Orthogonal Cationic and Radical RAFT Polymerizations to Prepare Bottlebrush Polymers

Tanaka Joji; H?kkinen Satu; Boeck Parker T.; Cong Yidan; Perrier Sébastien; Sheiko Sergei S.; You Wei

摘要

Abstract >An orthogonal combination of cationic and radical RAFT polymerizations is used to synthesize bottlebrush polymers using two distinct RAFT agents. Selective consumption of the first RAFT agent is used to control the cationic RAFT polymerization of a vinyl ether monomer bearing a secondary dormant RAFT agent, which subsequently allows side‐chain polymers to be grafted from the pendant RAFT agent by a radical‐mediated RAFT polymerization of a different monomer, thus completing the synthesis of bottlebrush polymers. The high efficiency and selectivity of the cationic and radical RAFT polymerizations allow both polymerizations to be conducted in one‐pot tandem without intermediate purification. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> >阳离子和自由基筏聚合的正交组合用于合成使用两个不同的筏剂的洗刷刷聚合物。第一筏剂的选择性消耗用于控制携带辅助休闲筏剂的乙烯基醚单体的阳离子筏聚合，随后允许通过自由基介导的筏聚合从侧链筏移植中从侧链筏剂移植不同的单体，从而完成吹瓶物聚合物的合成。阳离子和自由基筏聚合的高效率和选择性允许在不含中间纯化的情况下在一次串联中进行聚合。</ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-19011/'>《Angewandte Chemie》</a> <b style="margin: 0 2px;">|</b><span>2020年第18期</span><b style="margin: 0 2px;">|</b><span>共6页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Tanaka Joji&option=202" target="_blank" rel="nofollow">Tanaka Joji;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=H?kkinen Satu&option=202" target="_blank" rel="nofollow">H?kkinen Satu;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Boeck Parker T.&option=202" target="_blank" rel="nofollow">Boeck Parker T.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Cong Yidan&option=202" target="_blank" rel="nofollow">Cong Yidan;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Perrier Sébastien&option=202" target="_blank" rel="nofollow">Perrier Sébastien;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Sheiko Sergei S.&option=202" target="_blank" rel="nofollow">Sheiko Sergei S.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=You Wei&option=202" target="_blank" rel="nofollow">You Wei;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Department of ChemistryUniversity of North Carolina at Chapel HillChapel Hill NC 27599-3290 USA;</p> <p>Department of ChemistryUniversity of WarwickGibbet Hill Road Coventry CV4 7AL UK;</p> <p>Department of ChemistryUniversity of North Carolina at Chapel HillChapel Hill NC 27599-3290 USA;</p> <p>Department of ChemistryUniversity of North Carolina at Chapel HillChapel Hill NC 27599-3290 USA;</p> <p>Department of ChemistryUniversity of WarwickGibbet Hill Road Coventry CV4 7AL UK;</p> <p>Department of ChemistryUniversity of North Carolina at Chapel HillChapel Hill NC 27599-3290 USA;</p> <p>Department of ChemistryUniversity of North Carolina at Chapel HillChapel Hill NC 27599-3290 USA;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1188.html" title="应用化学">应用化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=bottlebrush polymers&option=203" rel="nofollow">bottlebrush polymers;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=cationic RAFT&option=203" rel="nofollow">cationic RAFT;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=orthogonal polymerization&option=203" rel="nofollow">orthogonal polymerization;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=selective RAFT process&option=203" rel="nofollow">selective RAFT process;</a> </p> <div class="translation"> 机译：泡刷聚合物;阳离子筏;正交聚合;选择性筏过程; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704028162612.html">Orthogonal Cationic and Radical RAFT Polymerizations to Prepare Bottlebrush 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href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=师永民&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,师永民</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=陈佳辉&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,陈佳辉</a> <span> <a href="/journal-cn-9217/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 应用化工 </a> </span> <span> . 2019</span><span>,第012期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-11698_thesis/02022444091.html">AKD专用新型阳离子聚合物乳化剂的制备与应用</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=龚本华&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 龚本华</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=严慧&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,严慧</a> <span> <a href="/conference-cn-11698/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 中国造纸学会涂布加工纸专业委员会第十六届学术年会、华东七省市造纸学会第二十五届学术年会、江西省造纸学(协)会2011年学术年会 </a> <span> <span> . 2011</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/02031766278.html">用多官能链转移剂通过普通自由基聚合制备两亲性杂臂星形聚合物</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=孔壮志&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 孔壮志</a> <span> . 2007</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06120885592.html">有机铋化合物、其制造方法、活性自由基聚合引发剂、使用该引发剂的聚合物制备方法及聚合物</a> <b>[P]</b> . <span> 中国专利： CN101090905B </span> <span> . 2012.02.15</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120766781.html">有机锑化合物、其制造方法、活性自由基聚合引发剂、使用该引发剂的聚合物制备方法及聚合物</a> <b>[P]</b> . <span> 中国专利： CN101076534B </span> <span> . 2011.06.22</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130429277843.html">Preparing graft rubber polymer, useful in thermoplastic molding materials, comprises adding graft monomers e.g. vinyl aromates, to mixture containing rubber and graft rubber polymer e.g. styrene, and radical polymerizing</a> <b>[P]</b> . <span> 外国专利：  DE102007035462A1 </span> <span> . 2009-01-29</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：制备可用于热塑性模塑材料中的接枝橡胶聚合物，包括加入接枝单体，例如丙烯酸。乙烯基芳香剂，形成含有橡胶和接枝橡胶聚合物（例如苯乙烯和自由基聚合 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130403850234.html">New photosensitizers for the processes of photoinitiated cationic, radical, thiol-ene and hybrid polymerization, new isomers of trans-aryl derivatives of 9-vinylanthracene and new photoinitiating systems for the processes of cationic, radical, thiol-ene and hybrid photopolymerization</a> <b>[P]</b> . <span> 外国专利：  PL231265B1 </span> <span> . 2019-02-28</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：用于光引发的阳离子，自由基，硫醇-烯和杂化聚合过程的新型光敏剂，9-乙烯基蒽的反式芳基衍生物的新异构体和用于阳离子，自由基，硫醇-烯和杂化光聚合过程的新光引发体系 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130403850227.html">New photoinitiating systems for the processes of photoinitiated cationic, radical, thiol-ene and hybrid polymerization, new derivatives of aniline, new fluorescent molecular probes for monitoring of the processes of photoinitiated cationic, radical, thiol-ene and hybrid polymerization and the application of aniline derivatives</a> <b>[P]</b> . <span> 外国专利：  PL231272B1 </span> <span> . 2019-02-28</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：用于光引发的阳离子，自由基，硫醇-烯和杂化聚合过程的新光引发体系，苯胺的新衍生物，用于监测光引发的阳离子，自由基，硫醇-烯和杂化聚合过程的新型荧光分子探针以及苯胺的应用衍生品 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" onclick="ywcd('0704028162612','4',7,2,1,'',this,24)" class="delivery" prompt="010401" title="通过人工服务将文献原文发送至邮箱" >获取原文</div> <div class="journalsub-pop-up" style="display: none"> <div class="journal-sub"> <h2>期刊订阅</h2> <img src="https://cdn.zhangqiaokeyan.com/img/loginclose.png" alt="关闭" onclick="$('.journalsub-pop-up').hide()"> <p class="pardon">抱歉，该期刊暂不可订阅，敬请期待！</p> <p 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