NHC‐Stabilized Iridium Nanoparticles as Catalysts in Hydrogen Isotope Exchange Reactions of Anilines

Valero Mégane; Bouzouita Donia; Palazzolo Alberto; Atzrodt Jens; Dugave Christophe; Tricard Simon; Feuillastre Sophie; Pieters Grégory; Chaudret Bruno; Derdau Volker

摘要

Abstract > The preparation of N‐heterocyclic carbene‐stabilized iridium nanoparticles and their application in hydrogen isotope exchange reactions is reported. These air‐stable and easy‐to‐handle iridium nanoparticles showed a unique catalytic activity, allowing selective and efficient hydrogen isotope incorporation on anilines using D <sub>2</sub> or T <sub>2</sub> as isotopic source. The usefulness of this transformation has been demonstrated by the deuterium and tritium labeling of diverse complex pharmaceuticals. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 据报道了N-杂环稳定铱纳米粒子的制备及其在同位素交换反应中的应用。这些空气稳定且易于处理的铱纳米颗粒显示出独特的催化活性，允许使用D的选择性和有效的氢同位素掺入苯胺 <sub> 2 </ sub> 或t. <sub> 2 </ sub> 作为同位素来源。氘和氚标记的不同复杂药物的氘标记已经证明了这种转化的有用性。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-19011/'>《Angewandte Chemie》</a> <b style="margin: 0 2px;">|</b><span>2020年第9期</span><b style="margin: 0 2px;">|</b><span>共6页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Valero Mégane&option=202" target="_blank" rel="nofollow">Valero Mégane;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Bouzouita Donia&option=202" target="_blank" rel="nofollow">Bouzouita Donia;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Palazzolo Alberto&option=202" target="_blank" rel="nofollow">Palazzolo Alberto;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Atzrodt Jens&option=202" target="_blank" rel="nofollow">Atzrodt Jens;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Dugave Christophe&option=202" target="_blank" rel="nofollow">Dugave Christophe;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Tricard Simon&option=202" target="_blank" rel="nofollow">Tricard Simon;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Feuillastre Sophie&option=202" target="_blank" rel="nofollow">Feuillastre Sophie;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Pieters Grégory&option=202" target="_blank" rel="nofollow">Pieters Grégory;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Chaudret Bruno&option=202" target="_blank" rel="nofollow">Chaudret Bruno;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Derdau Volker&option=202" target="_blank" rel="nofollow">Derdau Volker;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Integrated Drug DiscoverySanofi-Aventis (Deutschland) GmbH R&</p> <p>DIndustriepark H?chst 65926 Frankfurt am Main Germany;</p> <p>LPCNO Laboratoire de Physique et Chimie de Nano-ObjetsInstitut National des Sciences Appliquées135 Avenue de Rangueil 31077 Toulouse France;</p> <p>SCBMUniversité Paris-Saclay91191 Gif-sur-Yvette France;</p> <p>Integrated Drug DiscoverySanofi-Aventis (Deutschland) GmbH R&</p> <p>DIndustriepark H?chst 65926 Frankfurt am Main Germany;</p> <p>SCBMUniversité Paris-Saclay91191 Gif-sur-Yvette France;</p> <p>LPCNO Laboratoire de Physique et Chimie de Nano-ObjetsInstitut National des Sciences Appliquées135 Avenue de Rangueil 31077 Toulouse France;</p> <p>SCBMUniversité Paris-Saclay91191 Gif-sur-Yvette France;</p> <p>SCBMUniversité Paris-Saclay91191 Gif-sur-Yvette France;</p> <p>LPCNO Laboratoire de Physique et Chimie de Nano-ObjetsInstitut National des Sciences Appliquées135 Avenue de Rangueil 31077 Toulouse France;</p> <p>Integrated Drug DiscoverySanofi-Aventis (Deutschland) GmbH R&</p> <p>DIndustriepark H?chst 65926 Frankfurt am Main Germany;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1188.html" title="应用化学">应用化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=C?H activation&option=203" rel="nofollow">C?H activation;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=C?H functionalization&option=203" rel="nofollow">C?H functionalization;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=heterogeneous catalysis&option=203" rel="nofollow">heterogeneous catalysis;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=hydrogen isotope exchange&option=203" rel="nofollow">hydrogen isotope exchange;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=iridium nanoparticles&option=203" rel="nofollow">iridium nanoparticles;</a> </p> <div class="translation"> 机译：C？H激活;C？H官能化;异质催化;氢同位素交换;铱纳米粒子; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704028160875.html">NHC‐Stabilized Iridium Nanoparticles as Catalysts in Hydrogen 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</span> </div> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-journal-cn_precious-metals_thesis/0201221526396.html">反应条件对铱基催化剂催化甲醇羰基化反应产物的影响</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=郑修成&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 郑修成</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=张守民&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,张守民</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=黄唯平&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,黄唯平</a> <span> <a href="/journal-cn-8129/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 贵金属 </a> </span> <span> . 2003</span><span>,第001期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-14110_thesis/020221066902.html">磷酸对铱系催化剂羰基化反应性能的影响</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=刘博&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 刘博</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王世亮&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,王世亮</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李彤&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,李彤</a> <span> <a href="/conference-cn-14110/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 中国化工学会2010年石油化工学术年会 </a> <span> <span> . 2010</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020314035731.html">金属铱和NHC卡宾协同催化对硝基苯甲醛与不饱和酯的烯丙基化反应及磁性Fe3O4担载的金属钌催化剂的设计、合成及应用</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=翟宁宁&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 翟宁宁</a> <span> . 2017</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06120856261.html">水热稳定性的氢气选择性催化燃烧反应的催化剂</a> <b>[P]</b> . <span> 中国专利： CN101491779B </span> <span> . 2011.11.30</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120105692435.html">水热稳定性的氢气选择性催化燃烧反应的催化剂</a> <b>[P]</b> . <span> 中国专利： CN101491779A </span> <span> . 2009-07-29</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130421802871.html">METHOD OF PRODUCING Ag/SiO<Sub>2</Sub> CATALYST FOR HETEROGENEOUS CATALYSIS OF MOLECULAR HYDROGEN IN PROTIUM-DEUTERIUM ISOTOPIC EXCHANGE REACTIONS AND ORTHO-PARA CONVERSION OF PROTIUM</a> <b>[P]</b> . <span> 外国专利：  RU2461413C1 </span> <span> . 2012-09-20</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：生产Ag / SiO <Sub> 2 </ Sub>催化剂的方法，用于异质催化丙烷-氘同位素交换反应中的氢和OR的邻-偶数转化 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130421802872.html">METHOD OF PRODUCING Ag/SiO<Sub>2</Sub> CATALYST FOR HETEROGENEOUS CATALYSIS OF MOLECULAR HYDROGEN IN PROTIUM-DEUTERIUM ISOTOPIC EXCHANGE REACTIONS AND ORTHO-PARA CONVERSION OF PROTIUM</a> <b>[P]</b> . <span> 外国专利：  RU2461412C1 </span> <span> . 2012-09-20</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：生产Ag / SiO <Sub> 2 </ Sub>催化剂的方法，用于异质催化丙烷-氘同位素交换反应中的氢和OR的邻-偶数转化 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130450289269.html">Multi-tubular catalyst tower for hydrogen isotope exchange reaction between hydrogen and water</a> <b>[P]</b> . <span> 外国专利：  KR19990080570A </span> <span> . 1999-11-15</span> </div> <p class="zwjiyix 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