Photosensitized Intermolecular Carboimination of Alkenes through the Persistent Radical Effect

Patra Tuhin; Bellotti Peter; Strieth‐Kalthoff Felix; Glorius Frank

摘要

Abstract >An intermolecular, two‐component vicinal carboimination of alkenes has been accomplished by energy transfer catalysis. Oxime esters of alkyl carboxylic acids were used as bifunctional reagents to generate both alkyl and iminyl radicals. Subsequently, addition of the alkyl radical to an alkene generates a transient radical for selective radical–radical cross‐coupling with the persistent iminyl radical. Furthermore, this process provides direct access to aliphatic primary amines and α‐amino acids by simple hydrolysis. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> >分子间，通过能量转移催化来完成烯烃的两个组分邻烷基氧化。烷基羧酸的肟酯用作双官能试剂，以产生烷基和乙炔基。随后，向烯烃中加入烷基产生瞬态基团，以与持续的乙炔基团选择性自由基交联。此外，该方法通过简单的水解，提供直接进入脂族伯胺和α-氨基酸。</ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-19011/'>《Angewandte Chemie》</a> <b style="margin: 0 2px;">|</b><span>2020年第8期</span><b style="margin: 0 2px;">|</b><span>共6页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Patra Tuhin&option=202" target="_blank" rel="nofollow">Patra Tuhin;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Bellotti Peter&option=202" target="_blank" rel="nofollow">Bellotti Peter;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Strieth‐Kalthoff Felix&option=202" target="_blank" rel="nofollow">Strieth‐Kalthoff Felix;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Glorius Frank&option=202" target="_blank" rel="nofollow">Glorius Frank;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Organisch-Chemisches InstitutWestf?lische Wilhelms-Universit?t MünsterCorrensstra?e 40 48149 Münster Germany;</p> <p>Organisch-Chemisches InstitutWestf?lische Wilhelms-Universit?t MünsterCorrensstra?e 40 48149 Münster Germany;</p> <p>Organisch-Chemisches InstitutWestf?lische Wilhelms-Universit?t MünsterCorrensstra?e 40 48149 Münster Germany;</p> <p>Organisch-Chemisches InstitutWestf?lische Wilhelms-Universit?t MünsterCorrensstra?e 40 48149 Münster Germany;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1188.html" title="应用化学">应用化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=amination&option=203" rel="nofollow">amination;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=carboxylic acids&option=203" rel="nofollow">carboxylic acids;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=cross-coupling&option=203" rel="nofollow">cross-coupling;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=energy transfer&option=203" rel="nofollow">energy transfer;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=photocatalysis&option=203" rel="nofollow">photocatalysis;</a> </p> <div class="translation"> 机译：胺化;羧酸;交叉耦合;能量转移;光催化; 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