Controlling Gas Selectivity in Molecular Porous Liquids by Tuning the Cage Window Size

Egleston Benjamin D.; Luzyanin Konstantin V.; Brand Michael C.; Clowes Rob; Briggs Michael E.; Greenaway Rebecca L.; Cooper Andrew I.

摘要

Abstract > Control of pore window size is the standard approach for tuning gas selectivity in porous solids. Here, we present the first example where this is translated into a molecular porous liquid formed from organic cage molecules. Reduction of the cage window size by chemical synthesis switches the selectivity from Xe‐selective to CH <sub>4</sub> ‐selective, which is understood using 129 Xe, 1 H, and pulsed‐field gradient NMR spectroscopy. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 控制孔窗尺寸是在多孔固体中调谐气体选择性的标准方法。在这里，我们介绍了将其转化为由有机笼分子形成的分子多孔液体的第一个例子。通过化学合成减少笼式窗口大小从XE选择性切换到CH的选择性 <sub> 4 </ sub> - 选择使用的选择 129 </ sup> XE， 1 </ sup> h，和脉冲场梯度NMR光谱。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-19011/'>《Angewandte Chemie》</a> <b style="margin: 0 2px;">|</b><span>2020年第19期</span><b style="margin: 0 2px;">|</b><span>共5页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Egleston Benjamin D.&option=202" target="_blank" rel="nofollow">Egleston Benjamin D.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Luzyanin Konstantin V.&option=202" target="_blank" rel="nofollow">Luzyanin Konstantin V.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Brand Michael C.&option=202" target="_blank" rel="nofollow">Brand Michael C.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Clowes Rob&option=202" target="_blank" rel="nofollow">Clowes Rob;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Briggs Michael E.&option=202" target="_blank" rel="nofollow">Briggs Michael E.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Greenaway Rebecca L.&option=202" target="_blank" rel="nofollow">Greenaway Rebecca L.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Cooper Andrew I.&option=202" target="_blank" rel="nofollow">Cooper Andrew I.;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Department of Chemistry and Materials Innovation FactoryUniversity of LiverpoolOxford Street Liverpool L7 3NY UK;</p> <p>Department of ChemistryUniversity of LiverpoolCrown Street Liverpool L69 7ZD UK;</p> <p>Department of Chemistry and Materials Innovation FactoryUniversity of LiverpoolOxford Street Liverpool L7 3NY UK;</p> <p>Department of Chemistry and Materials Innovation FactoryUniversity of LiverpoolOxford Street Liverpool L7 3NY UK;</p> <p>Department of Chemistry and Materials Innovation FactoryUniversity of LiverpoolOxford Street Liverpool L7 3NY UK;</p> <p>Department of ChemistryUniversity of LiverpoolCrown Street Liverpool L69 7ZD UK;</p> <p>Department of Chemistry and Materials Innovation FactoryUniversity of LiverpoolOxford Street Liverpool L7 3NY UK;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1188.html" title="应用化学">应用化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=adsorption selectivity&option=203" rel="nofollow">adsorption selectivity;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=host-guest system&option=203" rel="nofollow">host-guest system;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=NMR&option=203" rel="nofollow">NMR;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=porous liquids&option=203" rel="nofollow">porous liquids;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=porous organic cages&option=203" rel="nofollow">porous organic cages;</a> </p> <div class="translation"> 机译：吸附选择性;寄宿机系统;NMR;多孔液体;多孔有机笼; 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