Stable Salts of Heteroleptic Iron Carbonyl/Nitrosyl Cations

摘要

Abstract > The oxidation of Fe(CO) <sub>5</sub> with the [NO] + salt of the weakly coordinating perfluoroalkoxyaluminate anion [F‐{Al(OR F ) <sub>3</sub> } <sub>2</sub> ] ? (R F =C(CF <sub>3</sub> ) <sub>3</sub> ) leads to stable salts of the 18?valence electron (VE) species [Fe(CO) <sub>4</sub> (NO)] + and [Fe(CO)(NO) <sub>3</sub> ] + with the Enemark–Feltham numbers of {FeNO} 8 and {FeNO} 10 . This finally concludes the triad of heteroleptic iron carbonyl/nitrosyl complexes, since the first discovery of the anionic ([Fe(CO) <sub>3</sub> (NO)] ? ) and neutral ([Fe(CO) <sub>2</sub> (NO) <sub>2</sub> ]) species over 80?years ago. Both complexes were fully characterized (IR, Raman, NMR, UV/Vis, scXRD, pXRD) and are stable at room temperature under inert conditions over months and may serve as useful starting materials for further investigations. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > Fe（CO）的氧化 <sub> 5 </ sub> 随着[否] + </ sup> 弱配位全氟烷氧氧缺失阴离子[F- {Al（或 f </ sup> 的） <sub> 3 </ sub> } <sub> 2 </ sub> ] ？</ sup> （r. f </ sup> = C（CF <sub> 3 </ sub> 的） <sub> 3 </ sub> ）导致18°的稳定盐（Ve）物种[Fe（Co） <sub> 4 </ sub> （不）] + </ sup> 和[fe（co）（否） <sub> 3 </ sub> ] + </ sup> 与{feno}的enemark-feltham数量 8 </ sup> 和{feno} 10 </ sup> 。这最后总结了异致铁/亚硝基复合物的三合会，自阴离子的第一次发现（[Fe（Co） <sub> 3 </ sub> （不）] ？</ sup> ）和中立（[Fe（Co） <sub> 2 </ sub> （不） <sub> 2 </ sub> ]）超过80年的物种？几年前。两种复合物完全表征（IR，拉曼，NMR，UV / Vis，SCXRD，PXRD），并且在室温下在惰性条件下在几个月内稳定，并且可以作为进一步研究的有用的起始材料。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-19011/'>《Angewandte Chemie》</a> <b style="margin: 0 2px;">|</b><span>2020年第14期</span><b style="margin: 0 2px;">|</b><span>共5页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1188.html" title="应用化学">应用化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=carbonyl Ligands&option=203" rel="nofollow">carbonyl Ligands;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=iron(I)&option=203" rel="nofollow">iron(I);</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=nitrogen oxides&option=203" rel="nofollow">nitrogen oxides;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=vibrational spectroscopy&option=203" rel="nofollow">vibrational spectroscopy;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=weakly coordinating anions (WCAs)&option=203" rel="nofollow">weakly coordinating anions (WCAs);</a> </p> <div class="translation"> 机译：羰基配体;铁（I）;氮氧化物;振动光谱;弱协调阴离子（WCA）; 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href="/patent-detail/06120104839940.html">3－(2－{4－(己氧羰基氨基－亚氨基－甲基)－苯基氨基－甲基}－1－甲基－1H－苯并咪唑－5－羰基）－吡啶－2－基－氨基－丙酸乙酯及其盐的口服施用的投药剂型</a> <b>[P]</b> . <span> 中国专利： CN1638771A </span> <span> . 2005-07-13</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130462684196.html">Preparation of iron nitrosyl carbonyl catalyst</a> <b>[P]</b> . <span> 外国专利：  US5096870A </span> <span> . 1992-03-17</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：亚硝酰基羰基铁催化剂的制备 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130462668756.html">Electrochemical preparation of iron nitrosyl carbonyl and its use as a catalyst</a> <b>[P]</b> . <span> 外国专利：  US5112451A </span> <span> . 1992-05-12</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：亚硝酰基羰基铁的电化学制备及其作为催化剂的用途 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130464133278.html">Preparation of iron nitrosyl carbonyl catalyst</a> <b>[P]</b> . <span> 外国专利：  US5057469A </span> <span> . 1991-10-15</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：亚硝酰基羰基铁催化剂的制备 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" onclick="ywcd('0704028160940','4',7,2,1,'',this,24)" 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