Ni(COD)(DQ): An Air‐Stable 18‐Electron Nickel(0)–Olefin Precatalyst

Tran Van T.; Li Zi‐Qi; Apolinar Omar; Derosa Joseph; Joannou Matthew V.; Wisniewski Steven R.; Eastgate Martin D.; Engle Keary M.

摘要

Abstract >We report that Ni(COD)(DQ) (COD=1,5‐cyclooctadiene, DQ=duroquinone), an air‐stable 18‐electron complex originally described by Schrauzer in 1962, is a competent precatalyst for a variety of nickel‐catalyzed synthetic methods from the literature. Due to its apparent stability, use of Ni(COD)(DQ) as a precatalyst allows reactions to be conveniently performed without use of an inert‐atmosphere glovebox, as demonstrated across several case studies. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> >我们报告说Ni（COD）（DQ）（COD = 1,5-环辛二烯，DQ = DUROQUINONE），1962年最初由Schrauzer最初描述的空气稳定的18个电子综合体，是各种竞争力的预催化剂来自文献的镍催化的合成方法。由于其表观稳定性，使用Ni（COD）（DQ）作为预催化剂允许在不使用惰性气氛手套箱的情况下方便地进行反应，如在几种情况下所示。</ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-19011/'>《Angewandte Chemie》</a> <b style="margin: 0 2px;">|</b><span>2020年第19期</span><b style="margin: 0 2px;">|</b><span>共5页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Tran Van T.&option=202" target="_blank" rel="nofollow">Tran Van T.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Li Zi‐Qi&option=202" target="_blank" rel="nofollow">Li Zi‐Qi;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Apolinar Omar&option=202" target="_blank" rel="nofollow">Apolinar Omar;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Derosa Joseph&option=202" target="_blank" rel="nofollow">Derosa Joseph;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Joannou Matthew V.&option=202" target="_blank" rel="nofollow">Joannou Matthew V.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wisniewski Steven R.&option=202" target="_blank" rel="nofollow">Wisniewski Steven R.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Eastgate Martin D.&option=202" target="_blank" rel="nofollow">Eastgate Martin D.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Engle Keary M.&option=202" target="_blank" rel="nofollow">Engle Keary M.;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Department of ChemistryThe Scripps Research Institute10550 North Torrey Pines Road La Jolla CA 92037 USA;</p> <p>Department of ChemistryThe Scripps Research Institute10550 North Torrey Pines Road La Jolla CA 92037 USA;</p> <p>Department of ChemistryThe Scripps Research Institute10550 North Torrey Pines Road La Jolla CA 92037 USA;</p> <p>Department of ChemistryThe Scripps Research Institute10550 North Torrey Pines Road La Jolla CA 92037 USA;</p> <p>Chemical &</p> <p>Synthetic DevelopmentBristol-Myers Squibb1 Squibb Drive New Brunswick NJ 08903 USA;</p> <p>Chemical &</p> <p>Synthetic DevelopmentBristol-Myers Squibb1 Squibb Drive New Brunswick NJ 08903 USA;</p> <p>Chemical &</p> <p>Synthetic DevelopmentBristol-Myers Squibb1 Squibb Drive New Brunswick NJ 08903 USA;</p> <p>Department of ChemistryThe Scripps Research Institute10550 North Torrey Pines Road La Jolla CA 92037 USA;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1188.html" title="应用化学">应用化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=cross-coupling&option=203" rel="nofollow">cross-coupling;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=homogeneous catalysis&option=203" rel="nofollow">homogeneous catalysis;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=nickel&option=203" rel="nofollow">nickel;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=precatalysts&option=203" rel="nofollow">precatalysts;</a> </p> <div class="translation"> 机译：交叉偶联;均匀催化;镍;催化剂; 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