Polyhalogen and Polyinterhalogen Anions from Fluorine to Iodine

摘要

Abstract >This Review deals with the evolving field of polyhalogen chemistry, specifically polyhalogen anions (polyhalides). In addition to a historical outline, current progress in synthetic approaches towards the formation of polyfluorides, polychlorides, polybromides, and polyinterhalides is also illustrated. The structural diversity of polyhalides has substantially increased in the past decade, especially for polychlorides and polybromides, which are commonly characterized by single‐crystal X‐ray diffraction, Raman spectroscopy, and quantum‐chemical calculations. Polyfluorides have been examined by sophisticated state‐of‐the‐art quantum‐chemical calculations and investigated spectroscopically in noble gas matrix‐isolation experiments under cryogenic conditions at 4?K. The bonding in such polyhalide systems is also discussed. The last Section deals with applications of polyhalides in halogenation reactions and electrochemistry as well as their use as reactive ionic liquids, emphasizing the promising future of polyhalogen chemistry. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> 本综述涉及多卤素化学的不断变化的领域，特别是聚卤代孔（多卤化物）。除了历史概述之外，还示出了朝向形成多金氟化物，聚氯化物，多溴体和聚硝基磷酸的合成方法的电流进展。多卤化物的结构多样性在过去十年中显着增加，特别是对于聚氯化物和多溴化物，其通常是单晶X射线衍射，拉曼光谱和量子化学计算的特征。已经通过复杂的最新量子化学计算检查了多氟醚，并在低温条件下在4〜K下在低惰性气体基质隔离实验中进行光谱术。还讨论了这种多晶硅体系中的键合。最后一段涉及聚卤化物在卤化反应和电化学中的应用以及它们用作反应性离子液体，强调多卤素化学的未来。</ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-19011/'>《Angewandte Chemie》</a> <b style="margin: 0 2px;">|</b><span>2020年第14期</span><b style="margin: 0 2px;">|</b><span>共30页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1188.html" title="应用化学">应用化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=halogen chemistry&option=203" rel="nofollow">halogen chemistry;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=halogenation&option=203" rel="nofollow">halogenation;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=interhalogen anions&option=203" rel="nofollow">interhalogen anions;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=interhalogen chemistry&option=203" rel="nofollow">interhalogen chemistry;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=polyhalogen anions&option=203" rel="nofollow">polyhalogen anions;</a> </p> <div class="translation"> 机译：卤素化学;卤化;搅拌阴离子;苯卤代化学;多卤素阴离子; 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using zirconium hydroxide as anion exchanger</a> <b>[P]</b> . <span> 外国专利：  EP0987221B1 </span> <span> . 2007-01-03</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：通过使用氢氧化锆作为阴离子交换剂通过阴离子交换除去碘和/或硅酸盐阴离子来纯化用于电解的盐溶液的方法 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130424874984.html">FLOW CELL, APPARATUS FOR CONCENTRATING RADIOACTIVE FLUORINE ANION, AND METHOD OF CONCENTRATING RADIOACTIVE FLUORINE ANION</a> <b>[P]</b> . <span> 外国专利：  EP2204233B1 </span> <span> . 2011-11-09</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：流动池，用于浓缩放射性氟阴离子的装置以及用于浓缩放射性氟阴离子的方法 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130424874985.html">FLOW CELL, APPARATUS FOR 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