meso‐(2‐Pyridyl)‐boron(III)‐subporphyrin: Perimeter Iridium(III) Coordination

Lavarda Giulia; Shimizu Daiki; Torres Tomás; Osuka Atsuhiro

摘要

Abstract > Peripherally metalated porphyrinoids are promising functional π‐systems displaying characteristic optical, electronic, and catalytic properties. In this work, 5‐(2‐pyridyl)‐ and 5,10,15‐tri(2‐pyridyl)‐B III ‐subporphyrins were prepared and used to produce cyclometalated subporphyrins by reactions with [Cp*IrCl <sub>2</sub> ] <sub>2</sub> , which proceeded through an efficient C?H activation to give the corresponding mono‐ and tri‐Ir III complexes, respectively. While the mono‐Ir III complex was obtained as a diastereomeric mixture, a C <sub>3</sub> ‐symmetric tri‐Ir III complex with the three Cp*‐units all at the concave side was predominantly obtained in a high yield of 90?%, which displays weak NIR phosphorescence even at room temperature in degassed CH <sub>2</sub> Cl <sub>2</sub> , differently from the mono‐Ir III complexes. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 外围金属化卟啉曲线是有前途的功能π-系统，显示特征光学，电子和催化性能。在该工作中，5-（2-吡啶基） - 和5,10,15-Tri（2-吡啶基）-B iii </ sup> 制备 - 磺脲蛋白，并通过与[CP * IRCL的反应来制备环荷酸的亚卟啉 <sub> 2 </ sub> ] <sub> 2 </ sub> ，通过高效的C？H激活进行，以提供相应的单反和三烯 iii </ sup> 分别复合物。虽然单反生道 iii </ sup> 将复合物作为非对映异构混合物获得 c </ i> <sub> 3 </ sub> -MEMMETRICRIC iii </ sup> 与三个CP *的复合物均以凹面侧的30℃，高产率为90μm，即使在脱气的CH中的室温下也显示出弱的NIR磷光 <sub> 2 </ sub> CL. <sub> 2 </ sub> ，不同于单反红外 iii </ sup> 复合物。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-19011/'>《Angewandte Chemie》</a> <b style="margin: 0 2px;">|</b><span>2020年第8期</span><b style="margin: 0 2px;">|</b><span>共4页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Lavarda Giulia&option=202" target="_blank" rel="nofollow">Lavarda Giulia;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Shimizu Daiki&option=202" target="_blank" rel="nofollow">Shimizu Daiki;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Torres Tomás&option=202" target="_blank" rel="nofollow">Torres Tomás;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Osuka Atsuhiro&option=202" target="_blank" rel="nofollow">Osuka Atsuhiro;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Departamento de Química OrgánicaUniversidad Autonoma de MadridCantoblanco 28049 Madrid Spain;</p> <p>Department of ChemistryKyoto UniversitySakyo-ku Kyoto 606-8502 Japan;</p> <p>Departamento de Química OrgánicaUniversidad Autonoma de MadridCantoblanco 28049 Madrid Spain;</p> <p>Department of ChemistryKyoto UniversitySakyo-ku Kyoto 606-8502 Japan;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1188.html" title="应用化学">应用化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=iridium&option=203" rel="nofollow">iridium;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=organometallics&option=203" rel="nofollow">organometallics;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=porphyrinoid&option=203" rel="nofollow">porphyrinoid;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=phosphorescence&option=203" rel="nofollow">phosphorescence;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=subporphyrin&option=203" rel="nofollow">subporphyrin;</a> </p> <div class="translation"> 机译：铱;有机金属;卟啉;磷光;子卟啉; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704028162654.html">meso‐(2‐Pyridyl)‐boron(III)‐subporphyrin: Perimeter Iridium(III) Coordination</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Lavarda Giulia&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Lavarda Giulia,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Shimizu Daiki&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Shimizu Daiki,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Torres Tomás&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Torres Tomás,</a> <a href="/journal-foreign-19011/" target="_blank" rel="nofollow" class="tuijian_authcolor">Angewandte Chemie .</a> <span>2020</span><span>,第8期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：Meso-（2-吡啶基）-boron（III）-subporphylin：周长铱（III）协调</span> </p> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704018723355.html">Amidate iridium(III) bis(2-pyridyl)phenyl complexes: Application examples of amidate ancillary ligands in iridium(III)-cyclometalated complexes</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yang W.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Yang W.,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Fu H.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Fu H.,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Song Q.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Song Q.,</a> <a href="/journal-foreign-27756/" target="_blank" rel="nofollow" class="tuijian_authcolor">Organometallics .</a> <span>2011</span><span>,第1期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：酰胺化铱（III）双（2-吡啶基）苯基配合物：酰胺化辅助配体在铱（III）-环金属化配合物中的应用实例</span> </p> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704019756325.html">Preparation and Photophysical Properties of Bis(tridentate) Iridium(III) Emitters: Pincer Coordination of 2,6-Di(2-pyridyl)phenyl</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> </a> <a href="/journal-foreign-21948/" target="_blank" rel="nofollow" class="tuijian_authcolor">Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics .</a> <span>2020</span><span>,第6期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：双（三叉子）铱（III）发射器的制备和光物理性质：2,6-二（2-吡啶基）苯基的钳配位</span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-conference-foreign_meeting-259750_thesis/0705011352977.html">Bifunctional Selective Hydrosilylation of Terminal Alkynes by Bis(carbene)Iridium(III)and Rhodium(III)Complexes</a> <b>[C]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Luis A.Oro&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Luis A.Oro </a> <a href="/conference-foreign-259750/" target="_blank" rel="nofollow" class="tuijian_authcolor">Annual Saudi-Japan Symposium on Technology in Petroleum Refining and Petrochemicals .</a> <span>2018</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：双（卡宾烯）铱（III）和铑（III）配合物的末端炔烃的双官能选择性氢化硅烷化</span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-degree-foreign_mphd_thesis/02061709026.html">I. 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