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首页> 外文期刊>Angewandte Chemie >Assembly of the Thiolated [Au1Ag22(S‐Adm)12]3+ Superatom Complex into a Framework Material through Direct Linkage by SbF6?Anions
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Assembly of the Thiolated [Au1Ag22(S‐Adm)12]3+ Superatom Complex into a Framework Material through Direct Linkage by SbF6?Anions

机译:通过SBF6的直接连接将硫醇化[AU1AG22(S-ADM)12] 3+超级复合物组装成框架材料

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Abstract > Building framework materials with desirable properties and enhanced functionalities with nanocluster/superatom complexes as building blocks remains a challenge in the field of nanomaterials. In this study, the chiral [Au <sub>1</sub> Ag <sub>22</sub> (S‐Adm) <sub>12</sub> ] 3+ nanocluster/superatom complex (SC, in which S‐Adm=1‐adamantanethiol) was employed as a building block to construct the three‐dimensional (3D) superatom complex inorganic framework (SCIF) materials SCIF‐1 and SCIF‐2 through inorganic SbF <sub>6</sub> ? linkers. SCIF‐1 is racemic due to the assembly of two SC enantiomers in a single crystal. In SCIF‐2, the SC enantiomers are packed in separate crystals, thus producing larger channels and a circularly polarized luminescence (CPL) response. These two 3D SCIF materials exhibit unique sensitive photoluminescence (PL) in protic solvents. Our study provides a new pathway for creating novel open‐framework materials with superatom complexes and a foundation for the further development of 3D framework materials for sensing and other applications. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译:</span><Abstract Type =“Main”XML:Lang =“en”> <标题类型=“main”>抽象</ title> > 构建具有理想性质的框架材料和具有纳米光泽/超级复合物作为构建块的增强功能仍然是纳米材料领域的挑战。在这项研究中,手性[au <sub> 1 </ sub> AG <sub> 22 </ sub> (S-ADM) <sub> 12 </ sub> ] 3 + </ sup> 使用纳米光泽/超级复合物(SC,其中S-ADM = 1-亚烷硫醇)作为构建块,以构建三维(3D)超自眼复杂无机框架(SCIF)材料SCIF-1和SCIF-2通过无机SBF <sub> 6 </ sub> ?</ sup> 链接器。由于在单晶中的两个SC对映体组装,SCIF-1是外消旋的。在SCIF-2中,SC对映体填充在单独的晶体中,从而产生较大的通道和圆极化发光(CPL)响应。这两个3D SCIF材料在质子溶剂中表现出独特的敏感光致发光(PL)。我们的研究提供了一种新的途径,可以创建具有超级复合物的新型开放式框架材料,以及用于传感和其他应用的3D框架材料的进一步发展的基础。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-19011/'>《Angewandte Chemie》</a> <b style="margin: 0 2px;">|</b><span>2020年第19期</span><b style="margin: 0 2px;">|</b><span>共6页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Chen Shuang&option=202" target="_blank" rel="nofollow">Chen Shuang;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Du Wenjun&option=202" target="_blank" rel="nofollow">Du Wenjun;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Qin Chenwanli&option=202" target="_blank" rel="nofollow">Qin Chenwanli;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Liu Danyu&option=202" target="_blank" rel="nofollow">Liu Danyu;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Tang Li&option=202" target="_blank" rel="nofollow">Tang Li;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Liu Ying&option=202" target="_blank" rel="nofollow">Liu Ying;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wang Shuxin&option=202" target="_blank" rel="nofollow">Wang Shuxin;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhu Manzhou&option=202" target="_blank" rel="nofollow">Zhu Manzhou;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Institutes of Physical Science and Information TechnologyAnhui UniversityJiuLong Rd Hefei Anhui 230601 P. R. China;</p> <p>Department of Chemistry and Centre for Atomic Engineering of Advanced Materials and Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized MaterialsAnhui UniversityHefei Anhui 230601 P. R. China;</p> <p>Department of Chemistry and Centre for Atomic Engineering of Advanced Materials and Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized MaterialsAnhui UniversityHefei Anhui 230601 P. R. China;</p> <p>Department of Chemistry and Centre for Atomic Engineering of Advanced Materials and Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized MaterialsAnhui UniversityHefei Anhui 230601 P. R. China;</p> <p>Department of Chemistry and Centre for Atomic Engineering of Advanced Materials and Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized MaterialsAnhui UniversityHefei Anhui 230601 P. R. China;</p> <p>Department of Chemistry and Centre for Atomic Engineering of Advanced Materials and Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized MaterialsAnhui UniversityHefei Anhui 230601 P. R. China;</p> <p>Department of Chemistry and Centre for Atomic Engineering of Advanced Materials and Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized MaterialsAnhui UniversityHefei Anhui 230601 P. R. China;</p> <p>Institutes of Physical Science and Information TechnologyAnhui UniversityJiuLong Rd Hefei Anhui 230601 P. R. China;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1188.html" title="应用化学">应用化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=circularly polarized luminescence&option=203" rel="nofollow">circularly polarized luminescence;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=fluorescence switches&option=203" rel="nofollow">fluorescence switches;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=framework materials&option=203" rel="nofollow">framework materials;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=metal clusters&option=203" rel="nofollow">metal clusters;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=superatom complexes&option=203" rel="nofollow">superatom complexes;</a> </p> <div class="translation"> 机译:圆偏振光;荧光开关;框架材料;金属簇;超级复合物; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704028161186.html">Assembly of the Thiolated [Au1Ag22(S‐Adm)12]3+ Superatom Complex into a Framework Material through Direct Linkage by SbF6?Anions</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Chen Shuang&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Chen Shuang,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Du Wenjun&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Du Wenjun,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Qin Chenwanli&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Qin Chenwanli,</a> <a href="/journal-foreign-19011/" target="_blank" rel="nofollow" class="tuijian_authcolor">Angewandte Chemie .</a> <span>2020</span><span>,第19期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译:通过SBF6的直接连接将硫醇化[AU1AG22(S-ADM)12] 3+超级复合物组装成框架材料</span> </p> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704026849208.html">ANION-DIRECTED ASSEMBLY OF TWO NOVEL CADMIUM(II) COMPLEXES CONTAINING 2,2'-(1,4-PROPYLENE)bis(1H-BENZIMIDAZOLE) LIGAND</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Y. 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