Space‐Confined Atomic Clusters Catalyze Superassembly of Silicon Nanodots within Carbon Frameworks for Use in Lithium‐Ion Batteries

Chen Bingjie; Zu Lianhai; Liu Yao; Meng Ruijing; Feng Yutong; Peng Chengxin; Zhu Feng; Hao Tianzi; Ru Jiajia; Wang Yonggang; Yang Jinhu

摘要

Abstract >Incorporating nanoscale Si into a carbon matrix with high dispersity is desirable for the preparation of lithium‐ion batteries (LIBs) but remains challenging. A space‐confined catalytic strategy is proposed for direct superassembly of Si nanodots within a carbon (Si NDs?C) framework by copyrolysis of triphenyltin hydride (TPT) and diphenylsilane (DPS), where Sn atomic clusters created from TPT pyrolysis serve as the catalyst for DPS pyrolysis and Si catalytic growth. The use of Sn atomic cluster catalysts alters the reaction pathway to avoid SiC generation and enable formation of Si NDs with reduced dimensions. A typical Si NDs?C framework demonstrates a remarkable comprehensive performance comparable to other Si‐based high‐performance half LIBs, and higher energy densities compared to commercial full LIBs, as a consequence of the high dispersity of Si NDs with low lithiation stress. Supported by mechanic simulations, this study paves the way for construction of Si/C composites suitable for applications in future energy technologies. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> 将纳米级Si掺入具有高分子的碳基质中，希望制备锂离子电池（Libs），但保持挑战性。提出了一种空间局限性催化策略，用于通过三苯基氢化物（TPT）和二苯基硅烷（DPS）的Coottry解（DP）和二苯基硅烷（DPS）的碳（Si Ndsβc）框架内的直接超级组装，其中由TPT热解产生的Sn原子簇用作催化剂对于DPS热解和Si催化生长。使用Sn原子簇催化剂改变了反应途径，以避免SiC产生，并使Si NDS形成具有降低的尺寸。典型的Si NDS？C框架展示了与其他基于Si的高性能半岛的综合性能相当，与商业全套Libs相比，与Si Nds具有低锂化应力的高分散性。该研究支持机械模拟，这项研究铺平了适用于未来能源技术应用的Si / C复合材料的施工方法。</ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-19011/'>《Angewandte Chemie》</a> <b style="margin: 0 2px;">|</b><span>2020年第8期</span><b style="margin: 0 2px;">|</b><span>共6页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Chen Bingjie&option=202" target="_blank" rel="nofollow">Chen Bingjie;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zu Lianhai&option=202" target="_blank" rel="nofollow">Zu Lianhai;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Liu Yao&option=202" target="_blank" rel="nofollow">Liu Yao;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Meng Ruijing&option=202" target="_blank" rel="nofollow">Meng Ruijing;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Feng Yutong&option=202" target="_blank" rel="nofollow">Feng Yutong;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Peng Chengxin&option=202" target="_blank" rel="nofollow">Peng Chengxin;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhu Feng&option=202" target="_blank" rel="nofollow">Zhu Feng;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Hao Tianzi&option=202" target="_blank" rel="nofollow">Hao Tianzi;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ru Jiajia&option=202" target="_blank" rel="nofollow">Ru Jiajia;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wang Yonggang&option=202" target="_blank" rel="nofollow">Wang Yonggang;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yang Jinhu&option=202" target="_blank" rel="nofollow">Yang Jinhu;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>School of Chemical Science and EngineeringTongji UniversityShanghai 200092 P. R. China;</p> <p>School of Chemical Science and EngineeringTongji UniversityShanghai 200092 P. R. China;</p> <p>Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative MaterialsFudan UniversityShanghai 200433 China;</p> <p>School of Chemical Science and EngineeringTongji UniversityShanghai 200092 P. R. China;</p> <p>School of Chemical Science and EngineeringTongji UniversityShanghai 200092 P. R. China;</p> <p>School of Materials Science and EngineeringUniversity of Shanghai for Science and TechnologyShanghai 200093 China;</p> <p>School of Aerospace Engineering and Applied MechanicsTongji UniversityShanghai 200433 China;</p> <p>School of Chemical Science and EngineeringTongji UniversityShanghai 200092 P. R. China;</p> <p>School of Chemical Science and EngineeringTongji UniversityShanghai 200092 P. R. China;</p> <p>Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative MaterialsFudan UniversityShanghai 200433 China;</p> <p>School of Chemical Science and EngineeringTongji UniversityShanghai 200092 P. R. China;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1188.html" title="应用化学">应用化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=atomic clusters&option=203" rel="nofollow">atomic clusters;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=carbon matrices&option=203" rel="nofollow">carbon matrices;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=pyrolysis strategies&option=203" rel="nofollow">pyrolysis strategies;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=silicon&option=203" rel="nofollow">silicon;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=structural stability&option=203" rel="nofollow">structural stability;</a> </p> <div class="translation"> 机译：原子簇;碳矩阵;热解策略;硅;结构稳定性; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704028161496.html">Space‐Confined Atomic Clusters Catalyze Superassembly of Silicon Nanodots within Carbon Frameworks for Use in Lithium‐Ion 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