" rel="nofollow">Messinis Antonis M.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ackermann Lutz&option=202" target="_blank" rel="nofollow">Ackermann Lutz;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Institut für Organische und Biomolekulare ChemieGeorg-August-Universit?t G?ttingenTammannstra?e 2 37077 G?ttingen Germany;</p> <p>Institut für Organische und Biomolekulare ChemieGeorg-August-Universit?t G?ttingenTammannstra?e 2 37077 G?ttingen Germany;</p> <p>Institut für Organische und Biomolekulare ChemieGeorg-August-Universit?t G?ttingenTammannstra?e 2 37077 G?ttingen Germany;</p> <p>Institut für Organische und Biomolekulare ChemieGeorg-August-Universit?t G?ttingenTammannstra?e 2 37077 G?ttingen Germany;</p> <p>Institut für Organische und Biomolekulare ChemieGeorg-August-Universit?t G?ttingenTammannstra?e 2 37077 G?ttingen Germany;</p> <p>Institut für Organische und Biomolekulare ChemieGeorg-August-Universit?t G?ttingenTammannstra?e 2 37077 G?ttingen Germany;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1188.html" title="应用化学">应用化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=C?H activation&option=203" rel="nofollow">C?H activation;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=electrocatalysis&option=203" rel="nofollow">electrocatalysis;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=hypervalent iodine species&option=203" rel="nofollow">hypervalent iodine species;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=oxygenation&option=203" rel="nofollow">oxygenation;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=ruthenium&option=203" rel="nofollow">ruthenium;</a> </p> <div class="translation"> 机译：C？H激活;电殖分解;氧化碘;氧合;钌; 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