Synthetic Applications of Oxidative Aromatic Coupling—From Biphenols to Nanographenes

Grzybowski Marek; Sadowski Bart?omiej; Butensch?n Holger; Gryko Daniel T.

摘要

Abstract >Oxidative aromatic coupling occupies a fundamental place in the modern chemistry of aromatic compounds. It is a method of choice for the assembly of large and bewildering architectures. Considerable effort was also devoted to applications of the Scholl reaction for the synthesis of chiral biphenols and natural products. The ability to form biaryl linkages without any prefunctionalization provides an efficient pathway to many complex structures. Although the chemistry of this process is only now becoming fully understood, this reaction continues to both fascinate and challenge researchers. This is especially true for heterocoupling, that is, oxidative aromatic coupling with the chemoselective formation of a C?C bond between two different arenes. Analysis of the progress achieved in this field since 2013 reveals that many groups have contributed by pushing the boundary of structural possibilities, expanding into surface‐assisted (cyclo)dehydrogenation, and developing new reagents. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> >氧化芳族偶联占据芳香化合物的现代化学中的基础位置。它是一种选择大型和困惑架构的选择方法。相当大的努力也致力于Scholl反应用于合成手性Biphenols和天然产物的应用。在没有任何预函数的情况下形成野牛连接的能力为许多复杂结构提供了有效的途径。虽然该过程的化学才能完全了解，但这种反应仍然占迷人和挑战研究人员。对于杂耦合，即氧化芳族偶联与两种不同的芳烃之间的C 2 C键合的氧化芳族偶联尤其如此。自2013年以来，对该领域实现的进展揭示了许多群体通过推动结构可能性的边界，扩展到表面辅助（环偶）脱氢，以及开发新试剂。</ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-19011/'>《Angewandte Chemie》</a> <b style="margin: 0 2px;">|</b><span>2020年第8期</span><b style="margin: 0 2px;">|</b><span>共30页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Grzybowski Marek&option=202" target="_blank" rel="nofollow">Grzybowski Marek;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Sadowski Bart?omiej&option=202" target="_blank" rel="nofollow">Sadowski Bart?omiej;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Butensch?n Holger&option=202" target="_blank" rel="nofollow">Butensch?n Holger;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Gryko Daniel T.&option=202" target="_blank" rel="nofollow">Gryko Daniel T.;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Institute of Organic ChemistryPolish Academy of SciencesKasprzaka 44/52 01-224 Warsaw Poland;</p> <p>Institute of Organic ChemistryPolish Academy of SciencesKasprzaka 44/52 01-224 Warsaw Poland;</p> <p>Institut für Organische ChemieLeibniz Universit?t HannoverSchneiderberg 1B 30167 Hannover Germany;</p> <p>Institute of Organic ChemistryPolish Academy of SciencesKasprzaka 44/52 01-224 Warsaw Poland;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1188.html" title="应用化学">应用化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=biaryls&option=203" rel="nofollow">biaryls;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Lewis acids&option=203" rel="nofollow">Lewis acids;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=nanographenes&option=203" rel="nofollow">nanographenes;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=oxidative coupling&option=203" rel="nofollow">oxidative coupling;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Scholl reaction&option=203" rel="nofollow">Scholl reaction;</a> </p> <div class="translation"> 机译：野生酱;路易斯酸;纳米甲酸;氧化偶联;舒尔反应; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704028162380.html">Synthetic Applications of Oxidative Aromatic Coupling—From Biphenols to Nanographenes</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Grzybowski Marek&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Grzybowski Marek,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Sadowski Bart?omiej&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Sadowski Bart?omiej,</a> <a 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