Divergent Synthesis of Vinyl‐, Benzyl‐, and Borylsilanes: Aryl to Alkyl 1,5‐Palladium Migration/Coupling Sequences

Han Jie‐Lian; Qin Ying; Ju Cheng‐Wei; Zhao Dongbing

摘要

Abstract > Organosilicon compounds have been extensively utilized both in industry and academia. Studies on the syntheses of diverse organosilanes is highly appealing. Through‐space metal/hydrogen shifts allow functionalization of C?H bonds at a remote site, which are otherwise difficult to achieve. However, until now, an aryl to alkyl 1,5‐palladium migration process seems to have not been presented. Reported herein is the remote olefination, arylation, and borylation of a methyl group on silicon to access diverse vinyl‐, benzyl‐, and borylsilanes, constituting a unique C(sp 3 )?H transformation based on a 1,5‐palladium migration process. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 有机硅化合物已被广泛使用工业和学术界。对各种有机硅烷合成的研究非常吸引人。通过空间金属/氢气转换允许在遥控部位进行C 2 H键的官能化，否则难以实现。然而，直到现在，似乎尚未介绍1,5-钯迁移过程的芳基。本文报道的是硅上甲基的远程烯醇化，芳基化和硼化甲基，以进入各种乙烯基 - ，苄基 - 和硼硅烷，构成唯一的C（SP 3 </ sup> ）？基于1,5-钯迁移过程的转换。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-19011/'>《Angewandte Chemie》</a> <b style="margin: 0 2px;">|</b><span>2020年第16期</span><b style="margin: 0 2px;">|</b><span>共6页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Han Jie‐Lian&option=202" target="_blank" rel="nofollow">Han Jie‐Lian;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Qin Ying&option=202" target="_blank" rel="nofollow">Qin Ying;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ju Cheng‐Wei&option=202" target="_blank" rel="nofollow">Ju Cheng‐Wei;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhao Dongbing&option=202" target="_blank" rel="nofollow">Zhao Dongbing;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>State Key Laboratory and Institute of Elemento-Organic ChemistryNankai University94 Weijin Road Tianjin 300071 China;</p> <p>State Key Laboratory and Institute of Elemento-Organic ChemistryNankai University94 Weijin Road Tianjin 300071 China;</p> <p>State Key Laboratory and Institute of Elemento-Organic ChemistryNankai University94 Weijin Road Tianjin 300071 China;</p> <p>State Key Laboratory and Institute of Elemento-Organic ChemistryNankai University94 Weijin Road Tianjin 300071 China;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1188.html" title="应用化学">应用化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=cross-coupling&option=203" rel="nofollow">cross-coupling;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=palladium&option=203" rel="nofollow">palladium;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=reaction mechanisms&option=203" rel="nofollow">reaction mechanisms;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=silanes&option=203" rel="nofollow">silanes;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=synthetic methods&option=203" rel="nofollow">synthetic methods;</a> </p> <div class="translation"> 机译：交叉耦合;钯;反应机制;硅烷;合成方法; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704028161105.html">Divergent Synthesis of Vinyl‐, Benzyl‐, and Borylsilanes: Aryl to Alkyl 1,5‐Palladium Migration/Coupling Sequences</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Han Jie‐Lian&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Han Jie‐Lian,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Qin Ying&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Qin Ying,</a> <a 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rel="nofollow" class="tuijian_authcolor">Symposium on Organometallic Chemistry .</a> <span>2004</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：通过氧化添加到铂（O）复合物的氧化添加剂（O）复合物的二核烷基 - ，芳基和烯丙基 - 吡啶 - 吡啶（或-Palladium）配合物的合成与反应</span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-degree-foreign_mphd_thesis/02061321475.html">Synthesis of sterically-hindered 2,2-disubstituted ethyltrifluoroborate salts and their palladium-catalyzed cross-coupling with aryl and vinyl bromides.</a> <b>[D] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Guinn, Robert H.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Guinn, Robert H. </a> <span>2011</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: 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initial;text-overflow: initial;overflow: initial;"> <span>机译：芳基使Suzuki-Miyaura偶联至乙烯基14-钯迁移</span> </p> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/open-access_resources_thesis/01000125109903.html">Unsymmetrical Diaryl Sulfones and Aryl Vinyl Sulfones through Palladium-Catalyzed Coupling of Aryl and Vinyl Halides or Triflates with Sulfinic Acid Salts</a> <b>[O] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> </a> <span>-1</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：通过钯催化芳基和乙烯基卤化物的偶联或用亚硫酸盐的三分之三通过钯 - 催化的二芳基砜和芳基乙烯基砜</span> </p> </li> <li> <div> <b>8. </b><a class="enjiyixqcontent" href="/ntis-science-report_ad_thesis/020711442591.html">Palladium Catalyzed Coupling of F-Vinyl Zinc Reagents with Aryl Iodides. An Improved Synthesis of Alpha, Beta, Beta-Trifluorostyrenes and the Stereospecific Preparation of 1-Phenyl-F-Propenes</a> <b>[R] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Heinze, P. L.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Heinze, P. L.,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Burton, D. J.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Burton, D. J. </a> <span>1986</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：钯催化F-乙烯基锌试剂与芳基碘化物的偶联。 α，β，β-三氟苯乙烯的改进合成及1-苯基-F-丙烯的立体特异性制备</span> </p> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/academic-journal-cn_journal-inner-mongolia-normal-university-natural-science-edition_thesis/0201250342900.html">钯(0)催化芳硒基三甲基硅烷与芳基高碘盐的偶联:一种新的芳基硒醚合成方法</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=熊知行&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 熊知行</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=钟平&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,钟平</a> <span> <a href="/journal-cn-4682/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 内蒙古师范大学学报（自然科学汉文版） </a> </span> <span> . 2000</span><span>,第001期</span> </span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/academic-journal-cn_journal-jiangxi-institute-education_thesis/0201236900205.html">钯（0）催化芳硫基三甲基硅烷与芳基高碘盐的偶联：一种新的？…</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=熊知行&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 熊知行</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=钟平&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,钟平</a> <span> <a href="/journal-cn-4011/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 江西教育学院学报 </a> </span> <span> . 1999</span><span>,第003期</span> </span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/academic-journal-cn_henan-science_thesis/0201256780788.html">室温下钯/硫酰胺配体催化的芳基碘化物和烷基锌试剂的交叉偶联反应</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=刘菲&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 刘菲</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=崔炳春&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,崔炳春</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=赵胜勇&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,赵胜勇</a> <span> <a href="/journal-cn-5169/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 河南科学 </a> </span> <span> . 2015</span><span>,第010期</span> </span> </div> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-journal-cn_chinese-journal-applied-chemistry_thesis/0201272096773.html">2-烷基氨基-3-芳基-5-苄基-1-咪唑啉-4-酮的合成及杀菌活性</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=许志锋&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 许志锋</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=丁明武&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,丁明武</a> <span> <a href="/journal-cn-54377/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 应用化学 </a> </span> <span> . 2003</span><span>,第010期</span> </span> </div> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-journal-cn_journal-nanjing-normal-university-natural-science-edition_thesis/0201250295205.html">一类含多苯基芳基硅烷偶联剂的合成及应用</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=史保川&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 史保川</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=张锦华&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,张锦华</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=张宏&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,张宏</a> <span> <a href="/journal-cn-4678/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 南京师大学报（自然科学版） </a> </span> <span> . 1994</span><span>,第004期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-43259_thesis/020222758080.html">O-苄基羟胺与丙酸乙酯经缩合、Pd催化C(sp2)-H键芳基化和苄基C-O键溶剂解反应序列合成2-芳基苄基乙酸酯</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ling-Yan Shao&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . Ling-Yan Shao</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=邵玲艳&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,邵玲艳</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Li-Hao Xing&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,Li-Hao Xing</a> <span> <a href="/conference-cn-43259/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 中国药学会制药工程专业委员会2017年学术年会暨药包材与药品关联审评审批研讨会 </a> <span> <span> . 2017</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020315207116.html">钯催化下芳基苄基硒化物脱苄基交叉偶联合成二芳基硒化物</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王浩&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 王浩</a> <span> . 2019</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/061202836513.html">制备在格氏偶联反应中具有高选择性的二烷基‑二卤代硅烷、二芳基‑二卤代硅烷、和烷基芳基‑二卤代硅烷的方法</a> <b>[P]</b> . <span> 中国专利： CN105164140B </span> <span> . 2018.04.17</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120107648372.html">制备在格氏偶联反应中具有高选择性的二烷基-二卤代硅烷、二芳基-二卤代硅烷、和烷基芳基-二卤代硅烷的方法</a> <b>[P]</b> . <span> 中国专利： CN105164140A </span> <span> . 2015-12-16</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130436667712.html">Solid-phase catalysts containing palladium plus antimony, bismuth, tin and/or copper, useful for catalyzing acyloxylation of alkyl-aromatic compounds to give aryl esters, especially benzyl acetate</a> <b>[P]</b> . <span> 外国专利：  DE102004030525A1 </span> <span> . 2006-01-12</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：包含钯和锑，铋，锡和/或铜的固相催化剂，可用于催化烷基芳族化合物的酰氧基化反应，以生成芳基酯，特别是乙酸苄酯 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130439070461.html">Solid-phase catalysts containing palladium plus antimony, bismuth, tin and/or copper, useful for catalyzing acyloxylation of alkyl-aromatic compounds to give aryl esters, especially benzyl acetate</a> <b>[P]</b> . <span> 外国专利：  DE102004002262A1 </span> <span> . 2005-08-11</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：包含钯和锑，铋，锡和/或铜的固相催化剂，可用于催化烷基芳族化合物的酰氧基化反应，以生成芳基酯，特别是乙酸苄酯 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130467504836.html">3-Allyl, benzyl or heterocyclyl:methyl 3-cephem prepn. - by coupling 3-halomethyl 3-cephem with hydrocarbyl tri:alkyl stannane in polar aprotic solvent in presence of palladium cpd. and phosphine</a> <b>[P]</b> . <span> 外国专利：  PT87366A </span> <span> . 1989-11-10</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：3-烯丙基，苄基或杂环基：甲基3- Cephem prepn。 -在钯cpd存在下，在极性非质子传递溶剂中将3-卤代甲基3- Cephem与烃基三：烷基锡烷偶联。和膦 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" onclick="ywcd('0704028161105','4',7,2,1,'',this,24)" class="delivery" prompt="010401" title="通过人工服务将文献原文发送至邮箱" >获取原文</div> <div class="journalsub-pop-up" style="display: none"> <div class="journal-sub"> <h2>期刊订阅</h2> <img 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