Soft Lattice and Defect Covalency Rationalize Tolerance of β‐CsPbI3 Perovskite Solar Cells to Native Defects

Chu Weibin; Saidi Wissam A.; Zhao Jin; Prezhdo Oleg V.

摘要

Abstract > Although all‐inorganic metal halide perovskites (MHPs) have shown tremendous improvement, they are still inferior to the hybrid organic–inorganic MHPs in efficiency. Recently, a conceptually new β‐CsPbI <sub>3</sub> perovskite reached 18.4?% efficiency combined with good thermodynamic stability at ambient conditions. We use ab initio non‐adiabatic molecular dynamics to show that native point defects in β‐CsPbI <sub>3</sub> are generally benign for nonradiative charge recombination, regardless of whether they introduce shallow or deep trap states. These results indicate that MHPs do not follow the simple models used to explain defect‐mediated charge recombination in the conventional semiconductors. The strong tolerance is due to the softness of the perovskite lattice, which permits separation of electrons and holes upon defect formation, and only allows carriers to couple to the low‐frequency vibrations. Both factors decrease notably the non‐adiabatic coupling and slow down the dissipation of energy to heat. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 虽然全无机金属卤化物钙酸盐（MHPS）表现出巨大的改进，但它们仍然效率较差，效率较差。最近，一个概念上的新β-cspbi <sub> 3 </ sub> Perovskite达到18.4倍的效率，在环境条件下具有良好的热力学稳定性。我们使用AB Initio非绝热分子动力学显示β-CSPBI中的本土点缺陷 <sub> 3 </ sub> 无论它们是否引入浅或深陷阱状态，都是良性的非抗体电荷重组。这些结果表明MHP不遵循用于解释常规半导体中缺陷介导的电荷重组的简单模型。强耐受性是由于钙钛矿晶格的柔软性，这允许在缺陷形成时分离电子和孔，并且仅允许载体耦合到低频振动。两个因素显着降低了非绝热耦合并减慢了对热量的耗散。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-19011/'>《Angewandte Chemie》</a> <b style="margin: 0 2px;">|</b><span>2020年第16期</span><b style="margin: 0 2px;">|</b><span>共7页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Chu Weibin&option=202" target="_blank" rel="nofollow">Chu Weibin;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Saidi Wissam A.&option=202" target="_blank" rel="nofollow">Saidi Wissam A.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhao Jin&option=202" target="_blank" rel="nofollow">Zhao Jin;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Prezhdo Oleg V.&option=202" target="_blank" rel="nofollow">Prezhdo Oleg V.;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Departments of Chemistry and Physics and AstronomyUniversity of Southern CaliforniaLos Angeles CA 90089 USA;</p> <p>Department of Mechanical Engineering and Materials ScienceUniversity of PittsburghPittsburgh PA 15261 USA;</p> <p>ICQD/Hefei National Laboratory for Physical Sciences at the MicroscaleUniversity of Science and Technology of ChinaHefei Anhui 230026 China;</p> <p>Departments of Chemistry and Physics and AstronomyUniversity of Southern CaliforniaLos Angeles CA 90089 USA;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1188.html" title="应用化学">应用化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=all-inorganic perovskites&option=203" rel="nofollow">all-inorganic perovskites;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=defects&option=203" rel="nofollow">defects;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=electron–phonon coupling&option=203" rel="nofollow">electron–phonon coupling;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=nonradiative recombination&option=203" rel="nofollow">nonradiative recombination;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=DFT calculations&option=203" rel="nofollow">DFT calculations;</a> </p> <div class="translation"> 机译：全无机钙钛矿;缺陷;电子 - 声子耦合;非接种性重组;DFT计算; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704028162193.html">Soft Lattice and Defect Covalency Rationalize Tolerance of β‐CsPbI3 Perovskite Solar Cells to Native Defects</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Chu Weibin&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Chu Weibin,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Saidi Wissam A.&option=202" target="_blank" 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target="_blank" rel="nofollow" class="tuijian_authcolor"> . 计算机技术与发展 </a> </span> <span> . 2015</span><span>,第002期</span> </span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/academic-journal-cn_acta-physico-chimica-sinica_thesis/0201288944768.html">卤化钙钛矿太阳能电池的缺陷容忍及缺陷钝化研究进展</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=尹媛&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 尹媛</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=郭振东&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,郭振东</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=陈高远&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,陈高远</a> <span> <a href="/journal-cn-15102/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 物理化学学报 </a> </span> <span> . 2021</span><span>,第004期</span> </span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/academic-journal-cn_journal-chengde-medical-college_thesis/0201243884767.html">灭活的啤酒酵母原生质体与营养缺陷型啤酒酵母原生质体的融合</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=安海谦&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 安海谦</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=莫冀湘&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,莫冀湘</a> <span> <a href="/journal-cn-6475/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 承德医学院学报 </a> </span> <span> . 1994</span><span>,第002期</span> </span> </div> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-journal-cn_detail_thesis/0201292839909.html">钙稀土氟碳酸盐矿物中不同多型体间共晶格取向连生的微结构研究</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=吴秀玲&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 吴秀玲</a> <a 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