Photodissociation Mechanisms of Major Mercury(II) Species in the Atmospheric Chemical Cycle of Mercury

Francés‐Monerris Antonio; Carmona‐García Javier; Acu?a A. Ulises; Dávalos Juan Z.; Cuevas Carlos A.; Kinnison Douglas E.; Francisco Joseph S.; Saiz‐Lopez Alfonso; Roca‐Sanjuán Daniel

摘要

Abstract > Mercury is a contaminant of global concern that is transported throughout the atmosphere as elemental mercury Hg 0 and its oxidized forms Hg I and Hg II . The efficient gas‐phase photolysis of Hg II and Hg I has recently been reported. However, whether the photolysis of Hg II leads to other stable Hg II species, to Hg I , or to Hg 0 and its competition with thermal reactivity remain unknown. Herein, we show that all oxidized forms of mercury rapidly revert directly and indirectly to Hg 0 by photolysis. Results are based on non‐adiabatic dynamics simulations, in which the photoproduct ratios were determined with maximum errors of 3%. We construct for the first time a complete quantitative mechanism of the photochemical and thermal conversion between atmospheric Hg II , Hg I , and Hg 0 compounds. These results reveal new fundamental chemistry that has broad implications for the global atmospheric Hg cycle. Thus, photoreduction clearly competes with thermal oxidation, with Hg 0 being the main photoproduct of Hg II photolysis in the atmosphere, which significantly increases the lifetime of this metal in the environment. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > Mercury是全球担忧的污染物，其在整个大气中作为元素汞汞柱运输 0 </ sup> 其氧化形式Hg i </ sup> 和幼崽 ii </ sup> 。 HG的有效气相光解 ii </ sup> 和幼崽 i </ sup> 最近报道。但是，无论是HG的光解 ii </ sup> 导致其他稳定的hg ii </ sup> 物种，到Hg i </ sup> ，或到hg 0 </ sup> 它与热反应性的竞争仍然未知。在此，我们表明所有氧化形式的汞迅速直接恢复为Hg 0 </ sup> 通过光解。结果基于非绝热动力学模拟，其中测定光调解物比率为3％的最大误差。我们首次构建了大气HG之间的光化学和热转换的完全定量机制 ii </ sup> ，Hg i </ sup> 和hg 0 </ sup> 化合物。这些结果揭示了新的基本化学，对全球大气的HG周期具有广泛影响。因此，光触发清晰地与热氧化竞争，HG 0 </ sup> 作为HG的主要光调节 ii </ sup> 在大气中的光解，显着增加了这种金属在环境中的寿命。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-19011/'>《Angewandte Chemie》</a> <b style="margin: 0 2px;">|</b><span>2020年第19期</span><b style="margin: 0 2px;">|</b><span>共6页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Francés‐Monerris Antonio&option=202" target="_blank" rel="nofollow">Francés‐Monerris Antonio;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Carmona‐García Javier&option=202" target="_blank" rel="nofollow">Carmona‐García Javier;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Acu?a A. Ulises&option=202" target="_blank" rel="nofollow">Acu?a A. Ulises;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Dávalos Juan Z.&option=202" target="_blank" rel="nofollow">Dávalos Juan Z.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Cuevas Carlos A.&option=202" target="_blank" rel="nofollow">Cuevas Carlos A.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Kinnison Douglas E.&option=202" target="_blank" rel="nofollow">Kinnison Douglas E.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Francisco Joseph S.&option=202" target="_blank" rel="nofollow">Francisco Joseph S.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Saiz‐Lopez Alfonso&option=202" target="_blank" rel="nofollow">Saiz‐Lopez Alfonso;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Roca‐Sanjuán Daniel&option=202" target="_blank" rel="nofollow">Roca‐Sanjuán Daniel;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>CNRS LPCTUniversité de Lorraine54000 Nancy France;</p> <p>Institut de Ciència MolecularUniversitat de València46071 València Spain;</p> <p>Department of Atmospheric Chemistry and ClimateCSIC28006 Madrid Spain;</p> <p>Department of Atmospheric Chemistry and ClimateCSIC28006 Madrid Spain;</p> <p>Department of Atmospheric Chemistry and ClimateCSIC28006 Madrid Spain;</p> <p>NCARAtmospheric Chemistry Observations and ModellingBoulder CO 80301 USA;</p> <p>Department of Earth and Environmental Sciences and Department of ChemistryUniversity of PennsylvaniaPhiladelphia PA 19104 USA;</p> <p>Department of Atmospheric Chemistry and ClimateCSIC28006 Madrid Spain;</p> <p>Institut de Ciència MolecularUniversitat de València46071 València Spain;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1188.html" title="应用化学">应用化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=atmospheric chemistry&option=203" rel="nofollow">atmospheric chemistry;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=mercury&option=203" rel="nofollow">mercury;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=multiconfigurational quantum chemistry&option=203" rel="nofollow">multiconfigurational quantum chemistry;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=non-adiabatic dynamics&option=203" rel="nofollow">non-adiabatic dynamics;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=photodissociation&option=203" rel="nofollow">photodissociation;</a> </p> <div class="translation"> 机译：大气化学;汞;多功能措施量子化学;非绝热动力学;光度解放; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704028162236.html">Photodissociation Mechanisms of Major Mercury(II) Species in the Atmospheric Chemical Cycle of Mercury</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Francés‐Monerris Antonio&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Francés‐Monerris Antonio,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Carmona‐García Javier&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Carmona‐García Javier,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Acu?a A. Ulises&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Acu?a A. Ulises,</a> <a href="/journal-foreign-19011/" target="_blank" rel="nofollow" class="tuijian_authcolor">Angewandte Chemie .</a> <span>2020</span><span>,第19期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：汞大气化学循环中主要汞（II）物种的光沉积机制</span> </p> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/070404998693.html">Global atmospheric cycle of mercury: a model study on the impact of oxidation mechanisms</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=F. De Simone&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">F. De Simone,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=C. N. Gencarelli&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">C. N. Gencarelli,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=I. M. Hedgecock&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">I. M. Hedgecock </a> <a href="/journal-foreign-22738/" target="_blank" rel="nofollow" class="tuijian_authcolor">Environmental Science and Pollution Research .</a> <span>2014</span><span>,第6期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：汞的全球大气循环：氧化机理影响的模型研究</span> </p> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/academic-journal-foreign_detail_thesis/0204118635857.html">Overview of major processes and mechanisms affecting the mercury cycle on different spatial and temporal scales</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=N. Pirrone&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">N. Pirrone,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=I.M. Hedgecock&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">I.M. Hedgecock,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=S. Cinnirella&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">S. Cinnirella,</a> <a href="/journal-foreign-22705/" target="_blank" rel="nofollow" class="tuijian_authcolor">EPJ Web of Conferences .</a> <span>2010</span><span>,第1期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：概述在不同时空尺度上影响汞循环的主要过程和机制</span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-conference-foreign_meeting-255966_thesis/0705010006733.html">Distribution of Mercury in different Soils in Amazonia's Mid-Rio Negro Basin: Influence of Organic Matter on the Biogeochemical Cycle of Mercury</a> <b>[C]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Julio Cesar Rocha&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Julio Cesar Rocha,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Luciana Camargo de Oliveira&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Luciana Camargo de Oliveira,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ricardo Lima Serudo&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Ricardo Lima Serudo </a> <a href="/conference-foreign-255966/" target="_blank" rel="nofollow" class="tuijian_authcolor">the Meeting of the International Humic Substances Society .</a> <span>2006</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：亚马逊中里约Negro盆地不同土壤中汞的分布：有机物对汞生物地球化学循环的影响</span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-degree-foreign_mphd_thesis/02061211657.html">Application of chemical kinetics to mercury cycling in the aquatic environment: Photoreduction of mercury(II) and binding of mercury(II) and methylmercury(+) to natural ligands.</a> <b>[D] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ababneh, Fuad A.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Ababneh, Fuad A. </a> <span>2005</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：化学动力学在水生环境中汞循环中的应用：汞（II）的光还原以及汞（II）和甲基汞（+）与天然配体的结合。</span> </p> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-journal-foreign-pmc_bacteriological-reviews_thesis/040002929651.html">Mechanisms of microbial resistance and detoxification of mercury and organomercury compounds: physiological biochemical and genetic analyses.</a> <b>[O] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=J B Robinson&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">J B Robinson,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=O H Tuovinen&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">O H Tuovinen </a> <span>1984</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：汞和有机汞化合物的微生物抗性和解毒机理：生理生化和遗传分析。</span> </p> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/open-access_resources_thesis/01000127318227.html">Photodissociation Mechanisms of Major Mercury(II) Species in the Atmospheric Chemical Cycle of Mercury</a> <b>[O] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Antonio Francés‐Monerris&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Antonio Francés‐Monerris,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Javier Carmona‐García&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Javier Carmona‐García,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=A. Ulises Acuña&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">A. Ulises Acuña,</a> <span>2020</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：汞大气化学循环中主要汞（II）物种的光学探测机制</span> </p> </li> <li> <div> <b>8. </b><a class="enjiyixqcontent" href="/ntis-science-report_de_thesis/020711364404.html">Biogeochemical Cycle of Mercury Species in the Marine Environment. Final Report for the Period 1 May 1986 - 30 March 1987</a> <b>[R] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Branica, M.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Branica, M. </a> <span>1987</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：海洋环境中汞物种的生物地球化学循环。 1986年5月1日至1987年3月30日期间的最后报告</span> </p> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/academic-journal-cn_experimental-technology-management_thesis/020125424298.html">HydraIIC型汞分析仪测定人参中汞含量的方法研究</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=商云帅&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 商云帅</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王东&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,王东</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王峰&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,王峰</a> <span> <a href="/journal-cn-2730/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 实验技术与管理 </a> </span> <span> . 2014</span><span>,第010期</span> </span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/academic-journal-cn_journal-beijing-university-science-technology_thesis/0201279702621.html">酸性含汞溶液中电沉积回收汞的研究</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李子良&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 李子良</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=徐志峰&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,徐志峰</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=张溪&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,张溪</a> <span> <a href="/journal-cn-4503/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 北京科技大学学报 </a> </span> <span> . 2020</span><span>,第008期</span> </span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/academic-journal-cn_analytical-instrumentation_thesis/0201273285788.html">烷基汞分析仪测定沉积物中甲基汞</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=孔维恒&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 孔维恒</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=邱烨&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,邱烨</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王琳丽&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,王琳丽</a> <span> <a href="/journal-cn-8218/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 分析仪器 </a> </span> <span> . 2019</span><span>,第005期</span> </span> </div> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-journal-cn_detail_thesis/0201296856600.html">闽浙沿岸海域沉积物中汞和甲基汞的含量分布及其影响因素</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=张怀静&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 张怀静</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=翟世奎&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,翟世奎</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=周勇华&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,周勇华</a> <span> <a href="/journal-cn-56825/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 海洋地质与第四纪地质 </a> </span> <span> . 2016</span><span>,第6期</span> </span> </div> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-journal-cn_chinese-journal-analytical-chemistry_thesis/0201230558342.html">微波萃取高效液相色谱-冷原子荧光光谱法测定沉积物中甲基汞和无机汞</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=冷庚&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 冷庚</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王俊伟&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,王俊伟</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=万旭&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,万旭</a> <span> <a href="/journal-cn-10804/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 分析化学 </a> </span> <span> . 2012</span><span>,第002期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-4449_thesis/020221077802.html">水产养殖对水库沉积物中甲基汞地球化学循环的影响</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=闫海鱼&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 闫海鱼</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=冯彩艳&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,冯彩艳</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=俞奔&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,俞奔</a> <span> <a href="/conference-cn-4449/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 中国矿物岩石地球化学学会第14届学术年会 </a> <span> <span> . 2013</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020312755413.html">夹皮沟金矿区土壤中汞和甲基汞的空间分布及汞的生态风险评价</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=刘雪姣&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 刘雪姣</a> <span> . 2011</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06120113504836.html">一种通过氯硒汞沉积从含硫含汞烟气中捕集汞的方法</a> <b>[P]</b> . <span> 中国专利： CN113521979A </span> <span> . 2021-10-22</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/061202714295.html">从含汞蒸汽中回收汞的汞回收装置</a> <b>[P]</b> . <span> 中国专利： CN104998515B </span> <span> . 2017.12.29</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130417548925.html">recombinant bacterium capable of removing chemical species of mercury (II); cadmium and copper in the presence of other heavy metals from contaminated sites; bioremediation product; process of obtaining the product and method of application for bioremediation.</a> <b>[P]</b> . <span> 外国专利：  ES2396765B1 </span> <span> . 2014-01-15</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：能够去除化学汞的重组细菌;来自受污染场所的其他重金属存在下的镉和铜;生物修复产品;获得产品的过程和生物修复的应用方法。 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130420162303.html">recombinant bacterium capable of removing chemical species of mercury (II); cadmium and copper in the presence of other heavy metals from contaminated sites; bioremediation product; process of obtaining the product and method of application for bioremediation.</a> <b>[P]</b> . <span> 外国专利：  ES2396765A1 </span> <span> . 2013-02-26</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：能够去除化学汞的重组细菌;来自受污染场所的其他重金属存在下的镉和铜;生物修复产品;获得产品的过程和生物修复的应用方法。 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130424859403.html">RECOMBINANT BACTERIA CAPABLE OF REMOVING CHEMICAL SPECIES OF MERCURY (II), CADMIUM AND COPPER IN THE PRESENCE OF OTHER HEAVY METALS FROM CONTAMINATED LOCATIONS, PRODUCT FOR BIOREMEDIATION, PROCESS FOR THE OBTAINMENT OF THE PRODUCT AND METHOD OF APPLICATION FOR BIOREMEDIATION</a> <b>[P]</b> . <span> 外国专利：  WO2011080663A2 </span> <span> . 2011-07-07</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：在受污染场所，其他生物修复产品，该产品的获得过程和该产品的应用方法中，如果存在其他重金属，则能够去除汞（II），镉和铜的化学物种的重组细菌 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" onclick="ywcd('0704028162236','4',7,2,1,'',this,24)" class="delivery" prompt="010401" title="通过人工服务将文献原文发送至邮箱" >获取原文</div> <div class="journalsub-pop-up" style="display: none"> <div class="journal-sub"> <h2>期刊订阅</h2> <img src="https://cdn.zhangqiaokeyan.com/img/loginclose.png" alt="关闭" onclick="$('.journalsub-pop-up').hide()"> <p class="pardon">抱歉，该期刊暂不可订阅，敬请期待！</p> <p class="current">目前支持订阅全部北京大学中文核心（2020）期刊目录。</p> <div style="display: flex;margin-top: 69px;justify-content: space-between;"> <div class="no-sub" onclick="$('.journalsub-pop-up').hide()">暂不订阅</div> <div class="other-sub" onclick="continueSub('from=pc-detail')">继续订阅其他期刊</div> </div> </div> </div> <div class="right_btn"> <ul> <li class="gouwuche">  </li> <li class="yijian"> <a href="javascript:void(0);" onclick="link_analysis('/mycenter/auth/complaint.html',this)" title="意见反馈">意见反馈</a> </li> <li class="top"> <a href="javascript:scrollTo(0,0);" title="回到顶部">回到顶部</a> </li> <li class="shouye"> <a href="/" title="首页">回到首页</a> </li> </ul> </div> <div class="xllindexfooter"> <div class="xllindexfootercenter"> <div class="xllindexfooterleft left" > <div class="xllindexfooterleftli"> <ul> <li><a href="/about.html" title="关于掌桥">关于掌桥</a></li> <li><a href="/help/helpmap.html" title="资源导航">资源导航</a></li> <li><a href="/help/helpguide.html" title="新手指南">新手指南</a></li> <li><a href="/help/helpcenter.html" title="常见问题">常见问题</a></li> <li><a href="/sitemap.html" title="网站地图">网站地图</a></li> <li><a href="/help/helpcenter.html?type=9" title="版权声明">版权声明</a></li> </ul> </div> <div class="xllindexfooterleft"> <p class="xllindexfooterlefteamil">客服邮箱：kefu@zhangqiaokeyan.com</p> <div class="xllindexfooterlefttcp"> <div class="xllindexfooterpoliceiimg"></div> <div class="xllindexfooterpoliceispan"> <span>京公网安备：11010802029741号 </span> <span>ICP备案号：<a href="https://beian.miit.gov.cn" rel="nofollow" target="_blank" title="ICP备案号">京ICP备15016152号-6</a></span> <span>六维联合信息科技 (北京) 有限公司©版权所有</span> </div> </div> </div> </div> <div class="xllindexfooterright left"> <ul> <li> <p style="font-weight: bold;">客服微信</p> <div></div> </li> <li> <p style="font-weight: bold;">服务号</p> <div></div> </li> </ul> </div> </div> </div> <span id="0704028162236down" data-source="7," data-out-id="hyQA/gnNeqTV8OfASjVGNk4FFdQCdkHID0puo2waC1tOrnMmB6r27AA24LxOZMOH," data-f-source-id="7" data-title="Photodissociation Mechanisms of Major Mercury(II) Species in the Atmospheric Chemical Cycle of Mercury" data-price="20" data-site-name="" data-transnum="24" style="display:none;"></span> <input type="hidden" value="4" id="sourcetype"> <input type="hidden" value="19011" id="journalid"> <input type="hidden" value="1" id="inyn_provide_service_level"> <input type="hidden" value="https://cdn.zhangqiaokeyan.com" id="imgcdn"> <input type="hidden" value="1" id="isdeatail"> <input type="hidden" value="" id="syyn_indexed_database"> <input type="hidden" value="" id="servicetype"> <input type="hidden" id="pagename" value="Photodissociation Mechanisms of Major Mercury(II) Species in the Atmospheric Chemical Cycle of Mercury"/> <input type="hidden" value="thesis_get_original" id="pageIdentification"> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/jquery-1.12.4.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/lwlh_ajax.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/zq.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/common.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/jquery.cookie.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/top.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/tip.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/login.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/down.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/search.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/newmail.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/searchtype.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/user/regist.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/zxs_solor/detail.js?v=5.7.8"></script> <script type="text/javascript" src="https://www.zhangqiaokeyan.com/statistics/static/pagecollection.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/tj.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/sse.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/pushbaidu.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/history.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/util/cookie.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/weipu/weipu.js?v=5.7.8"></script> </body> <script> $(function(){ var weiPuStatus = getCookie('WeiPuStatus'); if(weiPuStatus){ tipWeiPuStatus(weiPuStatus); delCookie('WeiPuStatus'); } getFacetKeywordVoInId(); var sourcetype = $("#sourcetype").val(); var inyn_provide_service_level = $("#inyn_provide_service_level").val(); if((sourcetype ==1||sourcetype==4)&&inyn_provide_service_level!=4){ getJournal(); } }) </script> </html>