High‐Performance K–CO2 Batteries Based on Metal‐Free Carbon Electrocatalysts

Zhang Wenchao; Hu Chuangang; Guo Zaiping; Dai Liming

摘要

Abstract > Metal–CO <sub>2</sub> batteries have attracted much attention owing to their high energy density and use of greenhouse CO <sub>2</sub> waste as the energy source. However, the increasing cost of lithium and the low discharge potential of Na–CO <sub>2</sub> batteries create obstacles for practical applications of Li/Na–CO <sub>2</sub> batteries. Recently, earth‐abundant potassium ions have attracted considerable interest as fast ionic charge carriers for electrochemical energy storage. Herein, we report the first K–CO <sub>2</sub> battery with a carbon‐based metal‐free electrocatalyst. The battery shows a higher theoretical discharge potential ( E ? =2.48?V) than that of Na–CO <sub>2</sub> batteries ( E ? =2.35?V) and can operate for more than 250 cycles (1500?h) with a cutoff capacity of 300?mA?h?g ?1 . Combined DFT calculations and experimental observations revealed a reaction mechanism involving the reversible formation and decomposition of P 12 <sub>1</sub> / c 1‐type K <sub>2</sub> CO <sub>3</sub> at the efficient carbon‐based catalyst. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 金属CO. <sub> 2 </ sub> 由于它们的高能量密度和温室有限公司使用，电池引起了很多关注 <sub> 2 </ sub> 废物作为能源。但是，锂的成本增加以及Na-Co的低放电潜力 <sub> 2 </ sub> 电池为Li / Na-Co的实际应用产生障碍 <sub> 2 </ sub> 电池。最近，地球丰富的钾离子吸引了相当大的兴趣作为电化学能量储存的快速离子电荷载体。在此，我们报告了第一个K-CO <sub> 2 </ sub> 电池用碳基无金属电催化剂。电池显示出较高的理论放电电位（ e </ i> ？</ sup> = 2.48？v）比NA-CO <sub> 2 </ sub> 电池（ e </ i> ？</ sup> = 2.35？v）并且可以使用300多个循环能力（1500Ωh）的截止值300？ma？h？g ？1 </ sup> 。组合的DFT计算和实验观察结果显示了涉及可逆形成和分解的反应机制 p </ i> 12. <sub> 1 </ sub> / c </ i> 1型k <sub> 2 </ sub> CO. <sub> 3 </ sub> 在高效的碳基催化剂。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-19011/'>《Angewandte Chemie》</a> <b style="margin: 0 2px;">|</b><span>2020年第9期</span><b style="margin: 0 2px;">|</b><span>共5页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhang Wenchao&option=202" target="_blank" rel="nofollow">Zhang Wenchao;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Hu Chuangang&option=202" target="_blank" rel="nofollow">Hu Chuangang;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Guo Zaiping&option=202" target="_blank" rel="nofollow">Guo Zaiping;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Dai Liming&option=202" target="_blank" rel="nofollow">Dai Liming;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Institute for Superconducting and Electronic Materials (ISEM)University of WollongongWollongong NSW 2500 Australia;</p> <p>Center of Advanced Science and Engineering for Carbon (Case4Carbon)Case Western Reserve University10900 Euclid Avenue Cleveland OH 44106 USA;</p> <p>Institute for Superconducting and Electronic Materials (ISEM)University of WollongongWollongong NSW 2500 Australia;</p> <p>Center of Advanced Science and Engineering for Carbon (Case4Carbon)Case Western Reserve University10900 Euclid Avenue Cleveland OH 44106 USA;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1188.html" title="应用化学">应用化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=batteries&option=203" rel="nofollow">batteries;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=carbon dioxide&option=203" rel="nofollow">carbon dioxide;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=carbon nanotubes&option=203" rel="nofollow">carbon nanotubes;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=electrocatalysis&option=203" rel="nofollow">electrocatalysis;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=graphene oxide&option=203" rel="nofollow">graphene oxide;</a> </p> <div class="translation"> 机译：电池;二氧化碳;碳纳米管;电殖分析;石墨烯氧化物; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704028160984.html">High‐Performance K–CO2 Batteries Based on Metal‐Free Carbon Electrocatalysts</a> <b>[J]</b> . <span> <a 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href="/conference-cn-20939/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 第二届中国储能与动力电池及其关键材料学术研讨会与技术交流会 </a> <span> <span> . 2007</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020313242037.html">无电电镀法制备高性能柔性金属网络透明导电薄膜并应用于太阳能电池</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=杨霞&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 杨霞</a> <span> . 2018</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06120103999119.html">一种燃料电池的碳负载金属催化剂的热处理方法及其制备的碳负载金属催化剂</a> <b>[P]</b> . <span> 中国专利： CN111370710A </span> <span> . 2020-07-03</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120109586619.html">金属复合碳材料、燃料电池用催化剂、燃料电池、氢吸藏材料、氢罐、以及金属复合碳材料的制造方法</a> <b>[P]</b> . <span> 中国专利： CN107073446A </span> <span> . 2017-08-18</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130407448276.html">Carbon nanotube-metal nanocomposites as flexible, free standing, binder free high performance anode for Li-ion battery</a> <b>[P]</b> . <span> 外国专利：  US10003075B2 </span> <span> . 2018-06-19</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：碳纳米管-金属纳米复合材料是用于锂离子电池的柔性，自立，无粘结剂的高性能阳极 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130412140549.html">Carbon nanotube-metal nanocomposites as flexible, free standing, binder free high performance anode for li-ion battery</a> <b>[P]</b> . <span> 外国专利：  IN2014DE01592A </span> <span> . 2015-12-18</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：碳纳米管-金属纳米复合材料是用于锂离子电池的柔性，自立，无粘结剂的高性能阳极 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130412763539.html">CARBON NANOTUBE-METAL NANOCOMPOSITES AS FLEXIBLE, FREE STANDING, BINDER FREE HIGH PERFORMANCE ANODE FOR LI –ION BATTERY</a> <b>[P]</b> . <span> 外国专利：  US2015364750A1 </span> <span> . 2015-12-17</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：碳纳米管金属纳米复合物，是用于锂电池的灵活，自由站立，无粘结剂的高性能阳极 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 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