Controllable Synthesis of Porphyrin‐Based 2D Lanthanide Metal–Organic Frameworks with Thickness‐ and Metal‐Node‐Dependent Photocatalytic Performance

Jiang Zhong Wei; Zou Yang Chun; Zhao Ting Ting; Zhen Shu Jun; Li Yuan Fang; Huang Cheng Zhi

摘要

Abstract > Synthesizing 2D metal–organic frameworks (2D MOFs) in high yields and rational tailoring of the properties in a predictable manner for specific applications is extremely challenging. Now, a series of porphyrin‐based 2D lanthanide MOFs (Ln‐TCPP, Ln=Ce, Sm, Eu, Tb, Yb, TCPP=tetrakis(4‐carboxyphenyl) porphyrin) with different thickness were successfully prepared in a household microwave oven. The as‐prepared 2D Ln‐TCPP nanosheets showed thickness‐dependent photocatalytic performances towards photooxidation of 1,5‐dihydroxynaphthalene (1,5‐DHN) to synthesize juglone. Particularly, the Yb‐TCPP displayed outstanding photodynamic activity to generate O <sub>2</sub> ? and 1 O <sub>2</sub> . This work not only provides fundamental insights into structure designing and property tailoring of 2D MOFs nanosheets, but also pave a new way to improve the photocatalytic performance. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 以可预测的方式为特定应用的高收率和合理剪裁的高收率和合理剪裁的2D金属有机框架（2D MOF）非常具有挑战性。现在，在家用微波炉中成功制备了一系列基于卟啉的2D镧系元素（LN-TCPP，LN = Ce，SM，Eu，Tb，Yb，TCPP =四羧基）卟啉）。制备的2DLN-TCPP纳米片显示厚度依赖性光催化性能，朝向1,5-二羟基萘（1,5-DHN）的光氧化，以合成Juglone。特别是，YB-TCPP显示出优异的光动力活动以产生o <sub> 2 </ sub> ？</ sup> 和 1 </ sup> O. <sub> 2 </ sub> 。这项工作不仅为建筑设计和2D MOFS纳米片的物业剪裁，而且还提供了一种提高光催化性能的新方法。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-19011/'>《Angewandte Chemie》</a> <b style="margin: 0 2px;">|</b><span>2020年第8期</span><b style="margin: 0 2px;">|</b><span>共7页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Jiang Zhong Wei&option=202" target="_blank" rel="nofollow">Jiang Zhong Wei;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zou Yang Chun&option=202" target="_blank" rel="nofollow">Zou Yang Chun;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhao Ting Ting&option=202" target="_blank" rel="nofollow">Zhao Ting Ting;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhen Shu Jun&option=202" target="_blank" rel="nofollow">Zhen Shu Jun;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Li Yuan Fang&option=202" target="_blank" rel="nofollow">Li Yuan Fang;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Huang Cheng Zhi&option=202" target="_blank" rel="nofollow">Huang Cheng Zhi;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Key Laboratory of Luminescent and Real-Time Analytical ChemistryMinistry of EducationChongqing 400715 China;</p> <p>National Key Laboratory for Shock Wave and Detonation Physics ResearchChina Academy of Engineering PhysicsMianyang Sichuan 621900 China;</p> <p>Key Laboratory of Luminescent and Real-Time Analytical ChemistryMinistry of EducationChongqing 400715 China;</p> <p>Key Laboratory of Luminescent and Real-Time Analytical ChemistryMinistry of EducationChongqing 400715 China;</p> <p>Key Laboratory of Luminescent and Real-Time Analytical ChemistryMinistry of EducationChongqing 400715 China;</p> <p>Key Laboratory of Luminescent and Real-Time Analytical ChemistryMinistry of EducationChongqing 400715 China;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1188.html" title="应用化学">应用化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=2D materials&option=203" rel="nofollow">2D materials;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=metal–organic frameworks&option=203" rel="nofollow">metal–organic frameworks;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=metal nodes&option=203" rel="nofollow">metal nodes;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=photocatalysis&option=203" rel="nofollow">photocatalysis;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=thickness tuning&option=203" rel="nofollow">thickness tuning;</a> </p> <div class="translation"> 机译：2D材料;金属有机框架;金属节点;光催化;厚度调谐; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" 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2006</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020313438528.html">温和条件下萘镧系金属有机中间体合成及其真空热解制备纳米镧系金属粉末</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=高爱丽&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 高爱丽</a> <span> . 2005</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06120819318.html">萘镧系金属有机化合物合成及其真空热解制备纳米尺寸镧系金属粉末</a> <b>[P]</b> . <span> 中国专利： CN1557817B </span> <span> . 2011.09.14</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120427524.html">一种通过真空热解由卤代烃引发合成的蒽镧系金属有机化合物来制备纳米镧系金属粉末的方法</a> <b>[P]</b> . <span> 中国专利： CN100427249C </span> <span> . 2008.10.22</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130409826540.html">Metal-organic framework composite with nano metal-organic frameworks embedded in host metal-organic framework, method for producing the metal-organic framework composite and gas storage including the metal-organic framework composite</a> <b>[P]</b> . <span> 外国专利：  US9675958B2 </span> <span> . 2017-06-13</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：在主体金属有机骨架中埋入有纳米金属有机骨架的金属有机骨架复合物，金属有机骨架复合物的制造方法以及包含该金属有机骨架复合物的储气装置 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130410085492.html">METAL-ORGANIC FRAMEWORK COMPOSITE WITH NANO METAL-ORGANIC FRAMEWORKS EMBEDDED IN HOST METAL-ORGANIC FRAMEWORK, METHOD FOR PRODUCING THE METAL-ORGANIC FRAMEWORK COMPOSITE AND GAS STORAGE INCLUDING THE METAL-ORGANIC FRAMEWORK COMPOSITE</a> <b>[P]</b> . <span> 外国专利：  US2017072383A1 </span> <span> . 2017-03-16</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：包含在主体金属有机框架中的纳米金属有机框架的金属有机框架复合材料，制备金属有机框架复合材料的方法和包括金属有机框架复合材料的气体存储 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130412621576.html">Method for adsorbing carbon dioxide onto porous metal-organic framework materials, method for cooling porous metal-organic framework materials, method for obtaining aldehyde using porous metal-organic framework materials, and method for warming porous metal-organic framework materials</a> <b>[P]</b> . <span> 外国专利：  US9309264B2 </span> <span> . 2016-04-12</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：将二氧化碳吸附到多孔金属有机骨架材料上的方法，冷却多孔金属有机骨架材料的方法，使用多孔金属有机骨架材料获得醛的方法以及加热多孔金属有机骨架材料的方法 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: 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