Capturing the Monomeric (L)CuH in NHC‐Capped Cyclodextrin: Cavity‐Controlled Chemoselective Hydrosilylation of α,β‐Unsaturated Ketones

Xu Guangcan; Leloux Sébastien; Zhang Pinglu; Meijide Suárez Jorge; Zhang Yongmin; Derat Etienne; Ménand Micka?l; Bistri‐Aslanoff Olivia; Roland Sylvain; Leyssens Tom; Riant Olivier; Sollogoub Matthieu

摘要

Abstract > The encapsulation of copper inside a cyclodextrin capped with an N ‐heterocyclic carbene (ICyD) allowed both to catch the elusive monomeric (L)CuH and a cavity‐controlled chemoselective copper‐catalyzed hydrosilylation of α,β‐unsaturated ketones. Remarkably, (α‐ICyD)CuCl promoted the 1,2‐addition exclusively, while (β‐ICyD)CuCl produced the fully reduced product. The chemoselectivity is controlled by the size of the cavity and weak interactions between the substrate and internal C?H bonds of the cyclodextrin. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 环糊精内铜的封装用一个 n </ i> - 允许α，β-不饱和酮的均捕获难以捉摸的单体（L）CUH和腔控制的化学选择性铜催化氢硅烷化的α，β-不饱和酮。值得注意的是，（α-ICYD）CuCl专门促进了1,2-添加，而（β-ICYD）CuCl产生完全降低的产品。通过腔体的尺寸和基材与环糊精的内部C-H键之间的腔体和弱相互作用来控制化学选择性。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-19011/'>《Angewandte Chemie》</a> <b style="margin: 0 2px;">|</b><span>2020年第19期</span><b style="margin: 0 2px;">|</b><span>共7页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Xu Guangcan&option=202" target="_blank" rel="nofollow">Xu Guangcan;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Leloux Sébastien&option=202" target="_blank" rel="nofollow">Leloux Sébastien;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhang Pinglu&option=202" target="_blank" rel="nofollow">Zhang Pinglu;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Meijide Suárez Jorge&option=202" target="_blank" rel="nofollow">Meijide Suárez Jorge;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhang Yongmin&option=202" target="_blank" rel="nofollow">Zhang Yongmin;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Derat Etienne&option=202" target="_blank" rel="nofollow">Derat Etienne;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ménand Micka?l&option=202" target="_blank" rel="nofollow">Ménand Micka?l;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Bistri‐Aslanoff Olivia&option=202" target="_blank" rel="nofollow">Bistri‐Aslanoff Olivia;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Roland Sylvain&option=202" target="_blank" rel="nofollow">Roland Sylvain;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Leyssens Tom&option=202" target="_blank" rel="nofollow">Leyssens Tom;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Riant Olivier&option=202" target="_blank" rel="nofollow">Riant Olivier;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Sollogoub Matthieu&option=202" target="_blank" rel="nofollow">Sollogoub Matthieu;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>CNRSSorbonne Université4 place Jussieu 75005 Paris France;</p> <p>Institute of Condensed Matter and Nanosciences (IMCN) Molecules Solids and Reactivity (MOST)Université Catholique de Louvain (UCL)Place Louis Pasteur 1 1348 Louvain-La-Neuve Belgium;</p> <p>CNRSSorbonne Université4 place Jussieu 75005 Paris France;</p> <p>CNRSSorbonne Université4 place Jussieu 75005 Paris France;</p> <p>CNRSSorbonne Université4 place Jussieu 75005 Paris France;</p> <p>CNRSSorbonne Université4 place Jussieu 75005 Paris France;</p> <p>CNRSSorbonne Université4 place Jussieu 75005 Paris France;</p> <p>CNRSSorbonne Université4 place Jussieu 75005 Paris France;</p> <p>CNRSSorbonne Université4 place Jussieu 75005 Paris France;</p> <p>Institute of Condensed Matter and Nanosciences (IMCN) Molecules Solids and Reactivity (MOST)Université Catholique de Louvain (UCL)Place Louis Pasteur 1 1348 Louvain-La-Neuve Belgium;</p> <p>Institute of Condensed Matter and Nanosciences (IMCN) Molecules Solids and Reactivity (MOST)Université Catholique de Louvain (UCL)Place Louis Pasteur 1 1348 Louvain-La-Neuve Belgium;</p> <p>CNRSSorbonne Université4 place Jussieu 75005 Paris France;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1188.html" title="应用化学">应用化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=cavities&option=203" rel="nofollow">cavities;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=copper hydride&option=203" rel="nofollow">copper hydride;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=cyclodextrins&option=203" rel="nofollow">cyclodextrins;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=hydrosilylation&option=203" rel="nofollow">hydrosilylation;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=N-heterocyclic carbenes&option=203" rel="nofollow">N-heterocyclic carbenes;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=α&option=203" rel="nofollow">α;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=β-unsaturated ketones&option=203" rel="nofollow">β-unsaturated ketones;</a> </p> <div class="translation"> 机译：腔;铜氢化物;环糊精;氢化硅烷化;N-杂环碳;α;β-不饱和酮; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704028161799.html">Capturing the Monomeric (L)CuH in NHC‐Capped Cyclodextrin: Cavity‐Controlled Chemoselective Hydrosilylation of α,β‐Unsaturated Ketones</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Xu Guangcan&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Xu Guangcan,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Leloux Sébastien&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Leloux Sébastien,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhang Pinglu&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Zhang Pinglu,</a> <a href="/journal-foreign-19011/" target="_blank" rel="nofollow" class="tuijian_authcolor">Angewandte Chemie .</a> <span>2020</span><span>,第19期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：在NHC封端的环糊精中捕获单体（L）CUH：腔控制的α，β-不饱和酮的腔控制化学选择性氢化物。</span> </p> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/academic-journal-foreign_organic-and-biomolecular-chemistry_thesis/0204111651089.html">Origins of enantioselectivity in the chiral diphosphine-ligated CuH-catalyzed asymmetric hydrosilylation of ketones</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wei Zhang&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Wei Zhang,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Weiyi Li&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Weiyi Li,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Song Qin&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Song Qin </a> <a href="/journal-foreign-696/" target="_blank" rel="nofollow" class="tuijian_authcolor">Organic & biomolecular chemistry .</a> <span>2012</span><span>,第3期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：手性二膦连接的CuH催化酮的不对称氢化硅烷化中对映选择性的起源</span> </p> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704018708895.html">Nonracemic diarylmethanols from CuH-Catalyzed hydrosilylation of diaryl ketones</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Lee CT&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Lee CT,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Lipshutz BH&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Lipshutz BH </a> <a href="/journal-foreign-27730/" target="_blank" rel="nofollow" class="tuijian_authcolor">Organic letters .</a> <span>2008</span><span>,第19期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：CuH催化的二芳基酮氢化硅烷化的非外消旋二芳基甲醇</span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-conference-foreign_meeting-289074_thesis/0705017514104.html">Chemoselective olefin/ketone hydrosilylation catalyzed by Fe or Co complexes bearing an iminobipyridine ligand</a> <b>[C]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Katsuaki Kobayashi&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Katsuaki Kobayashi </a> <a href="/conference-foreign-289074/" target="_blank" rel="nofollow" class="tuijian_authcolor">日本化学会春季年会講演予稿集 .</a> <span>2018</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：由含有伊尼诺吡啶配体的Fe或Co复合物催化的化学选择性烯烃/酮氢化硅烷化</span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-degree-foreign_mphd_thesis/02061434169.html">I. Chemoselective catalytic hydrogenation of alpha, beta-unsaturated aldehydes and ketones using soluble copper(I) hydrides II. Free radical alkylation of titanium(III) allyl and propargyl complexes.</a> <b>[D] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Chen, Jianxian.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Chen, Jianxian. </a> <span>1999</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：I.使用可溶的氢化铜（I）对α，β-不饱和醛和酮进行化学选择性催化氢化。钛（III）烯丙基和炔丙基复合物的自由基烷基化。</span> </p> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-journal-foreign-pmc_detail_thesis/040005929485.html">CuH-Catalyzed Enantioselective 12-Reductions of αβ-Unsaturated Ketones</a> <b>[O] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ralph Moser&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Ralph Moser,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Žarko V. Bošković&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Žarko V. Bošković,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Christopher S. Crowe&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Christopher S. Crowe,</a> <span>-1</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：CUH催化对映选择性α12-削减β不饱和酮</span> </p> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/open-access_resources_thesis/0100016645005.html">Orthometallation of N-substituents at the NHC ligand of Rh(Cl)(COD)(NHC) complexes: its role in the catalytic hydrosilylation of ketones</a> <b>[O] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Lázaro Guillermo&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Lázaro Guillermo,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Fernández-Álvarez Francisco J.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Fernández-Álvarez Francisco J.,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Munárriz Julen&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Munárriz Julen,</a> <span>2016</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：Rh（Cl）（COD）（NHC）配合物NHC配体上N-取代基的正金属化：其在酮的催化氢化硅烷化中的作用</span> </p> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/academic-journal-cn_chinese-journal-catalysis_thesis/0201276411602.html">甲醇为氢源:Rhodacycle催化α,β-不饱和酮化学选择性转移加氢反应</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ahmed H. Aboo&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . Ahmed H. Aboo</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Robina Begum&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,Robina Begum</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Liangliang Zhao&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,Liangliang Zhao</a> <span> <a href="/journal-cn-28399/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 催化学报 </a> </span> <span> . 2019</span><span>,第011期</span> </span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/academic-journal-cn_detail_thesis/0201296789607.html">气相捕获腔对石墨烯低压化学气相沉积形核生长的影响</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=史永贵&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 史永贵</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=桑昭君&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,桑昭君</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王允威&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,王允威</a> <span> <a href="/journal-cn-56955/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 人工晶体学报 </a> </span> <span> . 2020</span><span>,第3期</span> </span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/academic-journal-cn_industrial-heating_thesis/0201228368830.html">气压控制系统在铜连铸保温炉铸造腔液面控制中的应用</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=张晓枫&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 张晓枫</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=陈惠军&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,陈惠军</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李庆文&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,李庆文</a> <span> <a href="/journal-cn-8389/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 工业加热 </a> </span> <span> . 2008</span><span>,第003期</span> </span> </div> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-journal-cn_detail_thesis/0201297323261.html">基于操作腔外原子比特控制腔内原子比特相干性时间演化</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=周并举&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 周并举</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=彭朝晖&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,彭朝晖</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=刘小娟&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,刘小娟</a> <span> <a href="/journal-cn-56962/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 光子学报 </a> </span> <span> . 2014</span><span>,第8期</span> </span> </div> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-journal-cn_detail_thesis/0201297769064.html">基于腔反射光控制的腔衰荡光谱测量实验研究</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李志新&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 李志新</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=付小芳&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,付小芳</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=谭巍&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,谭巍</a> <span> <a href="/journal-cn-57454/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 大气与环境光学学报 </a> </span> <span> . 2012</span><span>,第6期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-65361_thesis/020222945553.html">盐穴储气库造腔过程盐腔形态工艺控制方法</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=孙春柳&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 孙春柳</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=丁国生&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,丁国生</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=完颜祺琪&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,完颜祺琪</a> <span> <a href="/conference-cn-65361/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 2017年全国天然气学术年会 </a> <span> <span> . 2017</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020315569103.html">酮咯酸关节腔注射对膝关节镜术后疼痛控制影响的随机对照试验meta分析</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=万锐杰&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 万锐杰</a> <span> . 2020</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/061201672190.html">六苯基封端单体、制备方法及在制备六苯环封端聚醚酮中的应用</a> <b>[P]</b> . <span> 中国专利： CN104003861B </span> <span> . 2015.06.03</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120102630433.html">六苯基封端单体、制备方法及在制备六苯环封端聚醚酮中的应用</a> <b>[P]</b> . <span> 中国专利： CN104003861A </span> <span> . 2014-08-27</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130448657774.html">Unsaturated ketones as accelerators for hydrosilylation</a> <b>[P]</b> . <span> 外国专利：  EP0709390B1 </span> <span> . 2000-11-15</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：不饱和酮作为氢化硅烷化促进剂 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130457120368.html">Unsaturated ketones as accelerators for hydrosilylation</a> <b>[P]</b> . <span> 外国专利：  EP0709390A1 </span> <span> . 1996-05-01</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：不饱和酮作为氢化硅烷化促进剂 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130490440640.html">at room temperature with ketone peroxides in the presence of cobaltkatalysatorer to non grønfarvede formstoffer hærdelige mixtures of unsaturated polyesters and tilpolymeriserbare,monomeric ethylenisk</a> <b>[P]</b> . <span> 外国专利：  DK99901C </span> <span> . 1964-09-28</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：在室温下，在过氧化钴的存在下，在钴方解胺的存在下，转化为非grønfarvede形式，以饱和不饱和聚酯和缩聚物的混合物，单体烯 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" onclick="ywcd('0704028161799','4',7,2,1,'',this,24)" class="delivery" prompt="010401" title="通过人工服务将文献原文发送至邮箱" >获取原文</div> <div class="journalsub-pop-up" style="display: none"> <div class="journal-sub"> <h2>期刊订阅</h2> <img src="https://cdn.zhangqiaokeyan.com/img/loginclose.png" alt="关闭" onclick="$('.journalsub-pop-up').hide()"> <p class="pardon">抱歉，该期刊暂不可订阅，敬请期待！</p> <p class="current">目前支持订阅全部北京大学中文核心（2020）期刊目录。</p> <div style="display: flex;margin-top: 69px;justify-content: space-between;"> <div class="no-sub" onclick="$('.journalsub-pop-up').hide()">暂不订阅</div> <div class="other-sub" onclick="continueSub('from=pc-detail')">继续订阅其他期刊</div> </div> </div> </div> <div class="right_btn"> <ul> <li class="gouwuche">  </li> <li class="yijian"> <a href="javascript:void(0);" onclick="link_analysis('/mycenter/auth/complaint.html',this)" title="意见反馈">意见反馈</a> </li> <li class="top"> <a href="javascript:scrollTo(0,0);" title="回到顶部">回到顶部</a> </li> <li class="shouye"> <a href="/" title="首页">回到首页</a> </li> </ul> </div> <div class="xllindexfooter"> <div class="xllindexfootercenter"> <div class="xllindexfooterleft left" > <div class="xllindexfooterleftli"> <ul> <li><a href="/about.html" title="关于掌桥">关于掌桥</a></li> <li><a href="/help/helpmap.html" title="资源导航">资源导航</a></li> <li><a href="/help/helpguide.html" title="新手指南">新手指南</a></li> <li><a href="/help/helpcenter.html" title="常见问题">常见问题</a></li> <li><a href="/sitemap.html" title="网站地图">网站地图</a></li> <li><a href="/help/helpcenter.html?type=9" title="版权声明">版权声明</a></li> </ul> </div> <div class="xllindexfooterleft"> <p class="xllindexfooterlefteamil">客服邮箱：kefu@zhangqiaokeyan.com</p> <div class="xllindexfooterlefttcp"> <div class="xllindexfooterpoliceiimg"></div> <div class="xllindexfooterpoliceispan"> <span>京公网安备：11010802029741号 </span> <span>ICP备案号：<a href="https://beian.miit.gov.cn" rel="nofollow" target="_blank" title="ICP备案号">京ICP备15016152号-6</a></span> <span>六维联合信息科技 (北京) 有限公司©版权所有</span> </div> </div> </div> </div> <div class="xllindexfooterright left"> <ul> <li> <p style="font-weight: bold;">客服微信</p> <div></div> </li> <li> <p style="font-weight: bold;">服务号</p> <div></div> </li> </ul> </div> </div> </div> <span id="0704028161799down" data-source="7," data-out-id="nXkFMavjMZQ7ZNjegeYs7QxfHqMwslwxSKrzG96bLhJvAVwpEKI2fdB2+qLrR9rS," data-f-source-id="7" data-title="Capturing the Monomeric (L)CuH in NHC‐Capped Cyclodextrin: Cavity‐Controlled Chemoselective Hydrosilylation of α,β‐Unsaturated Ketones" data-price="20" data-site-name="" data-transnum="24" style="display:none;"></span> <input type="hidden" value="4" id="sourcetype"> <input type="hidden" value="19011" id="journalid"> <input type="hidden" value="1" id="inyn_provide_service_level"> <input type="hidden" value="https://cdn.zhangqiaokeyan.com" id="imgcdn"> <input type="hidden" value="1" id="isdeatail"> <input type="hidden" value="" id="syyn_indexed_database"> <input type="hidden" value="" id="servicetype"> <input type="hidden" id="pagename" value="Capturing the Monomeric (L)CuH in NHC‐Capped Cyclodextrin: Cavity‐Controlled Chemoselective Hydrosilylation of α,β‐Unsaturated Ketones"/> <input type="hidden" value="thesis_get_original" id="pageIdentification"> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/jquery-1.12.4.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/lwlh_ajax.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/zq.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/common.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/jquery.cookie.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/top.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/tip.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/login.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/down.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/search.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/newmail.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/searchtype.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/user/regist.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/zxs_solor/detail.js?v=5.7.8"></script> <script type="text/javascript" src="https://www.zhangqiaokeyan.com/statistics/static/pagecollection.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/tj.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/sse.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/pushbaidu.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/history.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/util/cookie.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/weipu/weipu.js?v=5.7.8"></script> </body> <script> $(function(){ var weiPuStatus = getCookie('WeiPuStatus'); if(weiPuStatus){ tipWeiPuStatus(weiPuStatus); delCookie('WeiPuStatus'); } getFacetKeywordVoInId(); var sourcetype = $("#sourcetype").val(); var inyn_provide_service_level = $("#inyn_provide_service_level").val(); if((sourcetype ==1||sourcetype==4)&&inyn_provide_service_level!=4){ getJournal(); } }) </script> </html>