Photoinduced Mo?CN Bond Breakage in Octacyanomolybdate Leading to Spin Triplet Trapping

Qi Xinghui; Pillet Sébastien; Graaf Coen; Magott Micha?; Bendeif El‐Eulmi; Guionneau Philippe; Rouzières Mathieu; Marvaud Valérie; Stefańczyk Olaf; Pinkowicz Dawid; Mathonière Corine

摘要

Abstract > The photoinduced properties of the octacoordinated complex K <sub>4</sub> Mo IV (CN) <sub>8</sub> ?2?H <sub>2</sub> O were studied by theoretical calculations, crystallography, and optical and magnetic measurements. The crystal structure recorded at 10?K after blue light irradiation reveals an heptacoordinated Mo(CN) <sub>7</sub> species originating from the light‐induced cleavage of one Mo?CN bond, concomitant with the photoinduced formation of a paramagnetic signal. When this complex is heated to 70?K, it returns to its original diamagnetic ground state, demonstrating full reversibility. The photomagnetic properties show a partial conversion into a triplet state possessing significant magnetic anisotropy, which is in agreement with theoretical studies. Inspired by these results, we isolated the new compound [K(crypt‐222)] <sub>3</sub> [Mo IV (CN) <sub>7</sub> ]?3?CH <sub>3</sub> CN using a photochemical pathway, confirming that photodissociation leads to a stable heptacyanomolybdate(IV) species in solution. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 八钒络合物K的光诱导性质 <sub> 4 </ sub> 莫 iv </ sup> （CN） <sub> 8 </ sub> ？2？H <sub> 2 </ sub> o由理论计算，晶体学和光学和磁测量研究。在蓝光照射之后记录在10μk的晶体结构显示略微展开庚烷（CN） <sub> 7 </ sub> 源自光诱导的一个MoβCN键的物种，伴随着光诱导的顺磁信号的形成。当将该复合物加热至70Ω·k时，它返回其原始的抗磁场地位，展示完全可逆性。光磁性特性显示出具有显着磁各向异性的三重态状态的部分转化，这与理论研究一致。受这些结果的启发，我们孤立新化合物[K（Crypt-222）] <sub> 3 </ sub> [莫 iv </ sup> （CN） <sub> 7 </ sub> ]？3？CH <sub> 3 </ sub> CN使用光化学途径，确认光探测器导致溶液中稳定的庚基钼钼酸盐（IV）物种。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-19011/'>《Angewandte Chemie》</a> <b style="margin: 0 2px;">|</b><span>2020年第8期</span><b style="margin: 0 2px;">|</b><span>共5页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Qi Xinghui&option=202" target="_blank" rel="nofollow">Qi Xinghui;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Pillet Sébastien&option=202" target="_blank" rel="nofollow">Pillet Sébastien;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Graaf Coen&option=202" target="_blank" rel="nofollow">Graaf Coen;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Magott Micha?&option=202" target="_blank" rel="nofollow">Magott Micha?;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Bendeif El‐Eulmi&option=202" target="_blank" rel="nofollow">Bendeif El‐Eulmi;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Guionneau Philippe&option=202" target="_blank" rel="nofollow">Guionneau Philippe;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Rouzières Mathieu&option=202" target="_blank" rel="nofollow">Rouzières Mathieu;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Marvaud Valérie&option=202" target="_blank" rel="nofollow">Marvaud Valérie;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Stefańczyk Olaf&option=202" target="_blank" rel="nofollow">Stefańczyk Olaf;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Pinkowicz Dawid&option=202" target="_blank" rel="nofollow">Pinkowicz Dawid;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Mathonière Corine&option=202" target="_blank" rel="nofollow">Mathonière Corine;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>CNRSUniv. BordeauxF-33600 Pessac France;</p> <p>CNRSUniversité de Lorraine54506 Vandoeuvre-les-Nancy France;</p> <p>Departament de Química Física i InorgànicaUniversitat Rovira i VirgiliCarrer Marcellí Domingo 1 Tarragona Spain;</p> <p>Faculty of ChemistryJagiellonian UniversityGronostajowa 2 30-387 Kraków Poland;</p> <p>CNRSUniversité de Lorraine54506 Vandoeuvre-les-Nancy France;</p> <p>CNRSUniv. BordeauxF-33600 Pessac France;</p> <p>CNRSUniv. BordeauxF-33600 Pessac France;</p> <p>IPCM-CNRS-UMR-8232 cc 229Sorbonne Université4 place Jussieu 75252 Paris Cedex 05 France;</p> <p>CNRSUniv. BordeauxF-33600 Pessac France;</p> <p>Faculty of ChemistryJagiellonian UniversityGronostajowa 2 30-387 Kraków Poland;</p> <p>CNRSUniv. BordeauxF-33600 Pessac France;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1188.html" title="应用化学">应用化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=cyanides&option=203" rel="nofollow">cyanides;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=magnetic properties&option=203" rel="nofollow">magnetic properties;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=molybdenum&option=203" rel="nofollow">molybdenum;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=photochemistry&option=203" rel="nofollow">photochemistry;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=X-ray diffraction&option=203" rel="nofollow">X-ray diffraction;</a> </p> <div class="translation"> 机译：氰化物;磁性;钼;光化学;X射线衍射; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704028161326.html">Photoinduced Mo?CN Bond Breakage in Octacyanomolybdate Leading to Spin Triplet Trapping</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Qi Xinghui&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Qi Xinghui,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Pillet Sébastien&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Pillet Sébastien,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Graaf Coen&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Graaf Coen,</a> <a href="/journal-foreign-19011/" target="_blank" rel="nofollow" class="tuijian_authcolor">Angewandte Chemie .</a> <span>2020</span><span>,第8期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：光致动的Mo？CN粘结破损在八辛酸盐斑块中导致旋转三态捕获</span> </p> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704012984619.html">Crystal Structures of Octacyanomolybdates(IV). IV Dodecahedral [Mo(CN)_8] Coordination of the Cyano-Bridged Cobalt and Nickel Ammin Complexes M_2~(II)(NH_3)_8[Mo(CN)_8] approx 1.5H_2O (M~(II) = Co, Ni) and Ni_2(NH_3)_9[Mo(CN)_8] centre dot 2H_2O</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=W. Meske&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">W. Meske,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=D. Babel&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">D. Babel </a> <a href="/journal-foreign-32749/" target="_blank" rel="nofollow" class="tuijian_authcolor">Zeitschrift fur Anorganische und Allgemeine Chemie .</a> <span>1999</span><span>,第1期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：八氰基钼酸盐（IV）的晶体结构。氰基桥连钴和镍Ammin配合物M_2〜（II）（NH_3）_8 [Mo（CN）_8]的IV十二面体[Mo（CN）_8]配位约1.5H_2O（M〜（II）= Co，Ni）和Ni_2（NH_3）_9 [Mo（CN）_8]中心点2H_2O</span> </p> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704011657843.html">Photoinduced Magnetization on Mo Ion in Copper Octacyanomolybdate: An X-ray Magnetic Circular Dichroism Investigation</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Marie-Anne Arrio&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Marie-Anne Arrio,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Jerome Long&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Jerome Long,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Christophe Cartier dit Moulin&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Christophe Cartier dit Moulin </a> <a href="/journal-foreign-30977/" target="_blank" rel="nofollow" class="tuijian_authcolor">The journal of physical chemistry, C. Nanomaterials and interfaces .</a> <span>2010</span><span>,第1期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：八氰钼酸铜中钼离子的光诱导磁化：X射线磁性圆二色性研究</span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-conference-foreign_meeting-253417_thesis/070509693705.html">Organometallic triplet emitters for OLED applications Spin-dependent exciton trapping and triplet harvesting</a> <b>[C]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Hartmut Yersin&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Hartmut Yersin </a> <a href="/conference-foreign-253417/" target="_blank" rel="nofollow" class="tuijian_authcolor">Triennial Conference on the ITG-Chapter 8.6 'Vacuum Electronics and Displays' .</a> <span>2004</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：OLED应用的有机金属三联发射器旋转依赖性激子捕获和三态收获</span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-degree-foreign_mphd_thesis/02061132729.html">The chemical trapping toolbox: Exploring ion binding with a rigid gemini surfactant, investigating weak hydrogen bonding, and demonstrating amide bond cleavage.</a> <b>[D] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Regler, Brian.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Regler, Brian. </a> <span>2006</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：化学捕集工具箱：探索与刚性双子表面活性剂的离子结合，研究弱氢键，并证明酰胺键裂解。</span> </p> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-journal-foreign-pmc_detail_thesis/040001778610.html">Radical Intermediates in Photoinduced Reactions on TiO2 (An EPR Spin Trapping Study)</a> <b>[O] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Dana Dvoranová&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Dana Dvoranová,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zuzana Barbieriková&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Zuzana Barbieriková,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Vlasta Brezová&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Vlasta Brezová </a> <span>2014</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：TiO2光诱导反应中的自由基中间体（EPR自旋俘获研究）</span> </p> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/open-access_resources_thesis/01000130611126.html">Photoinduced Mo−CN Bond Breakage in Octacyanomolybdate Leading to Spin Triplet Trapping</a> <b>[O] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Xinghui Qi&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Xinghui Qi,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Sébastien Pillet&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Sébastien Pillet,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Coen Graaf&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Coen Graaf,</a> <span>2020</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：八环钼族粘结族的光诱导的Mo-CN债券断裂导致旋转三态捕获</span> </p> </li> <li> <div> <b>8. </b><a class="enjiyixqcontent" href="/ntis-science-report_de_thesis/020711599800.html">Photoinduced Electron Transfer in Rigid Solution: Time Related Quenching of Triplet Zinc Tetraphenylporphine</a> <b>[R] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Kahlow, M. A.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Kahlow, M. A. </a> <span>1983</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：刚性溶液中的光诱导电子转移：三重态四苯基卟啉锌的时间相关猝灭</span> </p> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/academic-journal-cn_laser-infrared_thesis/0201236262189.html">光致旋转中晶体微粒厚度对旋转频率的影响</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=魏勇&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 魏勇</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=朱艳英&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,朱艳英</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=肖长江&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,肖长江</a> <span> <a href="/journal-cn-8754/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 激光与红外 </a> </span> <span> . 2014</span><span>,第010期</span> </span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/academic-journal-cn_laser-infrared_thesis/0201236282877.html">光阱中光致旋转测量液体温度的研究</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=魏强&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 魏强</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=秦水介&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,秦水介</a> <span> <a href="/journal-cn-8754/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 激光与红外 </a> </span> <span> . 2010</span><span>,第006期</span> </span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/academic-journal-cn_detail_thesis/0201297855108.html">对提拉法红宝石中光致离化导致光损伤的讨论</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李光晓&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 李光晓</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=杨林&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,杨林</a> <span> <a href="/journal-cn-56985/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 激光杂志 </a> </span> <span> . 1986</span><span>,第6期</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06120104472948.html">光投影系统中的薄膜致动镜象阵列及其制造方法</a> <b>[P]</b> . <span> 中国专利： CN1265251A </span> <span> . 2000-08-30</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06130458861901.html">METHOD OF TRAPPING, TREATMENT AND LEADING OF SLIVER END INTO THE SPINNING UNIT OF OPEN-END SPINNING MACHINE AND DEVICE FOR REALIZATION OF THIS METHOD</a> <b>[P]</b> . <span> 外国专利：  SK277982B6 </span> <span> . 1995-09-14</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：将尾端捕集，处理和引导到开放式纺丝机的纺丝单元中的方法及实现该方法的装置 </span> </p> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130458861902.html">METHOD OF TRAPPING, TREATMENT AND LEADING OF SLIVER END INTO THE SPINNING UNIT OF OPEN-END SPINNING MACHINE AND DEVICE FOR REALIZATION OF THIS METHOD</a> <b>[P]</b> . <span> 外国专利：  SK277982B6 </span> <span> . 1995-09-14</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：将尾端捕集，处理和引导到开放式纺丝机的纺丝单元中的方法及实现该方法的装置 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130455935265.html">CLAY TARGET TRAP HAVING LEADING EDGE OF THROWING ARM CURVED TO AVOID IMPACT BREAKAGE UPON RELEASE AND TO PROVIDE CLOSE FLIGHT TRAJECTORIES FOR PAIRS OF TARGETS</a> <b>[P]</b> . <span> 外国专利：  NZ314304A </span> <span> . 1997-09-22</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：黏土目标陷阱具有弯曲的前缘，可避免释放时的撞击破坏并为两对目标提供近距离飞行轨迹 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" onclick="ywcd('0704028161326','4',7,2,1,'',this,24)" class="delivery" prompt="010401" title="通过人工服务将文献原文发送至邮箱" >获取原文</div> <div class="journalsub-pop-up" style="display: none"> <div class="journal-sub"> <h2>期刊订阅</h2> <img src="https://cdn.zhangqiaokeyan.com/img/loginclose.png" alt="关闭" onclick="$('.journalsub-pop-up').hide()"> <p class="pardon">抱歉，该期刊暂不可订阅，敬请期待！</p> <p class="current">目前支持订阅全部北京大学中文核心（2020）期刊目录。</p> <div style="display: flex;margin-top: 69px;justify-content: space-between;"> <div class="no-sub" onclick="$('.journalsub-pop-up').hide()">暂不订阅</div> <div class="other-sub" onclick="continueSub('from=pc-detail')">继续订阅其他期刊</div> </div> </div> </div> <div class="right_btn"> <ul> <li class="gouwuche">  </li> <li class="yijian"> <a href="javascript:void(0);" onclick="link_analysis('/mycenter/auth/complaint.html',this)" title="意见反馈">意见反馈</a> </li> <li class="top"> <a href="javascript:scrollTo(0,0);" title="回到顶部">回到顶部</a> </li> <li class="shouye"> <a href="/" title="首页">回到首页</a> </li> </ul> </div> <div class="xllindexfooter"> <div class="xllindexfootercenter"> <div class="xllindexfooterleft left" > <div class="xllindexfooterleftli"> <ul> <li><a href="/about.html" title="关于掌桥">关于掌桥</a></li> <li><a href="/help/helpmap.html" title="资源导航">资源导航</a></li> <li><a href="/help/helpguide.html" title="新手指南">新手指南</a></li> <li><a href="/help/helpcenter.html" title="常见问题">常见问题</a></li> <li><a href="/sitemap.html" title="网站地图">网站地图</a></li> <li><a href="/help/helpcenter.html?type=9" title="版权声明">版权声明</a></li> </ul> </div> <div class="xllindexfooterleft"> <p class="xllindexfooterlefteamil">客服邮箱：kefu@zhangqiaokeyan.com</p> <div class="xllindexfooterlefttcp"> <div class="xllindexfooterpoliceiimg"></div> <div class="xllindexfooterpoliceispan"> <span>京公网安备：11010802029741号 </span> <span>ICP备案号：<a href="https://beian.miit.gov.cn" rel="nofollow" target="_blank" title="ICP备案号">京ICP备15016152号-6</a></span> <span>六维联合信息科技 (北京) 有限公司©版权所有</span> </div> </div> </div> </div> <div class="xllindexfooterright left"> <ul> <li> <p style="font-weight: bold;">客服微信</p> <div></div> </li> <li> <p style="font-weight: bold;">服务号</p> <div></div> </li> </ul> </div> </div> </div> <span id="0704028161326down" data-source="7," data-out-id="mby06wdI0PG4G0IBnqGNpBLFkzNG2HBNewyxSCcjUGmYR4bUypXKVQoVvMAIpytE," data-f-source-id="7" data-title="Photoinduced Mo?CN Bond Breakage in Octacyanomolybdate Leading to Spin Triplet Trapping" data-price="20" data-site-name="" data-transnum="24" style="display:none;"></span> <input type="hidden" value="4" id="sourcetype"> <input type="hidden" value="19011" id="journalid"> <input type="hidden" value="1" id="inyn_provide_service_level"> <input type="hidden" value="https://cdn.zhangqiaokeyan.com" id="imgcdn"> <input type="hidden" value="1" id="isdeatail"> <input type="hidden" value="" id="syyn_indexed_database"> <input type="hidden" value="" id="servicetype"> <input type="hidden" id="pagename" value="Photoinduced Mo?CN Bond Breakage in Octacyanomolybdate Leading to Spin Triplet Trapping"/> <input type="hidden" value="thesis_get_original" id="pageIdentification"> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/jquery-1.12.4.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/lwlh_ajax.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/zq.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/common.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/jquery.cookie.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/top.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/tip.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/login.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/down.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/search.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/newmail.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/searchtype.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/user/regist.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/zxs_solor/detail.js?v=5.7.8"></script> <script type="text/javascript" src="https://www.zhangqiaokeyan.com/statistics/static/pagecollection.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/tj.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/sse.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/pushbaidu.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/history.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/util/cookie.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/weipu/weipu.js?v=5.7.8"></script> </body> <script> $(function(){ var weiPuStatus = getCookie('WeiPuStatus'); if(weiPuStatus){ tipWeiPuStatus(weiPuStatus); delCookie('WeiPuStatus'); } getFacetKeywordVoInId(); var sourcetype = $("#sourcetype").val(); var inyn_provide_service_level = $("#inyn_provide_service_level").val(); if((sourcetype ==1||sourcetype==4)&&inyn_provide_service_level!=4){ getJournal(); } }) </script> </html>