Combined Intrinsic and Extrinsic Proton Conduction in Robust Covalent Organic Frameworks for Hydrogen Fuel Cell Applications

Yang Yi; He Xueyi; Zhang Penghui; Andaloussi Yassin H.; Zhang Hailu; Jiang Zhongyi; Chen Yao; Ma Shengqian; Cheng Peng; Zhang Zhenjie

摘要

Abstract > Developing new materials for the fabrication of proton exchange membranes (PEMs) for fuel cells is of great significance. Herein, a series of highly crystalline, porous, and stable new covalent organic frameworks (COFs) have been developed by a stepwise synthesis strategy. The synthesized COFs exhibit high hydrophilicity and excellent stability in strong acid or base (e.g., 12? <sc>m</sc> NaOH or HCl) and boiling water. These features make them ideal platforms for proton conduction applications. Upon loading with H <sub>3</sub> PO <sub>4</sub> , the COFs (H <sub>3</sub> PO <sub>4</sub> @COFs) realize an ultrahigh proton conductivity of 1.13×10 ?1 ?S?cm ?1 , the highest among all COF materials, and maintain high proton conductivity across a wide relative humidity (40–100?%) and temperature range (20–80?°C). Furthermore, membrane electrode assemblies were fabricated using H <sub>3</sub> PO <sub>4</sub> @COFs as the solid electrolyte membrane for proton exchange resulting in a maximum power density of 81?mW?cm ?2 and a maximum current density of 456?mA?cm ?2 , which exceeds all previously reported COF materials. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 为燃料电池制备质子交换膜（PEMS）的制备新材料具有重要意义。这里，通过逐步合成策略开发了一系列高度结晶，多孔和稳定的新共价有机框架（COF）。合成的COF在强酸或碱中表现出高亲水性和优异的稳定性（例如，12？ <sc> m </ sc> NaOH或HCl）和沸水。这些功能使它们成为质子传导应用的理想平台。加载h后 <sub> 3 </ sub> 宝 <sub> 4 </ sub> ，cofs（h <sub> 3 </ sub> 宝 <sub> 4 </ sub> @cofs）实现了1.13×10的超高型质子电导率？1 </ sup> ？s？cm ？1 </ sup> ，所有COF材料中的最高，并在宽的相对湿度（40-100Ω％）和温度范围内保持高的质子电导率（20-80Ω°C）。此外，使用H制造膜电极组件 <sub> 3 </ sub> 宝 <sub> 4 </ sub> @cofs作为质子交换的固体电解质膜，导致最大功率密度为81Ωmw？cm ？2 </ sup> 最大电流密度为456？ma？cm ？2 </ sup> ，超过所有先前报告的COF材料。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-19011/'>《Angewandte Chemie》</a> <b style="margin: 0 2px;">|</b><span>2020年第9期</span><b style="margin: 0 2px;">|</b><span>共7页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yang Yi&option=202" target="_blank" rel="nofollow">Yang Yi;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=He Xueyi&option=202" target="_blank" rel="nofollow">He Xueyi;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhang Penghui&option=202" target="_blank" rel="nofollow">Zhang Penghui;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Andaloussi Yassin H.&option=202" target="_blank" rel="nofollow">Andaloussi Yassin H.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhang Hailu&option=202" target="_blank" rel="nofollow">Zhang Hailu;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Jiang Zhongyi&option=202" target="_blank" rel="nofollow">Jiang Zhongyi;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Chen Yao&option=202" target="_blank" rel="nofollow">Chen Yao;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ma Shengqian&option=202" target="_blank" rel="nofollow">Ma Shengqian;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Cheng Peng&option=202" target="_blank" rel="nofollow">Cheng Peng;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhang Zhenjie&option=202" target="_blank" rel="nofollow">Zhang Zhenjie;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Renewable energy conversion and storage centerNankai UniversityTianjin 300071 China;</p> <p>School of Chemical Engineering and TechnologyTianjin UniversityTianjin 300072 China;</p> <p>Renewable energy conversion and storage centerNankai UniversityTianjin 300071 China;</p> <p>Department of Chemical Sciences Bernal InstituteUniversity of LimerickLimerick V94 T9PX Republic of Ireland;</p> <p>Suzhou institute of Nano-Tech and Nano-BionicsChinese Academy of SciencesSuzhou 215123 China;</p> <p>School of Chemical Engineering and TechnologyTianjin UniversityTianjin 300072 China;</p> <p>State Key Laboratory of Medicinal Chemical biologyNankai UniversityTianjin 300071 China;</p> <p>Department of ChemistryUniversity of South Florida4202 East Fowler Avenue Tampa FL 33620 USA;</p> <p>Renewable energy conversion and storage centerNankai UniversityTianjin 300071 China;</p> <p>Renewable energy conversion and storage centerNankai UniversityTianjin 300071 China;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1188.html" title="应用化学">应用化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=covalent organic frameworks&option=203" rel="nofollow">covalent organic frameworks;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=fuel cells&option=203" rel="nofollow">fuel cells;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=membranes&option=203" rel="nofollow">membranes;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=multiple-bond linkages&option=203" rel="nofollow">multiple-bond linkages;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=proton conduction&option=203" rel="nofollow">proton conduction;</a> </p> <div class="translation"> 机译：共价有机框架;燃料电池;膜;多键联系;质子传导; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" 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