Dendrite‐Free Sodium Metal Anodes Enabled by a Sodium Benzenedithiolate‐Rich Protection Layer

Zhu Ming; Wang Guanyao; Liu Xing; Guo Bingkun; Xu Gang; Huang Zhongyi; Wu Minghong; Liu Hua‐Kun; Dou Shi‐Xue; Wu Chao

摘要

Abstract > Sodium metal is an ideal anode material for metal rechargeable batteries, owing to its high theoretical capacity (1166?mAh?g ?1 ), low cost, and earth‐abundance. However, the dendritic growth upon Na plating, stemming from unstable solid electrolyte interphase (SEI) film, is a major and most notable problem. Here, a sodium benzenedithiolate (PhS <sub>2</sub> Na <sub>2</sub> )‐rich protection layer is synthesized in?situ on sodium by a facile method that effectively prevents dendrite growth in the carbonate electrolyte, leading to stabilized sodium metal electrodeposition for 400 cycles (800?h) of repeated plating/stripping at a current density of 1?mA?cm ?2 . The organic salt, PhS <sub>2</sub> Na <sub>2</sub> , is found to be a critical component in the protection layer. This finding opens up a new and promising avenue, based on organic sodium slats, to stabilize sodium metals with a protection layer. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 钠金属是用于金属可充电电池的理想阳极材料，由于其高理论能力（1166？MAH？G. ？1 </ sup> ），成本低，土壤丰富。然而，Na电镀后的树突生长，源于不稳定的固体电解质间（SEI）膜，是一个主要和最值得注意的问题。这里，苯二钠酸钠（pH） <sub> 2 </ sub> 纳 <sub> 2 </ sub> ）-RICH保护层通过容易的方法合成钠在钠上的钠中，其有效地防止碳酸盐电解质中的枝晶生长，导致稳定的钠金属电沉积在电流密度的反复电镀/剥离中的400次循环（800·H）。 1？ma？cm ？2 </ sup> 。有机盐，pHS <sub> 2 </ sub> 纳 <sub> 2 </ sub> ，被发现是保护层中的关键组件。这一发现根据有机板条开辟了新的和承诺的大道，以稳定带保护层的钠金属。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-19011/'>《Angewandte Chemie》</a> <b style="margin: 0 2px;">|</b><span>2020年第16期</span><b style="margin: 0 2px;">|</b><span>共5页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhu Ming&option=202" target="_blank" rel="nofollow">Zhu Ming;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wang Guanyao&option=202" target="_blank" rel="nofollow">Wang Guanyao;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Liu Xing&option=202" target="_blank" rel="nofollow">Liu Xing;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Guo Bingkun&option=202" target="_blank" rel="nofollow">Guo Bingkun;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Xu Gang&option=202" target="_blank" rel="nofollow">Xu Gang;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Huang Zhongyi&option=202" target="_blank" rel="nofollow">Huang Zhongyi;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wu Minghong&option=202" target="_blank" rel="nofollow">Wu Minghong;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Liu Hua‐Kun&option=202" target="_blank" rel="nofollow">Liu Hua‐Kun;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Dou Shi‐Xue&option=202" target="_blank" rel="nofollow">Dou Shi‐Xue;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wu Chao&option=202" target="_blank" rel="nofollow">Wu Chao;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>School of Environmental and Chemical EngineeringShanghai UniversityShanghai 200444 China;</p> <p>School of Environmental and Chemical EngineeringShanghai UniversityShanghai 200444 China;</p> <p>School of Environmental and Chemical EngineeringShanghai UniversityShanghai 200444 China;</p> <p>Materials Genome InstituteShanghai UniversityShanghai 200444 China;</p> <p>School of Environmental and Chemical EngineeringShanghai UniversityShanghai 200444 China;</p> <p>School of Environmental and Chemical EngineeringShanghai UniversityShanghai 200444 China;</p> <p>School of Environmental and Chemical EngineeringShanghai UniversityShanghai 200444 China;</p> <p>Institute for Superconducting &</p> <p>Electronic MaterialsUniversity of WollongongWollongong NSW 2522 Australia;</p> <p>Institute for Superconducting &</p> <p>Electronic MaterialsUniversity of WollongongWollongong NSW 2522 Australia;</p> <p>School of Environmental and Chemical EngineeringShanghai UniversityShanghai 200444 China;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1188.html" title="应用化学">应用化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=dendrite prevention&option=203" rel="nofollow">dendrite prevention;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=protection layer&option=203" rel="nofollow">protection layer;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=rechargeable batteries&option=203" rel="nofollow">rechargeable batteries;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=sodium benzenedithiolate&option=203" rel="nofollow">sodium benzenedithiolate;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=sodium metal&option=203" rel="nofollow">sodium metal;</a> </p> <div class="translation"> 机译：树突预防;保护层;可充电电池;苯二钠酸钠;钠金属; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704028161746.html">Dendrite‐Free Sodium Metal Anodes Enabled by a Sodium Benzenedithiolate‐Rich Protection Layer</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhu Ming&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Zhu Ming,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wang Guanyao&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Wang Guanyao,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Liu Xing&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Liu Xing,</a> <a href="/journal-foreign-19011/" target="_blank" rel="nofollow" class="tuijian_authcolor">Angewandte Chemie .</a> <span>2020</span><span>,第16期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：由富含苯二硫酸钠的保护层的无树枝状无钠金属阳极使能</span> </p> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/academic-journal-foreign_advanced-energy-materials_thesis/0204120459798.html">Red Phosphorous-Derived Protective Layers with High Ionic Conductivity and Mechanical Strength on Dendrite- Free Sodium and Potassium Metal Anodes</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Shi Pengcheng&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Shi Pengcheng,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhang Shipeng&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Zhang Shipeng,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Lu Gongxun&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Lu Gongxun,</a> <a href="/journal-foreign-3212/" target="_blank" rel="nofollow" class="tuijian_authcolor">Advanced energy materials .</a> <span>2021</span><span>,第5期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：具有高离子电导率的红色磷衍生的保护层和树枝状钠和钾金属阳极上的机械强度</span> </p> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/academic-journal-foreign_detail_thesis/0204116692929.html">Homogeneous guiding deposition of sodium through main group II metals toward dendrite-free sodium anodes</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Mengqi Zhu&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Mengqi Zhu,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Songmei Li&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Songmei Li,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Bin Li&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Bin Li,</a> <a href="/journal-foreign-27878/" target="_blank" rel="nofollow" class="tuijian_authcolor">Science Advances .</a> <span>2019</span><span>,第4期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：通过主要的第二族金属向无枝晶的钠阳极均匀引导钠的沉积</span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-conference-foreign_2001-cference-of-waste-management-wmannu_thesis/020512605935.html">NOVEL HYDROGEN-FREE TREATMENT OF SODIUM METAL MIXED WASTE BYMETAL OXIDE MITIGATION OF SODIUM (MOMS) PROCESS</a> <b>[C]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=David L. Baldwin&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">David L. Baldwin,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext= Glenn W. Hollenberg&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> Glenn W. Hollenberg,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext= Stanley J. Bos&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> Stanley J. Bos </a> <a href="/conference-foreign-74400/" target="_blank" rel="nofollow" class="tuijian_authcolor">2001 conference of Waste Management (WM);Annual Waste Management Symposium .</a> <span>2001</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：金属氧化物减缓钠（MOMS）过程的新型无氢处理金属钠废料</span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-degree-foreign_mphd_thesis/02061626093.html">Forcespinning of Metal Oxides and Metal Sulfides and Their Applications as Alternative Anode Materials for Lithium-ion and Sodium-ion Batteries</a> <b>[D] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Valdez, Alejandra.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Valdez, Alejandra. </a> <span>2018</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：金属氧化物和金属硫化物的强力纺丝及其在锂离子和钠离子电池负极材料中的应用</span> </p> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-journal-foreign-pmc_detail_thesis/040002392658.html">Homogeneous guiding deposition of sodium through main group II metals toward dendrite-free sodium anodes</a> <b>[O] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Mengqi Zhu&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Mengqi Zhu,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Songmei Li&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Songmei Li,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Bin Li&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Bin Li,</a> <span>2019</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：通过主要的第二族金属向无枝晶的钠阳极均匀引导钠的沉积</span> </p> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/open-access_resources_thesis/01000131445677.html">Dendrite‐Free Sodium Metal Anodes Enabled by a Sodium Benzenedithiolate‐Rich Protection Layer</a> <b>[O] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ming Zhu&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Ming Zhu,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Guanyao Wang&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Guanyao Wang,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Xing Liu&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Xing Liu,</a> <span>2020</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：由富含苯二硫酸钠的保护层的无树枝状无金属阳极使能</span> </p> </li> <li> <div> <b>8. </b><a class="enjiyixqcontent" href="/ntis-science-report_ad_thesis/02071189495.html">Dendrite-Free Electrodeposition and Reoxidation of Lithium-Sodium Alloy for Metal-Anode Battery</a> <b>[R] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Star, J. K.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Star, J. K.,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext= Ding, Y.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> Ding, Y.,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext= Kohl, P. A.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> Kohl, P. A. </a> <span>2011</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：金属阳极电池用锂 - 钠合金的无枝晶电沉积和再氧化</span> </p> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/academic-journal-cn_metallurgical-analysis_thesis/0201220557890.html">1,5-二(2-羟基-5-磺酸基苯)-3-氰基甲(月无无白)催化褪色光度法测定微量过氧化氢</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=刘长增&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 刘长增</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=徐文军&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,徐文军</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=魏乃静&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,魏乃静</a> <span> <a href="/journal-cn-8021/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 冶金分析 </a> </span> <span> . 2007</span><span>,第002期</span> </span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/academic-journal-cn_chinese-journal-synthetic-chemistry_thesis/0201234447645.html">新型树枝状分子3,5-二3,5-二(4-羧基苯甲氧基)苯甲氧基苯甲醇的合成</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=刘静&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 刘静</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=彭亦如&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,彭亦如</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=张宏&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,张宏</a> <span> <a href="/journal-cn-11569/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 合成化学 </a> </span> <span> . 2012</span><span>,第001期</span> </span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/academic-journal-cn_liaoning-chemical-industry_thesis/0201241797526.html">无苯非钠法制备原甲酸三乙酯新工艺</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=卢海&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 卢海</a> <span> <a href="/journal-cn-13039/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 辽宁化工 </a> </span> <span> . 1995</span><span>,第001期</span> </span> </div> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-journal-cn_detail_thesis/0201296378094.html">连二亚硫酸钠在建立培养细胞的无氧环境中的应用</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=许蜀闽&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 许蜀闽</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王培勇&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,王培勇</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=马红英&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,马红英</a> <span> <a href="/journal-cn-56856/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 第三军医大学学报 </a> </span> <span> . 2005</span><span>,第4期</span> </span> </div> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-journal-cn_science-technology-information_thesis/0201257428558.html">二苯碳酰二肼分光光度法测定无组织废气中铬酸雾的测量评定</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=邓顺&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 邓顺</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=刘华东&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,刘华东</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=柴敏平&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,柴敏平</a> <span> <a href="/journal-cn-5183/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 科技资讯 </a> </span> <span> . 2016</span><span>,第022期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-616_thesis/020221539273.html">超临界二氧化碳介质中无钯无碱无配体参与的铜催化芳基硼酸自偶联反应研究</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Li Fawang&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . Li Fawang</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李发旺&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,李发旺</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Han Limin&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,Han Limin</a> <span> <a href="/conference-cn-616/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 第十届全国超临界流体技术学术及应用研讨会暨第三届海峡两岸超临界流体技术研讨会 </a> <span> <span> . 2015</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020314943775.html">无金属催化苯炔、DMF与二芳基碘鎓盐的三组分反应合成邻醛基二芳基醚的研究</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=刘芳亮&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 刘芳亮</a> <span> . 2015</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06120108025964.html">一种使鸡蛋无腥味且富含氨基酸的蛋鸡饲料的加工方法</a> <b>[P]</b> . <span> 中国专利： CN105519817A </span> <span> . 2016-04-27</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120105030295.html">按使无纺带静电保持在尺寸小于无纺带的宽度的至少一区域的方式传送无纺带</a> <b>[P]</b> . <span> 中国专利： CN1834324A </span> <span> . 2006-09-20</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130500439363.html">Sodium metal anode having pyroprotein thin film layers and method for manufacturing the same, sodium ion battery including the anode</a> <b>[P]</b> . <span> 外国专利：  KR102285471B1 </span> <span> . 2021-08-03</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：具有蛋白质薄膜层的钠金属阳极及其制造方法，包括阳极在内的钠离子电池 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130409426162.html">The process of extracting precious metals from anode deposits by mixing sodium carbonate, quartz, coke powder and impurity free anode deposits, melting and transforming the mixture.</a> <b>[P]</b> . <span> 外国专利：  CL2016001582A1 </span> <span> . 2016-11-11</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：通过将碳酸钠，石英，焦炭粉和无杂质的阳极沉积物混合，熔融和转化混合物，从阳极沉积物中提取贵金属的过程。 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130416445515.html">Electrode, useful as anode in electrolysis of sodium perchlorate used in e.g. engine of missile, comprises titanium support covered with a metal layer made of noble metals or their alloys, where metal layer is obtained by electrolysis</a> <b>[P]</b> . <span> 外国专利：  FR2992661A1 </span> <span> . 2014-01-03</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：电极，用作电解高氯酸钠的阳极，例如导弹发动机，包括钛制支撑，覆盖有贵金属或其合金制成的金属层，其中金属层是通过电解获得的 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" onclick="ywcd('0704028161746','4',7,2,1,'',this,24)" class="delivery" prompt="010401" title="通过人工服务将文献原文发送至邮箱" >获取原文</div> <div class="journalsub-pop-up" style="display: none"> <div class="journal-sub"> <h2>期刊订阅</h2> <img src="https://cdn.zhangqiaokeyan.com/img/loginclose.png" alt="关闭" onclick="$('.journalsub-pop-up').hide()"> <p class="pardon">抱歉，该期刊暂不可订阅，敬请期待！</p> <p class="current">目前支持订阅全部北京大学中文核心（2020）期刊目录。</p> <div style="display: flex;margin-top: 69px;justify-content: space-between;"> <div class="no-sub" onclick="$('.journalsub-pop-up').hide()">暂不订阅</div> <div class="other-sub" onclick="continueSub('from=pc-detail')">继续订阅其他期刊</div> </div> </div> </div> <div class="right_btn"> <ul> <li class="gouwuche">  </li> <li class="yijian"> <a href="javascript:void(0);" onclick="link_analysis('/mycenter/auth/complaint.html',this)" title="意见反馈">意见反馈</a> </li> <li class="top"> <a href="javascript:scrollTo(0,0);" title="回到顶部">回到顶部</a> </li> <li class="shouye"> <a href="/" title="首页">回到首页</a> </li> </ul> </div> <div class="xllindexfooter"> <div class="xllindexfootercenter"> <div class="xllindexfooterleft left" > <div class="xllindexfooterleftli"> <ul> <li><a href="/about.html" title="关于掌桥">关于掌桥</a></li> <li><a href="/help/helpmap.html" title="资源导航">资源导航</a></li> <li><a href="/help/helpguide.html" title="新手指南">新手指南</a></li> <li><a href="/help/helpcenter.html" title="常见问题">常见问题</a></li> <li><a href="/sitemap.html" title="网站地图">网站地图</a></li> <li><a href="/help/helpcenter.html?type=9" title="版权声明">版权声明</a></li> </ul> </div> <div class="xllindexfooterleft"> <p class="xllindexfooterlefteamil">客服邮箱：kefu@zhangqiaokeyan.com</p> <div class="xllindexfooterlefttcp"> <div class="xllindexfooterpoliceiimg"></div> <div class="xllindexfooterpoliceispan"> <span>京公网安备：11010802029741号 </span> <span>ICP备案号：<a href="https://beian.miit.gov.cn" rel="nofollow" target="_blank" title="ICP备案号">京ICP备15016152号-6</a></span> <span>六维联合信息科技 (北京) 有限公司©版权所有</span> </div> </div> </div> </div> <div class="xllindexfooterright left"> <ul> <li> <p style="font-weight: bold;">客服微信</p> <div></div> </li> <li> <p style="font-weight: bold;">服务号</p> <div></div> </li> </ul> </div> </div> </div> <span id="0704028161746down" data-source="7," data-out-id="UR2DDXMBx4eR7LfSvkRohGWqEJvJHoc5oYb3BnWd9d2bGaojvvpRagxanmljuE8m," data-f-source-id="7" data-title="Dendrite‐Free Sodium Metal Anodes Enabled by a Sodium Benzenedithiolate‐Rich Protection Layer" data-price="20" data-site-name="" data-transnum="24" style="display:none;"></span> <input type="hidden" value="4" id="sourcetype"> <input type="hidden" value="19011" id="journalid"> <input type="hidden" value="1" id="inyn_provide_service_level"> <input type="hidden" value="https://cdn.zhangqiaokeyan.com" id="imgcdn"> <input type="hidden" value="1" id="isdeatail"> <input type="hidden" value="" id="syyn_indexed_database"> <input type="hidden" value="" id="servicetype"> <input type="hidden" id="pagename" value="Dendrite‐Free Sodium Metal Anodes Enabled by a Sodium Benzenedithiolate‐Rich Protection Layer"/> <input type="hidden" value="thesis_get_original" id="pageIdentification"> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/jquery-1.12.4.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/lwlh_ajax.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/zq.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/common.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/jquery.cookie.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/top.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/tip.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/login.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/down.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/search.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/newmail.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/searchtype.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/user/regist.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/zxs_solor/detail.js?v=5.7.8"></script> <script type="text/javascript" src="https://www.zhangqiaokeyan.com/statistics/static/pagecollection.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/tj.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/sse.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/pushbaidu.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/history.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/util/cookie.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/weipu/weipu.js?v=5.7.8"></script> </body> <script> $(function(){ var weiPuStatus = getCookie('WeiPuStatus'); if(weiPuStatus){ tipWeiPuStatus(weiPuStatus); delCookie('WeiPuStatus'); } getFacetKeywordVoInId(); var sourcetype = $("#sourcetype").val(); var inyn_provide_service_level = $("#inyn_provide_service_level").val(); if((sourcetype ==1||sourcetype==4)&&inyn_provide_service_level!=4){ getJournal(); } }) </script> </html>