Graphitic Carbon Nitride (g‐C3N4): An Interface Enabler for Solid‐State Lithium Metal Batteries

Huang Ying; Chen Bo; Duan Jian; Yang Fei; Wang Tengrui; Wang Zhengfeng; Yang Wenjuan; Hu Chenchen; Luo Wei; Huang Yunhui

摘要

Abstract > Solid‐state Li metal batteries (SSLMBs) have attracted considerable interests due to their promising energy density as well as high safety. However, the realization of a well‐matched Li metal/solid‐state electrolyte (SSE) interface remains challenging. Herein, we report g‐C <sub>3</sub> N <sub>4</sub> as a new interface enabler. We discover that introducing g‐C <sub>3</sub> N <sub>4</sub> into Li metal can not only convert the Li metal/garnet‐type SSE interface from point contact to intimate contact but also greatly enhance the capability to suppress the dendritic Li formation because of the greatly enhanced viscosity, decreased surface tension of molten Li, and the in?situ formation of Li <sub>3</sub> N at the interface. Thus, the resulting Li‐C <sub>3</sub> N <sub>4</sub> |SSE|Li‐C <sub>3</sub> N <sub>4</sub> symmetric cell gives a significantly low interfacial resistance of 11?Ω?cm 2 and a high critical current density (CCD) of 1500?μA?cm ?2 . In contrast, the same symmetric cell configuration with pristine Li metal electrodes has a much larger interfacial resistance (428?Ω?cm 2 ) and a much lower CCD (50?μA?cm ?2 ). </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 固态Li金属电池（SSLMBS）由于其有希望的能量密度和高安全性而引起了相当大的兴趣。然而，实现匹配良好的Li金属/固态电解质（SSE）界面仍然具有挑战性。在此，我们报告G-C <sub> 3 </ sub> N. <sub> 4 </ sub> 作为新的接口启动器。我们发现介绍G-C <sub> 3 </ sub> N. <sub> 4 </ sub> 进入锂金属不仅可以将Li Metal / Garnet型SSE界面转换为密码接触，也大大提高了抑制树突式锂形成的能力，因为粘度大大提高，熔融李的表面张力下降，和in？原位形成李 <sub> 3 </ sub> n在界面。因此，得到的Li-C. <sub> 3 </ sub> N. <sub> 4 </ sub> | SSE | LI-C <sub> 3 </ sub> N. <sub> 4 </ sub> 对称电池给出11ΩΩΩcm的明显低界面电阻 2 </ sup> 和1500ΩμA的高临界电流密度（CCD）？2 </ sup> 。相反，具有原始Li金属电极的相同对称电池构造具有更大的界面电阻（428ΩΩcm 2 </ sup> ）和更低的CCD（50？μA？cm ？2 </ sup> ）。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-19011/'>《Angewandte Chemie》</a> <b style="margin: 0 2px;">|</b><span>2020年第9期</span><b style="margin: 0 2px;">|</b><span>共6页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Huang Ying&option=202" target="_blank" rel="nofollow">Huang Ying;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Chen Bo&option=202" target="_blank" rel="nofollow">Chen Bo;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Duan Jian&option=202" target="_blank" rel="nofollow">Duan Jian;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yang Fei&option=202" target="_blank" rel="nofollow">Yang Fei;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wang Tengrui&option=202" target="_blank" rel="nofollow">Wang Tengrui;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wang Zhengfeng&option=202" target="_blank" rel="nofollow">Wang Zhengfeng;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yang Wenjuan&option=202" target="_blank" rel="nofollow">Yang Wenjuan;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Hu Chenchen&option=202" target="_blank" rel="nofollow">Hu Chenchen;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Luo Wei&option=202" target="_blank" rel="nofollow">Luo Wei;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Huang Yunhui&option=202" target="_blank" rel="nofollow">Huang Yunhui;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Institute of New Energy for VehiclesTongji UniversityShanghai 201804 P. R. China;</p> <p>Institute of New Energy for VehiclesTongji UniversityShanghai 201804 P. R. China;</p> <p>Institute of New Energy for VehiclesTongji UniversityShanghai 201804 P. R. China;</p> <p>Institute of New Energy for VehiclesTongji UniversityShanghai 201804 P. R. China;</p> <p>Institute of New Energy for VehiclesTongji UniversityShanghai 201804 P. R. China;</p> <p>Institute of New Energy for VehiclesTongji UniversityShanghai 201804 P. R. China;</p> <p>Institute of New Energy for VehiclesTongji UniversityShanghai 201804 P. R. China;</p> <p>Institute of New Energy for VehiclesTongji UniversityShanghai 201804 P. R. China;</p> <p>Institute of New Energy for VehiclesTongji UniversityShanghai 201804 P. R. China;</p> <p>Institute of New Energy for VehiclesTongji UniversityShanghai 201804 P. R. China;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1188.html" title="应用化学">应用化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=graphitic carbon nitride&option=203" rel="nofollow">graphitic carbon nitride;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=interfacial compatibility&option=203" rel="nofollow">interfacial compatibility;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Li dendrites&option=203" rel="nofollow">Li dendrites;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=solid-state electrolytes&option=203" rel="nofollow">solid-state electrolytes;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=solid-state lithium metal batteries&option=203" rel="nofollow">solid-state lithium metal batteries;</a> </p> <div class="translation"> 机译：石墨碳氮化物;界面相容性;李蕾丝;固态电解质;固态锂金属电池; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704028160858.html">Graphitic Carbon Nitride (g‐C3N4): An Interface Enabler for 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</li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/061204941645.html">一种固体电解质/金属锂界面的缓释改性方法以及固态锂金属电池</a> <b>[P]</b> . <span> 中国专利： CN111900485B </span> <span> . 2022.03.04</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120111620625.html">一种固体电解质/金属锂界面的缓释改性方法以及固态锂金属电池</a> <b>[P]</b> . <span> 中国专利： CN111900485A </span> <span> . 2020-11-06</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130404446526.html">Lithium metal anode comprising Langmuir-Blodgett films as an artificial solid electrolyte interface layer, lithium metal battery comprising the same, and preparation method thereof</a> <b>[P]</b> . <span> 外国专利：  US10243197B2 </span> <span> . 2019-03-26</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：包含Langmuir-Blodgett膜作为人造固体电解质界面层的锂金属阳极，包括该锂金属电池的锂金属电池及其制备方法 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130407216112.html">LITHIUM METAL ANODE COMPRISING LANGMUIR-BLODGETT FILMS AS AN ARTIFICIAL SOLID ELECTROLYTE INTERFACE LAYER, LITHIUM METAL BATTERY COMPRISING THE SAME, AND PREPARATION METHOD THEREOF</a> <b>[P]</b> . <span> 外国专利：  US2018123114A1 </span> <span> . 2018-05-03</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：包含作为人工固体电解质界面层的Langmuir-BloDGett膜的金属锂阳极，包括该膜的锂金属电池及其制备方法 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130416680699.html">METHOD FOR SYNTHESIZING NANOCARBON-METAL/METAL OXIDE HYBRIDS VIA SOLID-SOLVOTHERMAL PROCESS, NANOCARBON-METAL/METAL OXIDE HYBRIDS, AND LITHIUM ION REACHARGEABLE BATTERIES USING THE SAME</a> <b>[P]</b> . <span> 外国专利：  KR101409693B1 </span> <span> . 2014-06-20</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：固液热法合成纳米碳/金属氧化物杂化物，纳米碳/金属氧化物杂化物以及锂离子可再充电电池的方法 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" onclick="ywcd('0704028160858','4',7,2,1,'',this,24)" class="delivery" prompt="010401" title="通过人工服务将文献原文发送至邮箱" >获取原文</div> <div class="journalsub-pop-up" style="display: none"> <div class="journal-sub"> <h2>期刊订阅</h2> <img src="https://cdn.zhangqiaokeyan.com/img/loginclose.png" alt="关闭" 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