A Liquid/Liquid Electrolyte Interface that Inhibits Corrosion and Dendrite Growth of Lithium in Lithium‐Metal Batteries

He Xiaofeng; Liu Xiao; Han Qing; Zhang Peng; Song Xiaosheng; Zhao Yong

摘要

Abstract > A proof‐of‐concept study on a liquid/liquid (L/L) two‐phase electrolyte interface is reported by using the polarity difference of solvent for the protection of Li‐metal anode with long‐term operation over 2000?h. The L/L electrolyte interface constructed by non‐polar fluorosilicane (PFTOS) and conventionally polar dimethyl sulfoxide solvents can block direct contact between conventional electrolyte and Li anode, and consequently their side reactions can be significantly eliminated. Moreover, the homogeneous Li‐ion flow and Li‐mass deposition can be realized by the formation of a thin and uniform solid‐electrolyte interphase (SEI) composed of LiF, Li <sub> x </sub> C, Li <sub> x </sub> SiO <sub> y </sub> between PFTOS and Li anode, as well as the super‐wettability state of PFTOS to Li anode, resulting in the suppression of Li dendrite formation. The cycling stability in a lithium–oxygen battery as a model is improved 4 times with the L/L electrolyte interface. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 通过使用溶剂的极性差异来保护液/液（L / L）两相电解质界面对溶剂的极性差异来保护Li-Metal阳极，在2000μm中的长期运行中进行概念的概念研究。由非极性氟硅烷（PFTOS）构成的L / L电解质界面和常规极性二甲基亚砜溶剂可以阻断常规电解质和Li阳极之间的直接接触，因此它们的副反应可以显着消除。此外，通过形成LiF，Li的薄且均匀的固体电解质间（SEI），可以实现均相锂离子流量和锂质量沉积。 <sub> x </ i> </ sub> C，Li. <sub> x </ i> </ sub> SiO. <sub> Y </ I> </ sub> 在PFTOS和Li阳极之间，以及PFTOS的超湿度状态为Li阳极，导致抑制Li Dendrite的形成。锂 - 氧电池中的循环稳定性随着L / L电解质界面的改善4次。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-19011/'>《Angewandte Chemie》</a> <b style="margin: 0 2px;">|</b><span>2020年第16期</span><b style="margin: 0 2px;">|</b><span>共9页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=He Xiaofeng&option=202" target="_blank" rel="nofollow">He Xiaofeng;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Liu Xiao&option=202" target="_blank" rel="nofollow">Liu Xiao;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Han Qing&option=202" target="_blank" rel="nofollow">Han Qing;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhang Peng&option=202" target="_blank" rel="nofollow">Zhang Peng;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Song Xiaosheng&option=202" target="_blank" rel="nofollow">Song Xiaosheng;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhao Yong&option=202" target="_blank" rel="nofollow">Zhao Yong;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Key Lab for Special Functional Materials of Ministry of EducationHenan UniversityKaifeng 475004 P.R.China;</p> <p>Key Lab for Special Functional Materials of Ministry of EducationHenan UniversityKaifeng 475004 P.R.China;</p> <p>Key Lab for Special Functional Materials of Ministry of EducationHenan UniversityKaifeng 475004 P.R.China;</p> <p>Department of Materials Science &</p> <p>EngineeringSouthern University of Science and TechnologyShenzhen 518055 P.R.China;</p> <p>Key Lab for Special Functional Materials of Ministry of EducationHenan UniversityKaifeng 475004 P.R.China;</p> <p>Key Lab for Special Functional Materials of Ministry of EducationHenan UniversityKaifeng 475004 P.R.China;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1188.html" title="应用化学">应用化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=electrolyte interfaces&option=203" rel="nofollow">electrolyte interfaces;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=fluorosilane&option=203" rel="nofollow">fluorosilane;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=lithium anodes&option=203" rel="nofollow">lithium anodes;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=lithium metal batteries&option=203" rel="nofollow">lithium metal batteries;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=lithium oxygen batteries&option=203" rel="nofollow">lithium oxygen batteries;</a> </p> <div class="translation"> 机译：电解质界面;氟硅烷;锂阳极;锂金属电池;锂氧气电池; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704028161119.html">A Liquid/Liquid Electrolyte Interface that Inhibits Corrosion and Dendrite Growth of Lithium in Lithium‐Metal Batteries</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=He Xiaofeng&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">He Xiaofeng,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Liu Xiao&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Liu Xiao,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Han Qing&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Han Qing,</a> <a href="/journal-foreign-19011/" target="_blank" rel="nofollow" class="tuijian_authcolor">Angewandte Chemie .</a> <span>2020</span><span>,第16期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：一种液体/液体电解质界面，抑制锂金属电池中锂的腐蚀和枝晶生长</span> </p> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704020685255.html">Anion-cation, anion-lithium, cation-lithium and ion pair-lithium interactions in alicyclic ammonium based ionic liquids as electrolytes of lithium metal batteries</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=L. Maftoon-Azad&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">L. Maftoon-Azad,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=F. Nazari&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">F. Nazari </a> <a href="/journal-foreign-35144/" target="_blank" rel="nofollow" class="tuijian_authcolor">Journal of Molecular Liquids .</a> <span>2017</span><span>,第期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：脂环基离子液体的阴离子，阴离子 - 锂，阳离子和离子对锂相互作用作为锂金属电池的电解质</span> </p> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704023798501.html">A stable lithium–selenium interface via solid/liquid hybrid electrolytes: Blocking polyselenides and suppressing lithium dendrite</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yucun Zhou&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Yucun Zhou,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhejun Li&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Zhejun Li,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yi-Chun Lu&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Yi-Chun Lu </a> <a href="/journal-foreign-25507/" target="_blank" rel="nofollow" class="tuijian_authcolor">Nano Energy .</a> <span>2017</span><span>,第期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：通过固体/液体杂交电解质的稳定锂 - 硒接口：阻断多糖苷，抑制锂枝晶</span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-conference-foreign_meeting-281967_thesis/0705016248465.html">MODELING THE ELECTRON TRANSFER REACTION AT THE LITHIUM METAL ANODE- LIQUID ELECTROLYTE INTERFACE IN LITHIUM- AIR BATTERIES</a> <b>[C]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Saeed Kazemiabnavi&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Saeed Kazemiabnavi,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Prashanta Dutta&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Prashanta Dutta,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Soumik Banerjee&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Soumik Banerjee </a> <a href="/conference-foreign-281967/" target="_blank" rel="nofollow" class="tuijian_authcolor">ACS National Meeting Exhibition .</a> <span>2015</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：锂电池锂金属阳极电解质界面的电子转移反应建模</span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-degree-foreign_mphd_thesis/02061576858.html">The Use of Mixed Organic/Ionic Liquid Electrolytes with Forcespun Metal Oxides/Carbon Microfiber Electrodes in Lithium Ion Batteries</a> <b>[D] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Villarreal, Jahaziel.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Villarreal, Jahaziel. </a> <span>2018</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：有机/离子液体电解质与强力纺丝金属氧化物/碳超细纤维电极在锂离子电池中的应用</span> </p> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-journal-foreign-pmc_detail_thesis/040006804459.html">Design rules for liquid crystalline electrolytes for enabling dendrite-free lithium metal batteries</a> <b>[O] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zeeshan Ahmad&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Zeeshan Ahmad,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zijian Hong&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Zijian Hong,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Venkatasubramanian Viswanathan&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Venkatasubramanian Viswanathan </a> <span>2020</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：液晶电解质的设计规则用于实现无树枝状锂金属电池</span> </p> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/open-access_resources_thesis/01000129381148.html">Design rules for liquid crystalline electrolytes for enabling dendrite-free lithium metal batteries</a> <b>[O] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zeeshan Ahmad&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Zeeshan Ahmad,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zijian Hong&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Zijian Hong,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Venkatasubramanian Viswanathan&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Venkatasubramanian Viswanathan </a> <span>2020</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：液晶电解质的设计规则，用于实现无树枝状锂金属电池</span> </p> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/academic-journal-cn_journal-materials-engineering_thesis/0201290085049.html">锂金属电池中复合固态电解质与负极界面的研究进展</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=朱晓琪&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 朱晓琪</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=葛性波&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,葛性波</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=张格非&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,张格非</a> <span> <a href="/journal-cn-7646/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 材料工程 </a> </span> <span> . 2021</span><span>,第006期</span> </span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/academic-journal-cn_detail_thesis/0201294725445.html">固态锂电池中金属锂负极与固体电解质界面的关键挑战</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=胡晨晨&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 胡晨晨</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=罗巍&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,罗巍</a> <span> <a href="/journal-cn-57080/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 分析科学学报 </a> </span> <span> . 2019</span><span>,第6期</span> </span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/academic-journal-cn_energy-storage-science-technology_thesis/0201289459550.html">液体电解液改性石榴石型固体电解质与锂负极的界面</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=池上森&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 池上森</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=温兆银&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,温兆银</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=邓永红&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,邓永红</a> <span> <a href="/journal-cn-8375/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 储能科学与技术 </a> </span> <span> . 2021</span><span>,第003期</span> </span> </div> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-journal-cn_chinese-battery-industry_thesis/0201290782377.html">锂金属负极中抑制锂枝晶生长的研究进展</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=陈涛&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 陈涛</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李晶泽&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,李晶泽</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=刘洪利&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,刘洪利</a> <span> <a href="/journal-cn-8468/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 电池工业 </a> </span> <span> . 2021</span><span>,第004期</span> </span> </div> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-journal-cn_yunnan-electric-power_thesis/0201293724969.html">能量密度高达500 Wh/kg液体锂硫和锂硒电池采用固体电解质</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . </a> <span> <a href="/journal-cn-15890/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 云南电力技术 </a> </span> <span> . 2019</span><span>,第S01期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-26790_thesis/020221707598.html">双向脉冲充电方法在锂二次电池中抑制锂枝晶生长的研究</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=陈玲&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 陈玲</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李雪莉&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,李雪莉</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=赵强&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,赵强</a> <span> <a href="/conference-cn-26790/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 第十三次全国电化学会议 </a> <span> <span> . 2005</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020315266857.html">不锈钢网集流体的表面亲锂改性及抑制锂金属枝晶生长的研究</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=梁杰铬&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 梁杰铬</a> <span> . 2019</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06120100880243.html">用于锂金属二次电池的液体电解质制剂和包含所述液体电解质制剂的锂金属二次电池</a> <b>[P]</b> . <span> 中国专利： CN109962286A </span> <span> . 2019-07-02</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120109326835.html">抑制全固态电池中锂枝晶生长的固态电解质及其制备方法</a> <b>[P]</b> . <span> 中国专利： CN106848392A </span> <span> . 2017-06-13</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130500194591.html">Liquid electrolyte formulation for lithium metal secondary battery and lithium metal secondary battery comprising said liquid electrolyte formulation</a> <b>[P]</b> . <span> 外国专利：  US11050090B2 </span> <span> . 2021-06-29</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：锂金属二次电池和锂金属二次电池的液体电解质配方，包括所述液体电解质配方 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130402258133.html">Liquid electrolyte composition for lithium metal secondary battery and lithium metal secondary battery having such liquid electrolyte composition</a> <b>[P]</b> . <span> 外国专利：  JP6744899B2 </span> <span> . 2020-08-19</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：用于锂金属二次电池的液体电解质组合物和具有该液体电解质组合物的锂金属二次电池 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130403263276.html">LIQUID ELECTROLYTE FORMULATION FOR LITHIUM METAL SECONDARY BATTERY AND LITHIUM METAL SECONDARY BATTERY COMPRISING SAID LIQUID ELECTROLYTE FORMULATION</a> <b>[P]</b> . <span> 外国专利：  KR20190076841A </span> <span> . 2019-07-02</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：用于金属锂二次电池的液体电解质配方和包含所述液体电解质配方的金属锂二次电池 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" onclick="ywcd('0704028161119','4',7,2,1,'',this,24)" class="delivery" prompt="010401" title="通过人工服务将文献原文发送至邮箱" >获取原文</div> <div class="journalsub-pop-up" style="display: none"> <div class="journal-sub"> <h2>期刊订阅</h2> <img src="https://cdn.zhangqiaokeyan.com/img/loginclose.png" alt="关闭" onclick="$('.journalsub-pop-up').hide()"> <p class="pardon">抱歉，该期刊暂不可订阅，敬请期待！</p> <p class="current">目前支持订阅全部北京大学中文核心（2020）期刊目录。</p> <div style="display: flex;margin-top: 69px;justify-content: space-between;"> <div class="no-sub" onclick="$('.journalsub-pop-up').hide()">暂不订阅</div> <div class="other-sub" onclick="continueSub('from=pc-detail')">继续订阅其他期刊</div> </div> </div> </div> <div class="right_btn"> <ul> <li class="gouwuche">  </li> <li class="yijian"> <a href="javascript:void(0);" onclick="link_analysis('/mycenter/auth/complaint.html',this)" title="意见反馈">意见反馈</a> </li> <li class="top"> <a href="javascript:scrollTo(0,0);" title="回到顶部">回到顶部</a> </li> <li class="shouye"> <a href="/" title="首页">回到首页</a> </li> </ul> </div> <div class="xllindexfooter"> <div class="xllindexfootercenter"> <div class="xllindexfooterleft left" > <div class="xllindexfooterleftli"> <ul> <li><a href="/about.html" title="关于掌桥">关于掌桥</a></li> <li><a href="/help/helpmap.html" title="资源导航">资源导航</a></li> <li><a href="/help/helpguide.html" title="新手指南">新手指南</a></li> <li><a href="/help/helpcenter.html" title="常见问题">常见问题</a></li> <li><a href="/sitemap.html" title="网站地图">网站地图</a></li> <li><a href="/help/helpcenter.html?type=9" title="版权声明">版权声明</a></li> </ul> </div> <div class="xllindexfooterleft"> <p class="xllindexfooterlefteamil">客服邮箱：kefu@zhangqiaokeyan.com</p> <div class="xllindexfooterlefttcp"> <div class="xllindexfooterpoliceiimg"></div> <div class="xllindexfooterpoliceispan"> <span>京公网安备：11010802029741号 </span> <span>ICP备案号：<a href="https://beian.miit.gov.cn" rel="nofollow" target="_blank" title="ICP备案号">京ICP备15016152号-6</a></span> <span>六维联合信息科技 (北京) 有限公司©版权所有</span> </div> </div> </div> </div> <div class="xllindexfooterright left"> <ul> <li> <p style="font-weight: bold;">客服微信</p> <div></div> </li> <li> <p style="font-weight: bold;">服务号</p> <div></div> </li> </ul> </div> </div> </div> <span id="0704028161119down" data-source="7," data-out-id="FFRiUrqoluRsCQpw6LNTc6Tc6DZYPIFOPpdcnm7xrpm3t/dbwC3vazTWk3H5yAX1," data-f-source-id="7" data-title="A Liquid/Liquid Electrolyte Interface that Inhibits Corrosion and Dendrite Growth of Lithium in Lithium‐Metal Batteries" data-price="20" data-site-name="" data-transnum="24" style="display:none;"></span> <input type="hidden" value="4" id="sourcetype"> <input type="hidden" value="19011" id="journalid"> <input type="hidden" value="1" id="inyn_provide_service_level"> <input type="hidden" value="https://cdn.zhangqiaokeyan.com" id="imgcdn"> <input type="hidden" value="1" id="isdeatail"> <input type="hidden" value="" id="syyn_indexed_database"> <input type="hidden" value="" id="servicetype"> <input type="hidden" id="pagename" value="A Liquid/Liquid Electrolyte Interface that Inhibits Corrosion and Dendrite Growth of Lithium in Lithium‐Metal Batteries"/> <input type="hidden" value="thesis_get_original" id="pageIdentification"> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/jquery-1.12.4.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/lwlh_ajax.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/zq.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/common.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/jquery.cookie.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/top.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/tip.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/login.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/down.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/search.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/newmail.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/searchtype.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/user/regist.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/zxs_solor/detail.js?v=5.7.8"></script> <script type="text/javascript" src="https://www.zhangqiaokeyan.com/statistics/static/pagecollection.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/tj.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/sse.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/pushbaidu.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/history.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/util/cookie.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/weipu/weipu.js?v=5.7.8"></script> </body> <script> $(function(){ var weiPuStatus = getCookie('WeiPuStatus'); if(weiPuStatus){ tipWeiPuStatus(weiPuStatus); delCookie('WeiPuStatus'); } getFacetKeywordVoInId(); var sourcetype = $("#sourcetype").val(); var inyn_provide_service_level = $("#inyn_provide_service_level").val(); if((sourcetype ==1||sourcetype==4)&&inyn_provide_service_level!=4){ getJournal(); } }) </script> </html>