Co‐syndiospecific Alternating Copolymerization of Functionalized Propylenes and Styrene by Rare‐Earth Catalysts

Wang Haobing; Wu Xia; Yang Yang; Nishiura Masayoshi; Hou Zhaomin

摘要

Abstract >The precise control of monomer sequence and stereochemistry in copolymerization is of much interest and importance for the synthesis of functional polymers, but studies toward this goal have met with only limited success to date. Now, the co‐syndiospecific alternating copolymerization of methoxyphenyl‐ and N,N‐dimethylaminophenyl‐functionalized propylenes with styrene by half‐sandwich rare‐earth catalysts is reported. This reaction efficiently afforded the corresponding functionalized propylene‐alt‐styrene copolymers with a perfect alternating sequence and excellent co‐syndiotacticity (rrrr 99?%), thus constituting the first example of co‐stereospecific alternating copolymerization of polar and non‐polar olefins. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> >在共聚中的单体序列和立体化学的精确控制对于合成功能聚合物具有很大的感兴趣，但对该目标的研究仅达到了有限的成功。现在，报道了通过半夹心稀土催化剂的甲氧基苯基 - 和N，N-二甲基氨基苯基官能化丙烯与苯乙烯的共同结构交替共聚。该反应有效地提供了相应的官能化丙烯-ATR-苯乙烯共聚物，其具有完美的交替顺序和优异的共同形状（RRRR＆GT; 99〜％），因此构成了极性和非极性烯烃的共同特异性交替共聚的第一实例。</ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-19011/'>《Angewandte Chemie》</a> <b style="margin: 0 2px;">|</b><span>2020年第18期</span><b style="margin: 0 2px;">|</b><span>共5页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wang Haobing&option=202" target="_blank" rel="nofollow">Wang Haobing;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wu Xia&option=202" target="_blank" rel="nofollow">Wu Xia;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yang Yang&option=202" target="_blank" rel="nofollow">Yang Yang;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Nishiura Masayoshi&option=202" target="_blank" rel="nofollow">Nishiura Masayoshi;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Hou Zhaomin&option=202" target="_blank" rel="nofollow">Hou Zhaomin;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Advanced Catalysis Research GroupRIKEN Center for Sustainable Resource Science2-1 Hirosawa Wako Saitama 351-0198 Japan;</p> <p>Advanced Catalysis Research GroupRIKEN Center for Sustainable Resource Science2-1 Hirosawa Wako Saitama 351-0198 Japan;</p> <p>Advanced Catalysis Research GroupRIKEN Center for Sustainable Resource Science2-1 Hirosawa Wako Saitama 351-0198 Japan;</p> <p>Advanced Catalysis Research GroupRIKEN Center for Sustainable Resource Science2-1 Hirosawa Wako Saitama 351-0198 Japan;</p> <p>Advanced Catalysis Research GroupRIKEN Center for Sustainable Resource Science2-1 Hirosawa Wako Saitama 351-0198 Japan;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1188.html" title="应用化学">应用化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=alternating sequence control&option=203" rel="nofollow">alternating sequence control;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=copolymerization&option=203" rel="nofollow">copolymerization;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=olefins&option=203" rel="nofollow">olefins;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=rare-earth catalysts&option=203" rel="nofollow">rare-earth catalysts;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=stereoselectivity&option=203" rel="nofollow">stereoselectivity;</a> </p> <div class="translation"> 机译：交替的顺序控制;共聚;烯烃;稀土催化剂;立体选择性; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704028160884.html">Co‐syndiospecific Alternating Copolymerization of Functionalized Propylenes and Styrene by Rare‐Earth Catalysts</a> 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href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Lin Li&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Lin Li,</a> <span>2017</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：带有萘桥型氮磺酸磺酸盐配体的钒配合物作为乙烯和丙烯共聚的催化剂</span> </p> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/open-access_resources_thesis/01000132181261.html">Copolymerization of Propylene and Styrene Derivatives with Al(C2H5)3-TiCl3 Catalyst</a> <b>[O] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ikuya HAYASHI&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Ikuya HAYASHI </a> <span>1965</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：丙烯和苯乙烯衍生物与Al（C2H5）3-TiCl3催化剂的共聚</span> </p> </li> <li> <div> <b>8. </b><a class="enjiyixqcontent" href="/ntis-science-report_pb_thesis/02071960222.html">Review on Styrene Homopolymerization and Copolymerization with Ethylene UsingGroup 4A Catalyst Compounds</a> <b>[R] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Aaltonen, P.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Aaltonen, P.,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Seppaelae, J. V.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Seppaelae, J. V. </a> <span>1992</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：用4a族催化剂化合物研究苯乙烯均聚和与乙烯的共聚合</span> </p> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/academic-journal-cn_detail_thesis/0201294233972.html">新型阳离子（甲基丙烯酸季铵盐酯－苯乙烯）共聚物的研究──Ⅰ阳离子（甲基丙烯酸二甲氨基乙酯溴代正丁烷盐－苯乙烯）共聚物的合成与表征</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=赵常礼&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 赵常礼</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=程远杰&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,程远杰</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李晶&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,李晶</a> <span> <a href="/journal-cn-57577/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 沈阳化工学院学报 </a> </span> <span> . 1996</span><span>,第3期</span> </span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/academic-journal-cn_journal-functional-polymers_thesis/0201232659363.html">新型阳离子(苯乙烯—丙烯酰胺)共聚物的研究Ⅱ.阳离子(苯乙烯——丙烯酰胺)共聚物与染料的相互作用</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=臧庆达&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 臧庆达</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李卓美&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,李卓美</a> <span> <a href="/journal-cn-11101/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 功能高分子学报 </a> </span> <span> . 1993</span><span>,第001期</span> </span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/academic-journal-cn_journal-functional-polymers_thesis/0201232671130.html">新型阳离子(苯乙烯—丙烯酰胺)共聚物的研究 Ⅰ.阳离子(苯乙烯—丙烯酰胺)共聚物的合成和表征</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=臧庆达&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 臧庆达</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李卓美&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,李卓美</a> <span> <a href="/journal-cn-11101/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 功能高分子学报 </a> </span> <span> . 1992</span><span>,第004期</span> </span> </div> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-journal-cn_china-synthetic-rubber-industry_thesis/0201271044888.html">用偶联法合成极性官能化苯乙烯-丁二烯-苯乙烯嵌段共聚物</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李静静&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 李静静</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=倪春霞&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,倪春霞</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=梁志斌&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,梁志斌</a> <span> <a href="/journal-cn-9131/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 合成橡胶工业 </a> </span> <span> . 2019</span><span>,第001期</span> </span> </div> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-journal-cn_china-synthetic-rubber-industry_thesis/0201246712482.html">以西弗碱为封端剂原位合成官能化苯乙烯-丁二烯-苯乙烯嵌段共聚物</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=廖明义&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 廖明义</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=郑仰才&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,郑仰才</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=金美花&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,金美花</a> <span> <a href="/journal-cn-9131/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 合成橡胶工业 </a> </span> <span> . 2008</span><span>,第002期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-31747_thesis/02022431935.html">1-(2-叔丁基过氧化异丙基)-3-异丙烯基苯和苯乙烯的自由基共聚反应及其在共聚物上的接枝研究</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=郭行蓬&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 郭行蓬</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李志昂&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,李志昂</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=杜强国&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,杜强国</a> <span> <a href="/conference-cn-31747/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 2001年全国高分子学术报告会 </a> <span> <span> . 2001</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020314925202.html">稀土催化剂在高分子合成中新应用—CO/苯乙烯及IP/极性单体共聚合研究</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=郑荣华&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 郑荣华</a> <span> . 1998</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06120448017.html">丙烯腈－苯乙烯共聚树脂/丙烯腈－氯化聚乙烯－苯乙烯共聚树脂塑料合金的制造方法</a> <b>[P]</b> . <span> 中国专利： CN100439444C </span> <span> . 2008.12.03</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120412063.html">阻燃丙烯腈－苯乙烯共聚树脂/丙烯腈－氯化聚乙烯－苯乙烯共聚树脂塑料合金的制造方法</a> <b>[P]</b> . <span> 中国专利： CN100402603C </span> <span> . 2008.07.16</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130448213706.html">A process for the copolymerization of conjugated diolefins (are) and vinylaromatic monomers with catalysts of the rare earths as well as the use of the copolymers in rubber mixtures for tire applications</a> <b>[P]</b> . <span> 外国专利：  DE19939842A1 </span> <span> . 2001-03-01</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：共轭二烯烃（和）和乙烯基芳族单体与稀土催化剂的共聚方法以及该共聚物在轮胎用橡胶混合物中的用途 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130442598890.html">Copolymerization of conjugated dienes with non-conjugated olefins by means of rare earth catalysts</a> <b>[P]</b> . <span> 外国专利：  US6706830B2 </span> <span> . 2004-03-16</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：稀土催化剂使共轭二烯与非共轭烯烃共聚 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130446892316.html">Method for the copolymerization of conjugated diolefins (dienes) and vinyl-aromatic monomers with rare-earth catalysts and use of the copolymers in rubber mixtures for tire applications</a> <b>[P]</b> . <span> 外国专利：  US6399726B1 </span> <span> . 2002-06-04</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：共轭二烯烃（二烯）和乙烯基芳族单体与稀土催化剂的共聚方法以及该共聚物在轮胎用橡胶混合物中的用途 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div 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