Nickel‐Catalyzed Electrochemical Reductive Relay Cross‐Coupling of Alkyl Halides to Aryl Halides

Jiao Ke‐Jin; Liu Dong; Ma Hong‐Xing; Qiu Hui; Fang Ping; Mei Tian‐Sheng

摘要

Abstract >A highly regioselective Ni‐catalyzed electrochemical reductive relay cross‐coupling between an aryl halide and an alkyl halide has been developed in an undivided cell. Various functional groups are tolerated under these mild reaction conditions, which provides an alternative approach for the synthesis of 1,1‐diarylalkanes. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> >在一个未分割的细胞中开发了芳基卤化物和烷基卤化物之间的高度区域选择性的电化学还原继电器交联偶联。在这些温和的反应条件下耐受各种官能团，其为合成1,1-二芳基烷烃提供替代方法。</ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-19011/'>《Angewandte Chemie》</a> <b style="margin: 0 2px;">|</b><span>2020年第16期</span><b style="margin: 0 2px;">|</b><span>共5页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Jiao Ke‐Jin&option=202" target="_blank" rel="nofollow">Jiao Ke‐Jin;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Liu Dong&option=202" target="_blank" rel="nofollow">Liu Dong;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ma Hong‐Xing&option=202" target="_blank" rel="nofollow">Ma Hong‐Xing;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Qiu Hui&option=202" target="_blank" rel="nofollow">Qiu Hui;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Fang Ping&option=202" target="_blank" rel="nofollow">Fang Ping;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Mei Tian‐Sheng&option=202" target="_blank" rel="nofollow">Mei Tian‐Sheng;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>State Key Laboratory of Organometallic ChemistryChinese Academy of Sciences345 Lingling Road Shanghai 200032 China;</p> <p>State Key Laboratory of Organometallic ChemistryChinese Academy of Sciences345 Lingling Road Shanghai 200032 China;</p> <p>State Key Laboratory of Organometallic ChemistryChinese Academy of Sciences345 Lingling Road Shanghai 200032 China;</p> <p>State Key Laboratory of Organometallic ChemistryChinese Academy of Sciences345 Lingling Road Shanghai 200032 China;</p> <p>State Key Laboratory of Organometallic ChemistryChinese Academy of Sciences345 Lingling Road Shanghai 200032 China;</p> <p>State Key Laboratory of Organometallic ChemistryChinese Academy of Sciences345 Lingling Road Shanghai 200032 China;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1188.html" title="应用化学">应用化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=arenes&option=203" rel="nofollow">arenes;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=cross-coupling&option=203" rel="nofollow">cross-coupling;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=electrochemistry&option=203" rel="nofollow">electrochemistry;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=nickel&option=203" rel="nofollow">nickel;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=reaction mechanisms&option=203" rel="nofollow">reaction mechanisms;</a> </p> <div class="translation"> 机译：arenes;交叉耦合;电化学;镍;反应机制; 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麻生明</a> <span> <a href="/conference-cn-33558/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 第十届金属有机化学讨论会 </a> <span> <span> . 1998</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/02031628547.html">镍催化（杂）芳基卤化物与单/二氟甲基卤代烃的还原偶联反应研究</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=尹涵&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 尹涵</a> <span> . 2019</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06120338294.html">氨基酸促进的CuI催化的芳基卤化物和烃基亚磺酸盐的偶联反应</a> <b>[P]</b> . <span> 中国专利： CN1332944C </span> <span> . 2007.08.22</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120104852097.html">氨基酸促进的CuI催化的芳基卤化物和烃基亚磺酸盐的偶联反应</a> <b>[P]</b> . <span> 中国专利： CN1651408A </span> <span> . 2005-08-10</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130431467202.html">METHOD FOR PRODUCING ORGANIC COMPOUND BY TRANSITION METAL-CATALYST CROSS-COUPLING REACTION OF ARYL-X, HETEROARYL-X, CYCLOALKENYL-X OR ALKENYL-X COMPOUND WITH ALKYL HALIDE, ALKENYL HALIDE, CYCLOALKYL HALIDE OR CYCLOALKENYL HALIDE</a> <b>[P]</b> . <span> 外国专利：  JP2009242399A </span> <span> . 2009-10-22</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：过渡金属催化剂与芳烃，卤代烃，环卤代烃或环卤代烃的芳烃-X，杂芳烃-X，环烯基-X或烯丙基-X化合物的过渡偶联制备有机化合物的方法 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130422732340.html">Process for the preparation of organic compounds by cross-coupling reaction catalyzed by a transition metal compound aryl-x, heteroaryl-x, cycloalkenyl-x, or alkenyl x, with an alkyl halide, alkenyl, cycloalkyl or cycloalkenyl.</a> <b>[P]</b> . <span> 外国专利：  ES2369961T3 </span> <span> . 2011-12-09</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：通过过渡金属化合物芳基-x，杂芳基-x，环烯基-x或烯基x与烷基卤化物，烯基，环烷基或环烯基的交叉偶联反应制备有机化合物的方法。 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130450880419.html">Method for preparing 3 - and 3 - alcanoilindoles alquilindoles through Friedel Crafts acylation type metal halide catalyzed by Lewis acid Type R '- (CI) 2 (R is alkyl orRILO) and subsequent Reduction with hidruroscomplejos Activating Through Lewis acid metal halide Type R '- (CI) 2.</a> <b>[P]</b> . <span> 外国专利：  CL1999002952A1 </span> <span> . 2000-09-28</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> 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