Enabling High‐Voltage Lithium Metal Batteries by Manipulating Solvation Structure in Ester Electrolyte

Jie Yulin; Liu Xiaojing; Lei Zhanwu; Wang Shiyang; Chen Yawei; Huang Fanyang; Cao Ruiguo; Zhang Genqiang; Jiao Shuhong

摘要

Abstract > Lithium metal is an ideal electrode material for future rechargeable lithium metal batteries. However, the widespread deployment of metallic lithium anode is significantly hindered by its dendritic growth and low Coulombic efficiency, especially in ester solvents. Herein, by rationally manipulating the electrolyte solvation structure with a high donor number solvent, enhancement of the solubility of lithium nitrate in an ester‐based electrolyte is successfully demonstrated, which enables high‐voltage lithium metal batteries. Remarkably, the electrolyte with a high concentration of LiNO <sub>3</sub> additive presents an excellent Coulombic efficiency up to 98.8?% during stable galvanostatic lithium plating/stripping cycles. A full‐cell lithium metal battery with a lithium nickel manganese cobalt oxide cathode exhibits a stable cycling performance showing limited capacity decay. This approach provides an effective electrolyte manipulation strategy to develop high‐voltage lithium metal batteries. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 锂金属是未来可充电锂金属电池的理想电极材料。然而，金属锂阳极的广泛展开通过其树枝状生长和低库仑效率而显着阻碍，特别是在酯溶剂中。这里，通过合理操纵具有高供体数溶剂的电解质溶剂化结构，成功地证明了硝酸锂溶解度在酯基电解质中的增强，这使得能够高压锂金属电池。值得注意的是，具有高浓度的LINO的电解质 <sub> 3 </ sub> 添加剂在稳定的电镀锂电镀/汽提循环期间呈现出高达98.8Ω％的优异的库仑效率。具有锂镍锰钴氧化物阴极的全细胞锂金属电池表现出稳定的循环性能，显示出有限的容量衰减。该方法提供了一种有效的电解质操纵策略来开发高压锂金属电池。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-19011/'>《Angewandte Chemie》</a> <b style="margin: 0 2px;">|</b><span>2020年第9期</span><b style="margin: 0 2px;">|</b><span>共6页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Jie Yulin&option=202" target="_blank" rel="nofollow">Jie Yulin;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Liu Xiaojing&option=202" target="_blank" rel="nofollow">Liu Xiaojing;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Lei Zhanwu&option=202" target="_blank" rel="nofollow">Lei Zhanwu;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wang Shiyang&option=202" target="_blank" rel="nofollow">Wang Shiyang;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Chen Yawei&option=202" target="_blank" rel="nofollow">Chen Yawei;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Huang Fanyang&option=202" target="_blank" rel="nofollow">Huang Fanyang;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Cao Ruiguo&option=202" target="_blank" rel="nofollow">Cao Ruiguo;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhang Genqiang&option=202" target="_blank" rel="nofollow">Zhang Genqiang;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Jiao Shuhong&option=202" target="_blank" rel="nofollow">Jiao Shuhong;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Hefei National Laboratory for Physical Science at the MicroscaleUniversity of Science and Technology of ChinaHefei 230026 P.R. China;</p> <p>Hefei National Laboratory for Physical Science at the MicroscaleUniversity of Science and Technology of ChinaHefei 230026 P.R. China;</p> <p>Hefei National Laboratory for Physical Science at the MicroscaleUniversity of Science and Technology of ChinaHefei 230026 P.R. China;</p> <p>Hefei National Laboratory for Physical Science at the MicroscaleUniversity of Science and Technology of ChinaHefei 230026 P.R. China;</p> <p>Hefei National Laboratory for Physical Science at the MicroscaleUniversity of Science and Technology of ChinaHefei 230026 P.R. China;</p> <p>Hefei National Laboratory for Physical Science at the MicroscaleUniversity of Science and Technology of ChinaHefei 230026 P.R. China;</p> <p>Hefei National Laboratory for Physical Science at the MicroscaleUniversity of Science and Technology of ChinaHefei 230026 P.R. China;</p> <p>Hefei National Laboratory for Physical Science at the MicroscaleUniversity of Science and Technology of ChinaHefei 230026 P.R. China;</p> <p>Hefei National Laboratory for Physical Science at the MicroscaleUniversity of Science and Technology of ChinaHefei 230026 P.R. China;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1188.html" title="应用化学">应用化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=electrode materials&option=203" rel="nofollow">electrode materials;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=high voltage&option=203" rel="nofollow">high voltage;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=lithium metal batteries&option=203" rel="nofollow">lithium metal batteries;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=lithium solvate sheath&option=203" rel="nofollow">lithium solvate sheath;</a> </p> <div class="translation"> 机译：电极材料;高压;锂金属电池;锂溶剂化物护套; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704028161829.html">Enabling High‐Voltage Lithium Metal Batteries by Manipulating Solvation Structure in Ester Electrolyte</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Jie Yulin&option=202" target="_blank" rel="nofollow" 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<span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . </a> <span> <a href="/journal-cn-9187/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 山东陶瓷 </a> </span> <span> . 2018</span><span>,第4期</span> </span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/academic-journal-cn_chinese-journal-power-sources_thesis/0201275597621.html">无机固体电解质用于锂及锂离子蓄电池的研究进展Ⅱ玻璃态锂无机固体电解质</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=郑洪河&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 郑洪河</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=曲群婷&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,曲群婷</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=石静&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,石静</a> <span> <a href="/journal-cn-8483/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 电源技术 </a> </span> <span> . 2007</span><span>,第012期</span> </span> </div> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-journal-cn_chinese-journal-power-sources_thesis/0201264394809.html">无机固体电解质用于锂及锂离子电池研究进展——Ⅰ锂陶瓷电解质</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=郑洪河&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 郑洪河</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=曲群婷&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,曲群婷</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=刘云伟&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,刘云伟</a> <span> <a href="/journal-cn-8483/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 电源技术 </a> </span> <span> . 2007</span><span>,第005期</span> </span> 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href="/academic-conference-cn_meeting-31994_thesis/02022487736.html">锂电池电解质溶液中锂离子溶剂化的光谱研究*</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王键吉&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 王键吉</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=轩小朋&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,轩小朋</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=卢锦梭&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,卢锦梭</a> <span> <a href="/conference-cn-31994/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 中国化学会2000年学术会议 </a> <span> <span> . 2000</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020315856351.html">环状碳酸酯基聚合物电解质在高电压锂金属电池中的应用研究</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=胡容祥&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 胡容祥</a> <span> . 2020</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06120111841020.html">一种高压聚合物电解质、高压聚合物锂金属电池及此电池的制备方法</a> <b>[P]</b> . <span> 中国专利： CN111786018A </span> <span> . 2020-10-16</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120113937506.html">一种用于高压锂金属电池的醚酯混合电解液及其应用</a> <b>[P]</b> . <span> 中国专利： CN114024022A </span> <span> . 2022-02-08</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130499915584.html">LIQUID AND SOLID ELECTROLYTES WITH LITHIUM-FLUORINE SOLVATION STRUCTURE FOR LITHIUM BATTERIES</a> <b>[P]</b> . <span> 外国专利：  WO2021086485A1 </span> <span> . 2021-05-06</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: 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