A Molecular Strategy to Lock‐in the Conformation of a Perylene Bisimide‐Derived Supramolecular Polymer

Ashcraft Adam; Liu Kaixuan; Mukhopadhyay Arindam; Paulino Victor; Liu Chuan; Bernard Brianna; Husainy Dalia; Phan Tina; Olivier Jean‐Hubert

摘要

Abstract >Locking‐in the conformation of supramolecular assemblies provides a new avenue to regulate the (opto)electronic properties of robust nanoscale objects. In the present contribution, we show that the covalent tethering of a perylene bisimide (PBI)‐derived supramolecular polymer with a molecular locker enables the formation of a locked superstructure equipped with emergent structure–function relationships. Experiments that exploit variable‐temperature ground‐state electronic absorption spectroscopy unambiguously demonstrate that the excitonic coupling between nearest neighboring units in the tethered superstructure is preserved at a temperature (371?K) where the pristine, non‐covalent assembly exists exclusively in a molecularly dissolved state. A close examination of the solid‐state morphologies reveals that the locked superstructure engenders the formation of hierarchical 1D materials which are not achievable by unlocked assemblies. To complement these structural attributes, we further demonstrate that covalently tethering a supramolecular polymer built from PBI subunits enables the emergence of electronic properties not evidenced in non‐covalent assemblies. Using cyclic voltammetry experiments, the elucidation of the potentiometric properties of the locked superstructure reveals a 100‐mV stabilization of the conduction band energy when compared to that recorded for the non‐covalent assembly. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> >锁定超分子组件的构象提供了一种新的途径来调节鲁棒纳米级对象的（光）电子特性。在目前的贡献中，我们表明，具有分子锁夹的鲍萘哒胺（PBI）的超分子聚合物的共价束缚使得能够形成配备有紧急结构函数关系的锁定的上部结构。利用可变温度地面电子吸收光谱的实验明确证明，在分子溶解的原始，非共价组装的温度（371Ωk）中保留了束缚上层结构中最近相邻单元之间的激动偶联。状态。对固态形态的密切检查表明，锁定的上部结构加剧了不可通过解锁组件无法实现的层级1D材料的形成。为了补充这些结构属性，我们进一步证明，共价束缚由PBI亚基构建的超分子聚合物使得能够在非共价组件中所证明的电子性质的出现。使用循环伏安法实验，锁定的上部结构的电位性能阐明，与非共价组装的记录相比，导带能量的100mV稳定。</ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-19011/'>《Angewandte Chemie》</a> <b style="margin: 0 2px;">|</b><span>2020年第19期</span><b style="margin: 0 2px;">|</b><span>共7页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ashcraft Adam&option=202" target="_blank" rel="nofollow">Ashcraft Adam;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Liu Kaixuan&option=202" target="_blank" rel="nofollow">Liu Kaixuan;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Mukhopadhyay Arindam&option=202" target="_blank" rel="nofollow">Mukhopadhyay Arindam;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Paulino Victor&option=202" target="_blank" rel="nofollow">Paulino Victor;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Liu Chuan&option=202" target="_blank" rel="nofollow">Liu Chuan;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Bernard Brianna&option=202" target="_blank" rel="nofollow">Bernard Brianna;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Husainy Dalia&option=202" target="_blank" rel="nofollow">Husainy Dalia;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Phan Tina&option=202" target="_blank" rel="nofollow">Phan Tina;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Olivier Jean‐Hubert&option=202" target="_blank" rel="nofollow">Olivier Jean‐Hubert;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Department of ChemistryThe University of Miami1301 Memorial Drive Cox Science Building Coral Gables FL 33146 USA;</p> <p>Department of ChemistryThe University of Miami1301 Memorial Drive Cox Science Building Coral Gables FL 33146 USA;</p> <p>Department of ChemistryThe University of Miami1301 Memorial Drive Cox Science Building Coral Gables FL 33146 USA;</p> <p>Department of ChemistryThe University of Miami1301 Memorial Drive Cox Science Building Coral Gables FL 33146 USA;</p> <p>Department of ChemistryThe University of Miami1301 Memorial Drive Cox Science Building Coral Gables FL 33146 USA;</p> <p>Department of ChemistryThe University of Miami1301 Memorial Drive Cox Science Building Coral Gables FL 33146 USA;</p> <p>Department of ChemistryThe University of Miami1301 Memorial Drive Cox Science Building Coral Gables FL 33146 USA;</p> <p>Department of ChemistryThe University of Miami1301 Memorial Drive Cox Science Building Coral Gables FL 33146 USA;</p> <p>Department of ChemistryThe University of Miami1301 Memorial Drive Cox Science Building Coral Gables FL 33146 USA;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1188.html" title="应用化学">应用化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=electrochemistry&option=203" rel="nofollow">electrochemistry;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=excitonic properties&option=203" rel="nofollow">excitonic properties;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=perylene bisimide&option=203" rel="nofollow">perylene bisimide;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=semiconducting nanomaterials&option=203" rel="nofollow">semiconducting nanomaterials;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=supramolecular polymer&option=203" rel="nofollow">supramolecular polymer;</a> </p> <div class="translation"> 机译：电化学;激子性质;Perylene Bisimide;半导体纳米材料;超分子聚合物; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul 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