Self‐Assembly of Coordination Polyhedra with Highly Entangled Faces Induced by Metal–Acetylene Interactions

Domoto Yuya; Abe Masahiro; Kikuchi Takashi; Fujita Makoto

摘要

Abstract > The self‐assembly of nanostructures is dominated by a limited number of strong coordination elements. Herein, we show that metal–acetylene π‐coordination of a tripodal ligand (L) with acetylene spacers gave an M <sub>3</sub> L <sub>2</sub> double‐propeller motif (M=Cu I or Ag I ), which dimerized into an M <sub>6</sub> L <sub>4</sub> interlocked cage (M=Cu I ). Higher (M <sub>3</sub> L <sub>2</sub> ) <sub> n </sub> oligomers were also selectively obtained: an M <sub>12</sub> L <sub>8</sub> truncated tetrahedron (M=Cu I ) and an M <sub>18</sub> L <sub>12</sub> truncated trigonal prism (M=Ag I ), both of which contain the same double‐propeller motif. The higher oligomers exhibit multiply entangled facial structures that are classified as a trefoil knot and a Solomon link. The inner cavities of the structures encapsulate counteranions, revealing a potential new strategy towards the synthesis of functional hollow structures that is powered by molecular entanglements. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 纳米结构的自组装由有限数量的强配位元件主导。在此，我们表明金属 - 乙炔π-配有乙炔间隔物的三码型配体（L）的配位给了M <sub> 3 </ sub> L. <sub> 2 </ sub> 双螺旋桨图案（M = Cu i </ sup> 或者 i </ sup> ），它将其二聚成m <sub> 6 </ sub> L. <sub> 4 </ sub> 互锁笼（M = Cu i </ sup> ）。更高（M. <sub> 3 </ sub> L. <sub> 2 </ sub> 的） <sub> n </ i> </ sub> 也选择性地获得低聚物：一个m <sub> 12 </ sub> L. <sub> 8 </ sub> 截短的四面体（m = Cu i </ sup> ）和一个m <sub> 18 </ sub> L. <sub> 12 </ sub> 截短的三角形棱镜（m = ag i </ sup> ），两者都包含相同的双螺旋桨图案。较高的低聚物表现出乘法缠绕的面部结构，其被分类为三叶刀和所罗门环节。结构的内腔封装了对抗，揭示了通过分子缠结供电的功能中空结构的潜在的新策略。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-19011/'>《Angewandte Chemie》</a> <b style="margin: 0 2px;">|</b><span>2020年第9期</span><b style="margin: 0 2px;">|</b><span>共5页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Domoto Yuya&option=202" target="_blank" rel="nofollow">Domoto Yuya;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Abe Masahiro&option=202" target="_blank" rel="nofollow">Abe Masahiro;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Kikuchi Takashi&option=202" target="_blank" rel="nofollow">Kikuchi Takashi;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Fujita Makoto&option=202" target="_blank" rel="nofollow">Fujita Makoto;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Department of Applied ChemistryThe University of Tokyo7-3-1 Hongo Bunkyo-ku Tokyo 113-8656 Japan;</p> <p>Department of Applied ChemistryThe University of Tokyo7-3-1 Hongo Bunkyo-ku Tokyo 113-8656 Japan;</p> <p>Rigaku Corporation3-9-12 Matsubaracho Akishima Tokyo 196-8666 Japan;</p> <p>Department of Applied ChemistryThe University of Tokyo7-3-1 Hongo Bunkyo-ku Tokyo 113-8656 Japan;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1188.html" title="应用化学">应用化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=alkyne ligands&option=203" rel="nofollow">alkyne ligands;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=cage compounds&option=203" rel="nofollow">cage compounds;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=self-assembly&option=203" rel="nofollow">self-assembly;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=structure elucidation&option=203" rel="nofollow">structure elucidation;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=tripodal ligands&option=203" rel="nofollow">tripodal ligands;</a> </p> <div class="translation"> 机译：炔烃配体;笼子化合物;自组装;结构阐明;三架子配体; 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