De Novo Construction of Catenanes with Dissymmetric Cages by Space‐Discriminative Post‐Assembly Modification

Li Pan; Xu Shijun; Yu Chunyang; Li Zi‐Ying; Xu Jianping; Li Zi‐Mu; Zou Lingyi; Leng Xuebing; Gao Shan; Liu Zhiqiang; Liu Xiaoyun; Zhang Shaodong

摘要

Abstract > Considerable efforts have been made to increase the topological complexity of mechanically interlocked molecules over the years. Three‐dimensional catenated structures composed of two or several (usually symmetrical) cages are one representative example. However, owing to the lack of an efficient universal synthetic strategy, interlocked structures made up of dissymmetric cages are relatively rare. Since the space volume of the inner cavity of an interlocked structure is smaller than that outside it, we developed a novel synthetic approach with the voluminous reductant NaBH(OAc) <sub>3</sub> that discriminates this space difference, and therefore selectively reduces the outer surface of a catenated dimer composed of two symmetric cages, thus yielding the corresponding catenane with dissymmetric cages. Insight into the template effect that facilitates the catenation of cages was provided by computational and experimental techniques. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 已经努力增加了多年来增加机械互锁分子的拓扑复杂性。由两个或几个（通常对称）笼组成的三维被连接的结构是一个代表性示例。然而，由于缺乏高效的通用综合策略，由不对称的笼子组成的互锁结构相对较少。由于互锁结构的内腔的空间容积小于其外部的空间，因此我们开发了一种新的合成方法，具有巨大的纳米（OAC） <sub> 3 </ sub> 鉴别该空间差异，因此选择性地减少由两个对称笼组成的被连接的二聚体的外表面，从而产生具有不对称的笼的相应的萘烷。通过计算和实验技术提供有利于笼子的模板效果的洞察。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-19011/'>《Angewandte Chemie》</a> <b style="margin: 0 2px;">|</b><span>2020年第18期</span><b style="margin: 0 2px;">|</b><span>共9页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Li Pan&option=202" target="_blank" rel="nofollow">Li Pan;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Xu Shijun&option=202" target="_blank" rel="nofollow">Xu Shijun;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yu Chunyang&option=202" target="_blank" rel="nofollow">Yu Chunyang;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Li Zi‐Ying&option=202" target="_blank" rel="nofollow">Li Zi‐Ying;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Xu Jianping&option=202" target="_blank" rel="nofollow">Xu Jianping;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Li Zi‐Mu&option=202" target="_blank" rel="nofollow">Li Zi‐Mu;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zou Lingyi&option=202" target="_blank" rel="nofollow">Zou Lingyi;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Leng Xuebing&option=202" target="_blank" rel="nofollow">Leng Xuebing;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Gao Shan&option=202" target="_blank" rel="nofollow">Gao Shan;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Liu Zhiqiang&option=202" target="_blank" rel="nofollow">Liu Zhiqiang;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Liu Xiaoyun&option=202" target="_blank" rel="nofollow">Liu Xiaoyun;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhang Shaodong&option=202" target="_blank" rel="nofollow">Zhang Shaodong;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Frontiers Science Center for Transformative MoleculesShanghai Jiao Tong University800 Dongchuan Road Shanghai 200240 China;</p> <p>Key Laboratory of Specially Functional Polymeric Materials and Related Technology (ECUST)Ministry of Education130 Meilong Road Shanghai 200237 China;</p> <p>Frontiers Science Center for Transformative MoleculesShanghai Jiao Tong University800 Dongchuan Road Shanghai 200240 China;</p> <p>Key Laboratory of Specially Functional Polymeric Materials and Related Technology (ECUST)Ministry of Education130 Meilong Road Shanghai 200237 China;</p> <p>Frontiers Science Center for Transformative MoleculesShanghai Jiao Tong University800 Dongchuan Road Shanghai 200240 China;</p> <p>Frontiers Science Center for Transformative MoleculesShanghai Jiao Tong University800 Dongchuan Road Shanghai 200240 China;</p> <p>Frontiers Science Center for Transformative MoleculesShanghai Jiao Tong University800 Dongchuan Road Shanghai 200240 China;</p> <p>State Key Laboratory of Organometallic ChemistryChinese Academy of SciencesShanghai 200032 China;</p> <p>Neurological Department Shanghai Jiao Tong University Affiliated Sixth People's HospitalSouth CampusShanghai 200240 China;</p> <p>The National and Local Joint Engineering Research Center for Biomanufacturing of Chiral ChemicalsZhejiang University of TechnologyHangzhou 310014 China;</p> <p>Key Laboratory of Specially Functional Polymeric Materials and Related Technology (ECUST)Ministry of Education130 Meilong Road Shanghai 200237 China;</p> <p>Frontiers Science Center for Transformative MoleculesShanghai Jiao Tong University800 Dongchuan Road Shanghai 200240 China;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1188.html" title="应用化学">应用化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=catenanes&option=203" rel="nofollow">catenanes;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=interlocked cages&option=203" rel="nofollow">interlocked cages;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=reduction&option=203" rel="nofollow">reduction;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=structural topology&option=203" rel="nofollow">structural topology;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=supramolecular chemistry&option=203" rel="nofollow">supramolecular chemistry;</a> </p> <div class="translation"> 机译：Catenanes;互锁笼子;减少;结构拓扑;超分子化学; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704028162397.html">De Novo Construction of Catenanes with Dissymmetric Cages by Space‐Discriminative Post‐Assembly Modification</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Li Pan&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Li Pan,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Xu Shijun&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Xu Shijun,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yu Chunyang&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Yu Chunyang,</a> <a href="/journal-foreign-19011/" target="_blank" rel="nofollow" class="tuijian_authcolor">Angewandte Chemie .</a> <span>2020</span><span>,第18期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：通过空间鉴别后组装修改德诺施工用不对称的笼子</span> </p> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/070407608641.html">Synthesis and post-assembly modification of some functionalised, neutral pi-associated [2]catenanes</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhang Q.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Zhang Q.,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Feeder N.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Feeder N.,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Teat SJ.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Teat SJ.,</a> <a href="/journal-foreign-25889/" target="_blank" rel="nofollow" class="tuijian_authcolor">New Journal of Chemistry .</a> <span>1999</span><span>,第9期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：一些功能化的中性π缔合[2] catenanes的合成和组装后修饰</span> </p> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/070401133569.html">Chemical Modification of Amide-Based Catenanes and Rotaxanes II. Synthesis of tertiary Amine [2]Catenanes and [2]Rotaxanes via N-Methylation Followed by Borane Reduction of secondary Amide [2]Catenanes and [2]Rotaxanes and Mobility of Their Components</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Nobuhiro Watanabe&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Nobuhiro Watanabe,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yoshio Furusho&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Yoshio Furusho,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Nobuhiro Kihara&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Nobuhiro Kihara,</a> <a href="/journal-foreign-16202/" target="_blank" rel="nofollow" class="tuijian_authcolor">Bulletin of the Chemical Society of Japan .</a> <span>2001</span><span>,第1期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：酰胺基链烷和轮烷的化学修饰II。 N-甲基化合成叔胺[2]邻苯二甲酸酯和[2]轮烷，然后硼烷还原仲酰胺[2]邻苯二甲酸酯和[2]轮烷及其组分的流动性</span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-conference-foreign_meeting-256173_thesis/0705010088850.html">De Novo Sequencing and Characterization of Post-translational Modifications of an Amyloidogenic Immunoglobulin Kappa Light Chain</a> <b>[C]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yan Jiang&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Yan Jiang,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Roger Theberge&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Roger Theberge,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Jeremy Eberhard&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Jeremy Eberhard,</a> <a href="/conference-foreign-256173/" target="_blank" rel="nofollow" class="tuijian_authcolor">ASMS Conference on Mass Spectrometry and Allied Topics .</a> <span>2006</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：淀粉样蛋白免疫球蛋白Kappa轻链的翻译后修饰的DE Novo测序与表征</span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-degree-foreign_mphd_thesis/02061845632.html">The isolation and post-assembly modification of acyl peptidic siderophores</a> <b>[D] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Kem, Michelle Peov.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Kem, Michelle Peov. </a> <span>2014</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：酰基肽磷光体的分离和后组装改性</span> </p> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-journal-foreign-pmc_detail_thesis/040003236115.html">De novo construction of a Gene-space for diploid plant genome rich in repetitive sequences by an iterative Process of Extraction and Assembly of NGS reads (iPEA protocol) with limited computing resources</a> <b>[O] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Christelle Aluome&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Christelle Aluome,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Grégoire Aubert&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Grégoire Aubert,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Susete Alves Carvalho&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Susete Alves Carvalho,</a> <span>2016</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：通过使用有限的计算资源进行NGS读段的提取和组装的迭代过程（iPEA协议）从头构建富含重复序列的二倍体植物基因组的基因空间</span> </p> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/open-access_resources_thesis/0100026186029.html">De novo construction of a “Gene-space” for diploid plant genome rich in repetitive sequences by an iterative Process of Extraction and Assembly of NGS reads (iPEA protocol) with limited computing resources</a> <b>[O] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> </a> <span>2016</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：通过使用有限的计算资源进行NGS读段的提取和组装的迭代过程（iPEA协议）从头构建富含重复序列的二倍体植物基因组的“基因空间”</span> </p> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/academic-journal-cn_863-aerospace-technology-newsletter_thesis/0201263422858.html">修改后的国际空间站组装日程</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=江丕栋&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 江丕栋</a> <span> <a href="/journal-cn-42024/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 863航天技术通讯 </a> </span> <span> . 1997</span><span>,第012期</span> </span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/academic-journal-cn_journal-southwest-jiaotong-university_thesis/0201211288888.html">破解伯川德悖论的新视角--修改前提下的古诺模型分析</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=史旗凯&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 史旗凯</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=史凯歌&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,史凯歌</a> <span> <a href="/journal-cn-7638/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 西南交通大学学报 </a> </span> <span> . 2004</span><span>,第002期</span> </span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/academic-journal-cn_construction-materials-decoration_thesis/020129025054.html">桥梁空间不对称状态下对称配筋对施工监控的影响</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=罗沐鑫&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 罗沐鑫</a> <span> <a href="/journal-cn-9582/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 建材与装饰 </a> </span> <span> . 2016</span><span>,第040期</span> </span> </div> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-journal-cn_southeast-real-estate_thesis/0201245880565.html">DEFURO 德福诺厨柜·情感空间</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . </a> <span> <a href="/journal-cn-1945/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 东南置业 </a> </span> <span> . 2005</span><span>,第092期</span> </span> </div> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-journal-cn_traffic-engineering-technology-national-defence_thesis/0201272812482.html">狭窄空间下大跨度钢箱梁构件滑移法组装施工</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=郑维通&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 郑维通</a> <span> <a href="/journal-cn-10050/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 国防交通工程与技术 </a> </span> <span> . 2019</span><span>,第004期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-66713_thesis/020223021201.html">空间扭曲反对称结构钢塔的桥位环缝施工技术和质量控制</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=罗政军&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 罗政军</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=朱庆菊&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,朱庆菊</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=马春江&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,马春江</a> <span> <a href="/conference-cn-66713/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 2018年全国钢桥技术交流会暨第十一次学术年会会议 </a> <span> <span> . 2018</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06120108894419.html">四个伞状托盘对称组装式网箱锚固基础及其施工方法</a> <b>[P]</b> . <span> 中国专利： CN106417131A </span> <span> . 2017-02-22</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120103795340.html">一种适用地铁地下线狭小空间和高架线跨线轨排组装机及其施工方法</a> <b>[P]</b> . <span> 中国专利： CN111270577A </span> <span> . 2020-06-12</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130433962412.html">Wood frame construction e.g. frame house, has arches including two posts each coupled to adjacent post by insulating material layers that delimit space to receive insulated web which is separated from insulating layers by air spaces</a> <b>[P]</b> . <span> 外国专利：  FR2894604A1 </span> <span> . 2007-06-15</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：木结构建筑例如框架房屋，具有包括两个柱的拱门，每个柱通过绝缘材料层耦合到相邻柱，绝缘材料层界定了空间以容纳绝缘网，绝缘网通过空气空间与绝缘层隔开 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130444590339.html">Fence construction has series of spaced apart rigid posts extending vertically, separated by a connecting structure, and auxiliary posts made of fiber-reinforced plastic with electrically conductive lines between them</a> <b>[P]</b> . <span> 外国专利：  NL1021683C1 </span> <span> . 2003-04-18</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：栅栏结构具有一系列垂直间隔开的刚性支柱，这些刚性支柱由连接结构隔开，辅助支柱由纤维增强塑料制成，它们之间具有导电线 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130416487298.html">Formwork element for use as prefabricated unit of ring girder casing in construction site, has reinforcing cage arranged between formwork boards, and spacers for fixing minimum distance between cage and respective formwork board</a> <b>[P]</b> . <span> 外国专利：  DE102013106598A1 </span> <span> . 2014-01-02</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：模板元件，用作建筑工地环形箱梁壳体的预制单元，在模板之间设有加固笼，隔板用于固定笼与相应模板之间的最小距离 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" onclick="ywcd('0704028162397','4',7,2,1,'',this,24)" class="delivery" prompt="010401" title="通过人工服务将文献原文发送至邮箱" >获取原文</div> <div class="journalsub-pop-up" style="display: none"> <div class="journal-sub"> <h2>期刊订阅</h2> <img src="https://cdn.zhangqiaokeyan.com/img/loginclose.png" alt="关闭" onclick="$('.journalsub-pop-up').hide()"> <p class="pardon">抱歉，该期刊暂不可订阅，敬请期待！</p> <p class="current">目前支持订阅全部北京大学中文核心（2020）期刊目录。</p> <div style="display: flex;margin-top: 69px;justify-content: space-between;"> <div class="no-sub" onclick="$('.journalsub-pop-up').hide()">暂不订阅</div> <div class="other-sub" onclick="continueSub('from=pc-detail')">继续订阅其他期刊</div> </div> </div> </div> <div class="right_btn"> <ul> <li class="gouwuche">  </li> <li class="yijian"> <a href="javascript:void(0);" onclick="link_analysis('/mycenter/auth/complaint.html',this)" title="意见反馈">意见反馈</a> </li> <li class="top"> <a href="javascript:scrollTo(0,0);" title="回到顶部">回到顶部</a> </li> <li class="shouye"> <a href="/" title="首页">回到首页</a> </li> </ul> </div> <div class="xllindexfooter"> <div class="xllindexfootercenter"> <div class="xllindexfooterleft left" > <div class="xllindexfooterleftli"> <ul> <li><a href="/about.html" title="关于掌桥">关于掌桥</a></li> <li><a href="/help/helpmap.html" title="资源导航">资源导航</a></li> <li><a href="/help/helpguide.html" title="新手指南">新手指南</a></li> <li><a href="/help/helpcenter.html" title="常见问题">常见问题</a></li> <li><a href="/sitemap.html" title="网站地图">网站地图</a></li> <li><a href="/help/helpcenter.html?type=9" title="版权声明">版权声明</a></li> </ul> </div> <div class="xllindexfooterleft"> <p class="xllindexfooterlefteamil">客服邮箱：kefu@zhangqiaokeyan.com</p> <div class="xllindexfooterlefttcp"> <div class="xllindexfooterpoliceiimg"></div> <div class="xllindexfooterpoliceispan"> <span>京公网安备：11010802029741号 </span> <span>ICP备案号：<a href="https://beian.miit.gov.cn" rel="nofollow" target="_blank" title="ICP备案号">京ICP备15016152号-6</a></span> <span>六维联合信息科技 (北京) 有限公司©版权所有</span> </div> </div> </div> </div> <div class="xllindexfooterright left"> <ul> <li> <p style="font-weight: bold;">客服微信</p> <div></div> </li> <li> <p style="font-weight: bold;">服务号</p> <div></div> </li> </ul> </div> </div> </div> <span id="0704028162397down" data-source="7," data-out-id="XCJoqzqh+gF/+FXjgXiJXUBfIZ5mMeLb8MIzY93J3MyppCkYaZN/jY2FFJ7TO/ic," data-f-source-id="7" data-title="De Novo Construction of Catenanes with Dissymmetric Cages by Space‐Discriminative Post‐Assembly Modification" data-price="20" data-site-name="" data-transnum="24" style="display:none;"></span> <input type="hidden" value="4" id="sourcetype"> <input type="hidden" value="19011" id="journalid"> <input type="hidden" value="1" id="inyn_provide_service_level"> <input type="hidden" value="https://cdn.zhangqiaokeyan.com" id="imgcdn"> <input type="hidden" value="1" id="isdeatail"> <input type="hidden" value="" id="syyn_indexed_database"> <input type="hidden" value="" id="servicetype"> <input type="hidden" id="pagename" value="De Novo Construction of Catenanes with Dissymmetric Cages by Space‐Discriminative Post‐Assembly Modification"/> <input type="hidden" value="thesis_get_original" id="pageIdentification"> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/jquery-1.12.4.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/lwlh_ajax.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/zq.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/common.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/jquery.cookie.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/top.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/tip.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/login.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/down.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/search.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/newmail.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/searchtype.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/user/regist.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/zxs_solor/detail.js?v=5.7.8"></script> <script type="text/javascript" src="https://www.zhangqiaokeyan.com/statistics/static/pagecollection.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/tj.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/sse.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/pushbaidu.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/history.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/util/cookie.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/weipu/weipu.js?v=5.7.8"></script> </body> <script> $(function(){ var weiPuStatus = getCookie('WeiPuStatus'); if(weiPuStatus){ tipWeiPuStatus(weiPuStatus); delCookie('WeiPuStatus'); } getFacetKeywordVoInId(); var sourcetype = $("#sourcetype").val(); var inyn_provide_service_level = $("#inyn_provide_service_level").val(); if((sourcetype ==1||sourcetype==4)&&inyn_provide_service_level!=4){ getJournal(); } }) </script> </html>