Confined Crystallization of Spin‐Crossover Nanoparticles in Block‐Copolymer Micelles

摘要

Abstract > Nanoparticles of the spin‐crossover coordination polymer [FeL(bipy)] <sub> n </sub> were synthesized by confined crystallization within the core of polystyrene‐ block ‐poly(4‐vinylpyridine) (PS‐ b ‐P4VP) diblock copolymer micelles. The 4VP units in the micellar core act as coordination sites for the Fe complex. In the bulk material, the spin‐crossover nanoparticles in the core are well isolated from each other allowing thermal treatment without disintegration of their structure. During annealing above the glass transition temperature of the PS block, the transition temperature is shifted gradually to higher temperatures from the as‐synthesized product ( T <sub>1/2</sub> ↓=163?K and T <sub>1/2</sub> ↑=170?K) to the annealed product ( T <sub>1/2</sub> ↓=203?K and T <sub>1/2</sub> ↑=217?K) along with an increase in hysteresis width from 6?K to 14?K. Thus, the spin‐crossover properties can be shifted towards the properties of the related bulk material. The stability of the nanocomposite allows further processing, such as electrospinning from solution. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 旋转交叉配角纳米颗粒[FEL（Bipy）] <sub> n </ i> </ sub> 通过聚苯乙烯核心内的狭窄结晶合成 - 块</ i> - 聚（4-乙烯基吡啶）（ps- b </ i> -P4VP）二嵌段共聚物胶束。胶束核心的4VP单元作为Fe复合物的配位位点。在散装材料中，芯中的旋转交叉纳米颗粒彼此均匀分离，允许热处理而不会崩解它们的结构。在退火期间，在PS块的玻璃化转变温度之上，过渡温度逐渐移位，以较高的优选产品（ t </ i> <sub> 1/2 </ sub> ↓= 163？k和 t </ i> <sub> 1/2 </ sub> ↑= 170？k）到退火产品（ t </ i> <sub> 1/2 </ sub> ↓= 203？k和 t </ i> <sub> 1/2 </ sub> ↑= 217？k）以及从6Ωk到14 k的滞后宽度的增加。因此，旋转交叉特性可以朝向相关散装材料的性质转移。纳米复合材料的稳定性允许进一步加工，例如静电纺丝。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-19011/'>《Angewandte Chemie》</a> <b style="margin: 0 2px;">|</b><span>2020年第14期</span><b style="margin: 0 2px;">|</b><span>共6页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1188.html" title="应用化学">应用化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=block copolymers&option=203" rel="nofollow">block copolymers;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=composite materials&option=203" rel="nofollow">composite materials;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=electrospinning&option=203" rel="nofollow">electrospinning;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=nanoparticles&option=203" rel="nofollow">nanoparticles;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=spin crossover&option=203" rel="nofollow">spin crossover;</a> </p> <div class="translation"> 机译：嵌段共聚物;复合材料;静电纺丝;纳米颗粒;旋转交叉; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704028161939.html">Confined Crystallization of Spin‐Crossover Nanoparticles in Block‐Copolymer Micelles</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> </a> <a href="/journal-foreign-19011/" target="_blank" rel="nofollow" class="tuijian_authcolor">Angewandte Chemie .</a> <span>2020</span><span>,第14期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：嵌段 - 共聚物胶束中旋转交叉纳米粒子的狭窄结晶</span> </p> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704019896818.html">Uniform Polyselenophene Block Copolymer Fiberlike Micelles and Block Co-micelles via Living Crystallization-Driven Self-Assembly</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Emily L. 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