2D and 3D Porphyrinic Covalent Organic Frameworks: The Influence of Dimensionality on Functionality

Meng Yi; Luo Yi; Shi Ji‐Long; Ding Huimin; Lang Xianjun; Chen Wei; Zheng Anmin; Sun Junliang; Wang Cheng

摘要

Abstract > The construction of 2D and 3D covalent organic frameworks (COFs) from functional moieties for desired properties has gained much attention. However, the influence of COFs dimensionality on their functionalities, which can further assist in COF design, has never been explored. Now, by selecting designed precursors and topology diagrams, 2D and 3D porphyrinic COFs (2D‐PdPor‐COF and 3D‐PdPor‐COF) are synthesized. By model building and Rietveld refinement of powder X‐ray diffraction, 2D‐PdPor‐COF crystallizes as 2D sheets while 3D‐PdPor‐COF adopts a five‐fold interpenetrated pts topology. Interestingly, compared with 2D‐PdPor‐COF, 3D‐PdPor‐COF showed interesting properties, including 1)?higher CO <sub>2</sub> adsorption capacity; 2)?better photocatalytic performance; and 3)?size‐selective photocatalysis. Based on this study, we believe that with the incorporation of functional moieties, the dimensionality of COFs can definitely influence their functionalities. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 从功能部分进行所需性能的2D和3D共价有机骨架（COF）的构建已经受到很多关注。然而，COFS维度对其功能的影响，可以进一步协助COF设计，从未被探索过。现在，通过选择设计的前体和拓扑图，合成了2D和3D卟啉COF（2D-PDPOR-COF和3D-PDPOR-COF）。通过模型建筑和粉末X射线衍射的RIETVELD改进，2D-PDPOR-COF作为2D薄片结晶，而3D-Pdpor-COF采用五倍的渗透 pts </ b> 拓扑。有趣的是，与2D-PDPOR-COF相比，3D-PDPOR-COF显示了有趣的性质，包括1）？更高的CO <sub> 2 </ sub> 吸附能力; 2）？更好的光催化性能; 3）？大小选择性光催化。基于这项研究，我们认为，通过掺入功能部分，COF的维度绝对可以影响其功能。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-19011/'>《Angewandte Chemie》</a> <b style="margin: 0 2px;">|</b><span>2020年第9期</span><b style="margin: 0 2px;">|</b><span>共6页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Meng Yi&option=202" target="_blank" rel="nofollow">Meng Yi;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Luo Yi&option=202" target="_blank" rel="nofollow">Luo Yi;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Shi Ji‐Long&option=202" target="_blank" rel="nofollow">Shi Ji‐Long;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ding Huimin&option=202" target="_blank" rel="nofollow">Ding Huimin;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Lang Xianjun&option=202" target="_blank" rel="nofollow">Lang Xianjun;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Chen Wei&option=202" target="_blank" rel="nofollow">Chen Wei;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zheng Anmin&option=202" target="_blank" rel="nofollow">Zheng Anmin;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Sun Junliang&option=202" target="_blank" rel="nofollow">Sun Junliang;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wang Cheng&option=202" target="_blank" rel="nofollow">Wang Cheng;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Sauvage Center for Molecular Sciences and Hubei Key Lab on Organic and Polymeric Optoelectronic MaterialsWuhan UniversityWuhan 430072 China;</p> <p>College of Chemistry and Molecular EngineeringPeking UniversityBeijing 100871 China;</p> <p>Sauvage Center for Molecular Sciences and Hubei Key Lab on Organic and Polymeric Optoelectronic MaterialsWuhan UniversityWuhan 430072 China;</p> <p>Sauvage Center for Molecular Sciences and Hubei Key Lab on Organic and Polymeric Optoelectronic MaterialsWuhan UniversityWuhan 430072 China;</p> <p>Sauvage Center for Molecular Sciences and Hubei Key Lab on Organic and Polymeric Optoelectronic MaterialsWuhan UniversityWuhan 430072 China;</p> <p>State Key Laboratory of Magnetic Resonance and Atomic and Molecular PhysicsChinese Academy of SciencesWuhan 430071 China;</p> <p>State Key Laboratory of Magnetic Resonance and Atomic and Molecular PhysicsChinese Academy of SciencesWuhan 430071 China;</p> <p>College of Chemistry and Molecular EngineeringPeking UniversityBeijing 100871 China;</p> <p>Sauvage Center for Molecular Sciences and Hubei Key Lab on Organic and Polymeric Optoelectronic MaterialsWuhan UniversityWuhan 430072 China;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1188.html" title="应用化学">应用化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=CO2 adsorption&option=203" rel="nofollow">CO2 adsorption;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=COFs&option=203" rel="nofollow">COFs;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=dimensionality effect&option=203" rel="nofollow">dimensionality effect;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=functional moieties&option=203" rel="nofollow">functional moieties;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=size-selective catalysis&option=203" rel="nofollow">size-selective catalysis;</a> </p> <div class="translation"> 机译：CO2吸附;COFS;维度效应;功能部分;大小选择性催化; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704028160883.html">2D and 3D Porphyrinic Covalent Organic Frameworks: The Influence of 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