Fast Lithium Ion Conduction in Lithium Phosphidoaluminates

摘要

Abstract > Solid electrolyte materials are crucial for the development of high‐energy‐density all‐solid‐state batteries (ASSB) using a nonflammable electrolyte. In order to retain a low lithium‐ion transfer resistance, fast lithium ion conducting solid electrolytes are required. We report on the novel superionic conductor Li <sub>9</sub> AlP <sub>4</sub> which is easily synthesised from the elements via ball‐milling and subsequent annealing at moderate temperatures and which is characterized by single‐crystal and powder X‐ray diffraction. This representative of the novel compound class of lithium phosphidoaluminates has, as an undoped material, a remarkable fast ionic conductivity of 3?mS?cm ?1 and a low activation energy of 29?kJ?mol ?1 as determined by impedance spectroscopy. Temperature‐dependent 7 Li NMR spectroscopy supports the fast lithium motion. In addition, Li <sub>9</sub> AlP <sub>4</sub> combines a very high lithium content with a very low theoretical density of 1.703?g?cm ?3 . The distribution of the Li atoms over the diverse crystallographic positions between the [AlP <sub>4</sub> ] 9? tetrahedra is analyzed by means of DFT calculations. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 固体电解质材料对于使用不易燃电解质开发高能密度全固态电池（ASSB）至关重要。为了保留低锂离子传递电阻，需要快速锂离子传导固体电解质。我们报告了小说的超越导体李 <sub> 9 </ sub> alp. <sub> 4 </ sub> 这通过球磨和随后在中等温度下进行的元素容易地合成，其特征在于单晶和粉末X射线衍射。该代表性的锂磷酸锂的新化合物类别具有未掺杂的材料，具有显着的快速离子电导率为3·ms？cm ？1 </ sup> 和低激活能量为29？kj？mol ？1 </ sup> 由阻抗光谱法确定。温度依赖 7 </ sup> Li NMR光谱支持快速锂运动。此外，李 <sub> 9 </ sub> alp. <sub> 4 </ sub> 将非常高的锂含量结合在非常低的理论密度为1.703？g？cm ？3 </ sup> 。锂原子在[ALP之间的不同晶体位置 <sub> 4 </ sub> ] 9？</ sup> 通过DFT计算分析Tetrahedra。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-19011/'>《Angewandte Chemie》</a> <b style="margin: 0 2px;">|</b><span>2020年第14期</span><b style="margin: 0 2px;">|</b><span>共10页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1188.html" title="应用化学">应用化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=all-solid-state batteries&option=203" rel="nofollow">all-solid-state batteries;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=impedance spectroscopy&option=203" rel="nofollow">impedance spectroscopy;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=lithium&option=203" rel="nofollow">lithium;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=solid electrolytes&option=203" rel="nofollow">solid electrolytes;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=solid-state structures&option=203" rel="nofollow">solid-state structures;</a> </p> <div class="translation"> 机译：全固态电池;阻抗光谱;锂;固体电解质;固态结构; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704028161583.html">Fast Lithium Ion Conduction in Lithium Phosphidoaluminates</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> </a> <a href="/journal-foreign-19011/" target="_blank" rel="nofollow" class="tuijian_authcolor">Angewandte Chemie 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