Fabrication of Microporous Metal–Organic Frameworks in Uninterrupted Mesoporous Tunnels: Hierarchical Structure for Efficient Trypsin Immobilization and Stabilization

Lu Jie; Wu Ju‐Kang; Jiang Yao; Tan Peng; Zhang Lin; Lei Yu; Liu Xiao‐Qin; Sun Lin‐Bing

摘要

Abstract >Hierarchically porous metal–organic frameworks (HP‐MOFs) are promising in various applications. Most reported HP‐MOFs are prepared based on the generation of mesopores in microporous frameworks, and the formed mesopores are connected by microporous channels, limiting the accessibility of mesopores for bulky molecules. A hierarchical structure is formed by constructing microporous MOFs in uninterrupted mesoporous tunnels. Using the confined space in as‐prepared mesoporous silica, highly dispersed metal precursors for MOFs are coated on the internal surface of mesoporous tunnels. Ligand vapor‐induced crystallization is employed to enable quantitative formation of MOFs in?situ, in which sublimated ligands diffuse into mesoporous tunnels and react with metal precursors. The obtained hierarchically porous composites exhibit record‐high adsorption capacity for the bulky molecule trypsin. The thermal and storage stability of trypsin is improved upon immobilization on the composites. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> >阶级多孔金属 - 有机框架（HP-MOFS）在各种应用中是有前途的。大多数报道的HP-MOF是基于微孔框架中的中孔的产生制备的，并且形成的中孔通过微孔通道连接，限制了庞大分子的中孔的可访问性。通过在不间断的中孔隧道中构建微孔MOF来形成层次结构。使用用作制备的中孔二氧化硅中的限制空间，用于MOF的高度分散的金属前体涂覆在中孔隧道的内表面上。使用配体蒸汽诱导的结晶以使得可以在β原位中定量形成MOF，其中升华配体漫射到中孔隧道中并与金属前体反应。所获得的分层多孔复合材料表现出庞大的分子胰蛋白酶的记录高吸附能力。在固定在复合材料上的固定时，胰蛋白酶的热量和储存稳定性得到改善。</ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-19011/'>《Angewandte Chemie》</a> <b style="margin: 0 2px;">|</b><span>2020年第16期</span><b style="margin: 0 2px;">|</b><span>共7页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Lu Jie&option=202" target="_blank" rel="nofollow">Lu Jie;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wu Ju‐Kang&option=202" target="_blank" rel="nofollow">Wu Ju‐Kang;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Jiang Yao&option=202" target="_blank" rel="nofollow">Jiang Yao;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Tan Peng&option=202" target="_blank" rel="nofollow">Tan Peng;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhang Lin&option=202" target="_blank" rel="nofollow">Zhang Lin;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Lei Yu&option=202" target="_blank" rel="nofollow">Lei Yu;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Liu Xiao‐Qin&option=202" target="_blank" rel="nofollow">Liu Xiao‐Qin;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Sun Lin‐Bing&option=202" target="_blank" rel="nofollow">Sun Lin‐Bing;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>State Key Laboratory of Materials-Oriented Chemical EngineeringNanjing Tech UniversityNanjing 211816 China;</p> <p>State Key Laboratory of Materials-Oriented Chemical EngineeringNanjing Tech UniversityNanjing 211816 China;</p> <p>State Key Laboratory of Materials-Oriented Chemical EngineeringNanjing Tech UniversityNanjing 211816 China;</p> <p>State Key Laboratory of Materials-Oriented Chemical EngineeringNanjing Tech UniversityNanjing 211816 China;</p> <p>State Key Laboratory of Materials-Oriented Chemical EngineeringNanjing Tech UniversityNanjing 211816 China;</p> <p>State Key Laboratory of Materials-Oriented Chemical EngineeringNanjing Tech UniversityNanjing 211816 China;</p> <p>State Key Laboratory of Materials-Oriented Chemical EngineeringNanjing Tech UniversityNanjing 211816 China;</p> <p>State Key Laboratory of Materials-Oriented Chemical EngineeringNanjing Tech UniversityNanjing 211816 China;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1188.html" title="应用化学">应用化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=enzyme immobilization&option=203" rel="nofollow">enzyme immobilization;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=mesoporous tunnels&option=203" rel="nofollow">mesoporous tunnels;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=metal–organic frameworks&option=203" rel="nofollow">metal–organic frameworks;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=solvent-free methods&option=203" rel="nofollow">solvent-free methods;</a> </p> <div class="translation"> 机译：酶固定化;中孔隧道;金属 - 有机框架;无溶剂方法; </div> </li> </ul> </div> </div> <div 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2003</span><span>,第001期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-2921_thesis/02022626729.html">微孔金属有机骨架材料对惰性气体吸附分离的研究</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=熊顺顺&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 熊顺顺</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李伟&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,李伟</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=龚有进&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,龚有进</a> <span> <a href="/conference-cn-2921/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 第十三届全国核化学与放射化学学术研讨会 </a> <span> <span> . 2014</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020315208560.html">基于金属有机骨架纳米片和超微孔金属有机骨架的气相色谱分离新方法</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=陶泽榕&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 陶泽榕</a> <span> . 2019</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/061204512159.html">一种利用微孔结构的金属有机骨架材UIO-67衍生物吸附水中有机染料的方法</a> <b>[P]</b> . <span> 中国专利： CN110065989B </span> <span> . 2021.07.06</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120100854431.html">一种利用微孔结构的金属有机骨架材UIO-67衍生物吸附水中有机染料的方法</a> <b>[P]</b> . <span> 中国专利： CN110065989A </span> <span> . 2019-07-30</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130416509607.html">Use of microporous anionic inorganic framework structures, in particular containing dopant cations, for the production of thin-film solar cells or modules, photovoltaic thin-film solar cells containing microporous anionic inorganic framework structures, and methods for producing such thin-film solar photovoltaic modules</a> <b>[P]</b> . <span> 外国专利：  DE102012211894A1 </span> <span> . 2014-01-09</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：微孔阴离子无机骨架结构，特别是包含掺杂剂阳离子的用途，用于生产薄膜太阳能电池或组件，包含微孔阴离子无机骨架结构的光伏薄膜太阳能电池，以及生产这种薄膜太阳能光伏组件的方法 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130417359123.html">USE OF MICROPOROUS ANIONIC INORGANIC FRAMEWORK STRUCTURES, IN PARTICULAR CONTAINING DOPANT CATIONS, FOR PRODUCING THIN FILM SOLAR CELLS AND/OR MODULES, PHOTOVOLTAIC THIN FILM SOLAR CELLS CONTAINING MICROPOROUS ANIONIC INORGANIC FRAMEWORK STRUCTURES, AND METHOD FOR PRODUCING SUCH PHOTOVOLTAIC THIN FILM SOLAR MODULES</a> <b>[P]</b> . <span> 外国专利：  WO2014009061A2 </span> <span> . 2014-01-16</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：使用微细的阴离子无机框架结构，尤其是包含掺杂剂阳离子的阳离子膜，生产薄的薄膜太阳能电池和/或模块，包含微孔的多孔的含硅的无机薄膜的光伏薄膜，以及含碳纳米管的方法 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130408602007.html">Hierarchically ordered mesoporous titanium dioxide based on metal-organic frameworks preparation method thereof and dye-sensitized solar cell using the same</a> <b>[P]</b> . <span> 外国专利：  KR101733405B1 </span> <span> . 2017-05-10</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：基于金属有机骨架的分级有序介孔二氧化钛的制备方法和使用该介孔二氧化钛的染料敏化太阳能电池 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 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