Active and Unidirectional Acceleration of Biaryl Rotation by a Molecular Motor

摘要

Abstract > Light‐driven molecular motors possess immense potential as central driving units for future nanotechnology. Integration into larger molecular setups and transduction of their mechanical motions represents the current frontier of research. Herein we report on an integrated molecular machine setup allowing the transmission of potential energy from a motor unit onto a remote receiving entity. The setup consists of a motor unit connected covalently to a distant and sterically encumbered biaryl receiver. By action of the motor unit, single‐bond rotation of the receiver is strongly accelerated and forced to proceed unidirectionally. The transmitted potential energy is directly measured as the extent to which energy degeneration is lifted in the thermal atropisomerization of this biaryl. Energy degeneracy is reduced by more than 1.5?kcal?mol ?1 , and rate accelerations of several orders of magnitude in terms of the rate constants are achieved. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 光驱动的分子电机具有巨大的潜力，作为未来纳米技术的中央驾驶单元。融入较大的分子设置并转换它们的机械运动代表了当前的研究前沿。在此，我们报告了集成的分子机器设置，允许将电位能量从电动机单元传输到远程接收实体上。该设置包括与远处和空心上的BiAlyl接收器共价连接的电机单元。通过电动机单元的作用，接收器的单键旋转被强烈加速并强制直接进行单向进行。透射电位能量是直接测量能量变性在该壳体的热反异构化中的能量变性的程度。能量退化减少超过1.5？kcal？mol ？1 </ sup> 实现了几个数量级的速率加速度在速率常数方面的速率加速度。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-19011/'>《Angewandte Chemie》</a> <b style="margin: 0 2px;">|</b><span>2020年第14期</span><b style="margin: 0 2px;">|</b><span>共8页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1188.html" title="应用化学">应用化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=hemithioindigo&option=203" rel="nofollow">hemithioindigo;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=isomerization&option=203" rel="nofollow">isomerization;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=molecular machines&option=203" rel="nofollow">molecular machines;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=photochemistry&option=203" rel="nofollow">photochemistry;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=physical chemistry&option=203" rel="nofollow">physical chemistry;</a> </p> <div class="translation"> 机译：Hemithioindigo;异构化;分子机;光化学;物理化学; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704028161544.html">Active and Unidirectional Acceleration of Biaryl Rotation by a Molecular Motor</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> </a> <a href="/journal-foreign-19011/" target="_blank" rel="nofollow" class="tuijian_authcolor">Angewandte Chemie .</a> <span>2020</span><span>,第14期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：分子电机的主动和单向加速辅助旋转</span> </p> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/academic-journal-foreign_organic-letters_thesis/020415101043.html">180° Unidirectional Bond Rotation in a Biaryl Lactone Artificial Molecular Motor Prototype</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Bart J. 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href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王桂芝&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 王桂芝</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=杨明蕾&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,杨明蕾</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=张荣&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,张荣</a> <span> <a href="/journal-cn-8551/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 微电机 </a> </span> <span> . 2017</span><span>,第009期</span> </span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/academic-journal-cn_chinese-journal-tissue-engineering-research_thesis/0201252393180.html">计算机辅助角膜分析系统在主动眼球跟踪近视准分子激光原位角膜磨镶术后光学切削区偏中心应用中的意义</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=刘美光&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 刘美光</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=林静&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,林静</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王传富&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,王传富</a> <span> <a href="/journal-cn-15352/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 中国组织工程研究 </a> </span> <span> . 2007</span><span>,第022期</span> </span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/academic-journal-cn_practical-journal-cardiac-cerebral-pneumal-vascular-disease_thesis/0201279241146.html">"单向"导丝技术结合新型Castor分支支架植入在Stanford B型主动脉夹层患者胸主动脉腔内修复术中的应用效果及体会</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=孙玉桂&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 孙玉桂</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=张显岚&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,张显岚</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=孙江滨&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,孙江滨</a> <span> <a href="/journal-cn-5978/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 实用心脑肺血管病杂志 </a> </span> <span> . 2020</span><span>,第006期</span> </span> </div> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-journal-cn_chemical-journal-chinese-universities_thesis/0201231635712.html">应用分子图形学、分子力学、量子化学及静电势研究农药分子结构与性能关系(Ⅹ)——磺酰脲分子内旋转通道的分子力学研究</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=刘艾林&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 刘艾林</a> <span> <a href="/journal-cn-10958/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 高等学校化学学报 </a> </span> <span> . 1997</span><span>,第004期</span> </span> </div> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-journal-cn_journal-jixi-university_thesis/0201236847531.html">知识分子到知识工人--在单向度视野下看现代中国知识分子的职能转变</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=魏宏玉&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 魏宏玉</a> <span> <a href="/journal-cn-4009/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 鸡西大学学报 </a> </span> <span> . 2014</span><span>,第010期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-13629_thesis/02022946402.html">单向走丝电火花线切割机床直线-旋转轴联动切割加工</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=朱宁&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 朱宁</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=叶军&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,叶军</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=许庆平&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,许庆平</a> <span> <a href="/conference-cn-13629/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 2010年全国电火花线切割加工技术与市场研讨会 </a> <span> <span> . 2010</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020314939840.html">基于旋转角加速度传感器的电力拖动系统扭振检测及电机扭振抑制方法研究</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=赵浩&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 赵浩</a> <span> . 2017</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/061203189485.html">单向旋转电机及用于单向旋转电机的定子</a> <b>[P]</b> . <span> 中国专利： CN106253507B </span> <span> . 2019.02.05</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120108731877.html">单向旋转电机及用于单向旋转电机的定子</a> <b>[P]</b> . <span> 中国专利： CN106253507A </span> <span> . 2016-12-21</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130424279819.html">Gear parameter e.g. camber, determining device for motor car, has acceleration sensor arranged at wheel of motor car, and rotation speed sensor determining wheel base, where acceleration sensor determines centrifugal acceleration</a> <b>[P]</b> . <span> 外国专利：  DE102010055378A1 </span> <span> . 2011-08-25</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：齿轮参数外倾角，用于汽车的确定装置，具有在汽车的车轮上布置的加速度传感器，以及用于确定离心加速度的转速传感器，其确定轴距。 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130421737718.html">Method for limiting drive-related wheel rotational acceleration of driving wheel in e.g. hybrid car, involves limiting motor rotational acceleration in given threshold value by engine control equipments</a> <b>[P]</b> . <span> 外国专利：  DE102011087640A1 </span> <span> . 2012-07-19</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：限制驱动轮的与驱动有关的轮旋转加速度的方法，例如混合动力汽车，涉及通过发动机控制设备将电动机旋转加速度限制在给定的阈值内 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130429245368.html">Engine's gearbox controlling method for motor vehicle, involves providing acceleration value and increasing moment-rotational speed with acceleration value, until target-rotational speed value is reached</a> <b>[P]</b> . <span> 外国专利：  DE102008020713A1 </span> <span> . 2009-10-01</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：用于汽车的发动机的变速箱控制方法，包括提供加速度值并随着加速度值增加力矩转速，直到达到目标转速值为止。 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" onclick="ywcd('0704028161544','4',7,2,1,'',this,24)" class="delivery" prompt="010401" title="通过人工服务将文献原文发送至邮箱" >获取原文</div> <div class="journalsub-pop-up" style="display: none"> <div class="journal-sub"> <h2>期刊订阅</h2> <img src="https://cdn.zhangqiaokeyan.com/img/loginclose.png" alt="关闭" onclick="$('.journalsub-pop-up').hide()"> <p class="pardon">抱歉，该期刊暂不可订阅，敬请期待！</p> <p class="current">目前支持订阅全部北京大学中文核心（2020）期刊目录。</p> <div style="display: flex;margin-top: 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