Unveiling Latent Photoreactivity of Imines

Uraguchi Daisuke; Tsuchiya Yuto; Ohtani Tsuyoshi; Enomoto Takafumi; Masaoka Shigeyuki; Yokogawa Daisuke; Ooi Takashi

摘要

Abstract >Unlike carbonyl compounds, it has long been common understanding that excited imines show virtually no photoreactivity, and hence their properties and potential utility in chemical science remain largely unexplored. Now, a strategy is presented for eliciting latent photoreactivity of imines based on the introduction of a donor–acceptor (D‐A) structure to extend the lifetime of their photoexcited states. A series of spectroscopic analyses and density functional theory calculations reveal unique photophysical properties of the D‐A‐type imines. Furthermore, the reactivity of the D‐A‐type imines is demonstrated by using them as a photoredox catalyst for atom‐transfer radical addition. These findings illuminate a previously neglected chemical space in the field of photochemistry, which will be exploited by taking advantage of the inherent structural modularity of imines. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> >与羰基化合物不同，它一直很想普遍理解，激发亚胺显示实际上没有光度反应性，因此它们的化学科学的性质和潜在效用仍然很大程度上是未开发的。现在，提出了一种基于引入供体 - 受体（D-A）结构来引入亚胺的潜在光反应性的策略，以延长其光透明的状态的寿命。一系列光谱分析和密度官能理论计算揭示了D-A型亚胺的独特光学性质。此外，通过使用它们作为原子转移自由基加成的光致毒剂催化剂来证明D-A型亚胺的反应性。这些发现在光化学领域中照亮了先前被忽略的化学空间，这将通过利用亚胺的固有结构模块来利用。</ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-19011/'>《Angewandte Chemie》</a> <b style="margin: 0 2px;">|</b><span>2020年第9期</span><b style="margin: 0 2px;">|</b><span>共6页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Uraguchi Daisuke&option=202" target="_blank" rel="nofollow">Uraguchi Daisuke;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Tsuchiya Yuto&option=202" target="_blank" rel="nofollow">Tsuchiya Yuto;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ohtani Tsuyoshi&option=202" target="_blank" rel="nofollow">Ohtani Tsuyoshi;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Enomoto Takafumi&option=202" target="_blank" rel="nofollow">Enomoto Takafumi;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Masaoka Shigeyuki&option=202" target="_blank" rel="nofollow">Masaoka Shigeyuki;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yokogawa Daisuke&option=202" target="_blank" rel="nofollow">Yokogawa Daisuke;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ooi Takashi&option=202" target="_blank" rel="nofollow">Ooi Takashi;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Department of Molecular and Macromolecular ChemistryNagoya UniversityNagoya 464-8603 Japan;</p> <p>Department of Molecular and Macromolecular ChemistryNagoya UniversityNagoya 464-8603 Japan;</p> <p>Department of Molecular and Macromolecular ChemistryNagoya UniversityNagoya 464-8603 Japan;</p> <p>Department of Life and Coordination-Complex Molecular ScienceInstitute for Molecular Science (IMS)5-1 Higashiyama Myodaiji Okazaki Aichi 444-8787 Japan;</p> <p>Department of Life and Coordination-Complex Molecular ScienceInstitute for Molecular Science (IMS)5-1 Higashiyama Myodaiji Okazaki Aichi 444-8787 Japan;</p> <p>Institute of Transformative Bio-Molecules (WPI-ITbM)Nagoya UniversityNagoya 464-8601 Japan;</p> <p>Department of Molecular and Macromolecular ChemistryNagoya UniversityNagoya 464-8603 Japan;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1188.html" title="应用化学">应用化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=conical intersections&option=203" rel="nofollow">conical intersections;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=imines&option=203" rel="nofollow">imines;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=photocatalysis&option=203" rel="nofollow">photocatalysis;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=photochemistry&option=203" rel="nofollow">photochemistry;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=radical reactions&option=203" rel="nofollow">radical reactions;</a> </p> <div class="translation"> 机译：锥形交叉;亚胺;光催化;光化学;激进的反应; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704028160793.html">Unveiling Latent Photoreactivity of Imines</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Uraguchi Daisuke&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Uraguchi Daisuke,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Tsuchiya Yuto&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Tsuchiya Yuto,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ohtani Tsuyoshi&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Ohtani Tsuyoshi,</a> <a href="/journal-foreign-19011/" target="_blank" rel="nofollow" class="tuijian_authcolor">Angewandte Chemie .</a> <span>2020</span><span>,第9期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：揭示亚胺的潜在光反应性</span> </p> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704028161652.html">Unveiling the Local Structure of Palladium Loaded into Imine-Linked Layered Covalent Organic Frameworks for Cross-Coupling Catalysis</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Romero-Muniz Ignacio&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Romero-Muniz Ignacio,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Mavrandonakis Andreas&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Mavrandonakis Andreas,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Albacete Pablo&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Albacete Pablo,</a> <a href="/journal-foreign-19011/" target="_blank" rel="nofollow" class="tuijian_authcolor">Angewandte Chemie .</a> <span>2020</span><span>,第31期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：揭示钯的局部结构，载入亚胺连接的层状共价有机骨架中，用于交叉偶联催化</span> </p> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704020542215.html">Unveiling the effects of the in situ generated arene anion radical and imine radical on catecholase like activity: a DFT supported experimental investigation</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Dasgupta Sanchari&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Dasgupta Sanchari,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Adhikary Jaydeep&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Adhikary Jaydeep,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Giri Sanjib&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Giri Sanjib,</a> <a href="/journal-foreign-32850/" target="_blank" rel="nofollow" class="tuijian_authcolor">Dalton transactions: An international journal of inorganic chemistry .</a> <span>2017</span><span>,第18期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：揭示原位生成的芳香阴离子自由基和亚胺自由基对等活性的影响：DFT支持的实验研究</span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-conference-foreign_meeting-206232_thesis/020514170699.html">Unveiling Topics from Scientific Literature on the Subject of Self-driving Cars using Latent Dirichlet Allocation</a> <b>[C]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Workneh Y. Ayele&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Workneh Y. Ayele,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Gustaf Juell-Skielse&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Gustaf Juell-Skielse </a> <a href="/conference-foreign-206232/" target="_blank" rel="nofollow" class="tuijian_authcolor">IEEE Annual Information Technology, Electronics and Mobile Communication Conference .</a> <span>2018</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：使用潜在狄利克雷分配从科学文献中揭示关于自动驾驶汽车的主题</span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-degree-foreign_mphd_thesis/02061853579.html">N-Terminal Imine Derivatization for Enhanced de novo Peptide Sequencing: A Study of the Fragmentation Pattern Generated from CID of Peptide-Imines</a> <b>[D] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Patterson, Khiry L.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Patterson, Khiry L. </a> <span>2020</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：N-末端亚胺衍生化，用于增强DE Novo肽测序：从肽 - 亚胺CID产生的碎片模式研究</span> </p> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-journal-foreign-pmc_detail_thesis/040002390894.html">In situ generation of N-unsubstituted imines from alkyl azides and their applications for imine transfer via copper catalysis</a> <b>[O] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Lu Hu&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Lu Hu,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yahu A. Liu&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Yahu A. Liu,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Xuebin Liao&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Xuebin Liao </a> <span>2017</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：由烷基叠氮化物原位生成N-未取代的亚胺及其在铜催化下亚胺转移的应用</span> </p> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/open-access_resources_thesis/0100026697448.html">Unveiling Covariate Inclusion Structures In Economic Growth Regressions Using Latent Class Analysis</a> <b>[O] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Crespo Cuaresma Jesus&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Crespo Cuaresma Jesus,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Grün Bettina&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Grün Bettina,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Hofmarcher Paul&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Hofmarcher Paul,</a> <span>2016</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：使用潜在类分析揭示经济增长回归中的协变量包含结构</span> </p> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/academic-journal-cn_shanghai-plastics_thesis/0201248077089.html">反应性阻燃剂N-(2,4,6-三溴苯基)马来酰亚胺改性聚甲基丙烯酰亚胺(PMI)泡沫的制备与性能研究</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=杨洋&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 杨洋</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=袁协尧&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,袁协尧</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=刘卫平&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,刘卫平</a> <span> <a href="/journal-cn-9191/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 上海塑料 </a> </span> <span> . 2015</span><span>,第001期</span> </span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/academic-journal-cn_detail_thesis/0201296297381.html">基于光声技术研究硝酸钾/石墨的反应性光声谱</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王惠娥&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 王惠娥</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=沈瑞琪&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,沈瑞琪</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=叶迎华&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,叶迎华</a> <span> <a href="/journal-cn-56985/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 激光杂志 </a> </span> <span> . 2012</span><span>,第6期</span> </span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/academic-journal-cn_chinese-journal-inorganic-chemistry_thesis/0201250688523.html">2-苯亚胺官能化吲哚基铕胺基配合物与芳基取代甲脒的反应性</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=冯志君&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 冯志君</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=崔巧玉&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,崔巧玉</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=韦芸&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,韦芸</a> <span> <a href="/journal-cn-15070/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 无机化学学报 </a> </span> <span> . 2017</span><span>,第001期</span> </span> </div> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-journal-cn_materials-reports_thesis/0201211351606.html">反应性钌(Ⅱ)-二亚胺类荧光指示剂的研究进展</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=胡小英&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 胡小英</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李建雄&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,李建雄</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=刘安华&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,刘安华</a> <span> <a href="/journal-cn-7645/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 材料导报 </a> </span> <span> . 2016</span><span>,第001期</span> </span> </div> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-journal-cn_chinese-journal-inorganic-chemistry_thesis/0201250703146.html">基于β-二亚胺配体的铝氧硼六元环化合物和其中间体的合成、表征及其反应性研究</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=郝朋飞&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 郝朋飞</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=杨俊娟&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,杨俊娟</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=杨智&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,杨智</a> <span> <a href="/journal-cn-15070/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 无机化学学报 </a> </span> <span> . 2014</span><span>,第012期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-11607_thesis/02022421746.html">反应性阻燃剂N-(2,4,6-三溴苯基)马来酰亚胺改性聚甲基丙烯酰亚胺（PMI）泡沫的制备与性能研究</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=杨洋&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 杨洋</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=刘卫平&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,刘卫平</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=陈小强&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,陈小强</a> <span> <a href="/conference-cn-11607/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 2011年商用飞机复合材料应用国际论坛 </a> <span> <span> . 2011</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020316045204.html">ɑ-二亚胺配体稳定的低价铝、镓化合物与碳二亚胺类小分子的反应性研究</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=肖林&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 肖林</a> <span> . 2020</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06120113899722.html">基于潜在反应性组合物的可压缩的压敏的结构性粘合膜</a> <b>[P]</b> . <span> 中国专利： CN113993959A </span> <span> . 2022-01-28</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120113108377.html">基于聚氨酯的潜在反应性的胶膜</a> <b>[P]</b> . <span> 中国专利： CN113166602A </span> <span> . 2021-07-23</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130443351000.html">PHOTOREACTIVE COMPOSITION, PHOTO-POSTCURING COMPOSITION, PHOTOREACTIVE ADHESIVE AND PHOTOREACTIVE SEALING AGENT</a> <b>[P]</b> . <span> 外国专利：  JP2004269678A </span> <span> . 2004-09-30</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：光活性成分，光后组成，光粘合剂和光密封剂 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130500361789.html">Composition, preparation method, and use of crosslinked polymer containing pendant binding and exchangeable cross-linking by aldehyde imine and / or imine imine exchange reaction</a> <b>[P]</b> . <span> 外国专利：  JP6908956B2 </span> <span> . 2021-07-28</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：组合物，制备方法和使用含有侧链结合和通过醛亚胺和/或亚胺亚胺交换反应的可交换交联的交联聚合物的使用 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130500855738.html">Compositions, preparation methods, and uses that include a crosslinked polymer network containing pendant bonds and crosslinks that can be exchanged by an aldehyde-imine and / or imine-imine exchange reaction.</a> <b>[P]</b> . <span> 外国专利：  JP6952398B2 </span> <span> . 2021-10-20</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：包含包含垂侧粘合剂和交联的交联聚合物网络的组合物，制备方法和用途，其可以通过醛 - 亚胺和/或亚胺 - 亚胺交换反应交换。 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" onclick="ywcd('0704028160793','4',7,2,1,'',this,24)" class="delivery" prompt="010401" title="通过人工服务将文献原文发送至邮箱" >获取原文</div> <div class="journalsub-pop-up" style="display: none"> <div class="journal-sub"> <h2>期刊订阅</h2> <img src="https://cdn.zhangqiaokeyan.com/img/loginclose.png" alt="关闭" onclick="$('.journalsub-pop-up').hide()"> <p class="pardon">抱歉，该期刊暂不可订阅，敬请期待！</p> <p class="current">目前支持订阅全部北京大学中文核心（2020）期刊目录。</p> <div style="display: flex;margin-top: 69px;justify-content: space-between;"> <div class="no-sub" onclick="$('.journalsub-pop-up').hide()">暂不订阅</div> <div class="other-sub" onclick="continueSub('from=pc-detail')">继续订阅其他期刊</div> </div> </div> </div> <div class="right_btn"> <ul> <li class="gouwuche">  </li> <li class="yijian"> <a href="javascript:void(0);" onclick="link_analysis('/mycenter/auth/complaint.html',this)" title="意见反馈">意见反馈</a> </li> <li class="top"> <a href="javascript:scrollTo(0,0);" title="回到顶部">回到顶部</a> </li> <li class="shouye"> <a href="/" title="首页">回到首页</a> </li> </ul> </div> <div class="xllindexfooter"> <div class="xllindexfootercenter"> <div class="xllindexfooterleft left" > <div class="xllindexfooterleftli"> <ul> <li><a href="/about.html" title="关于掌桥">关于掌桥</a></li> <li><a href="/help/helpmap.html" title="资源导航">资源导航</a></li> <li><a href="/help/helpguide.html" title="新手指南">新手指南</a></li> <li><a href="/help/helpcenter.html" title="常见问题">常见问题</a></li> <li><a href="/sitemap.html" title="网站地图">网站地图</a></li> <li><a href="/help/helpcenter.html?type=9" title="版权声明">版权声明</a></li> </ul> </div> <div class="xllindexfooterleft"> <p class="xllindexfooterlefteamil">客服邮箱：kefu@zhangqiaokeyan.com</p> <div class="xllindexfooterlefttcp"> <div class="xllindexfooterpoliceiimg"></div> <div class="xllindexfooterpoliceispan"> <span>京公网安备：11010802029741号 </span> <span>ICP备案号：<a href="https://beian.miit.gov.cn" rel="nofollow" target="_blank" title="ICP备案号">京ICP备15016152号-6</a></span> <span>六维联合信息科技 (北京) 有限公司©版权所有</span> </div> </div> </div> </div> <div class="xllindexfooterright left"> <ul> <li> <p style="font-weight: bold;">客服微信</p> <div></div> </li> <li> <p style="font-weight: bold;">服务号</p> <div></div> </li> </ul> </div> </div> </div> <span id="0704028160793down" data-source="7," data-out-id="TDmTtrpEg2U1Gv4gKuSLWSpcgTZqtpXhxGnTgx9LjW3ifMgoOsLHsnYV/rF8Ee0M," data-f-source-id="7" data-title="Unveiling Latent Photoreactivity of Imines" data-price="20" data-site-name="" data-transnum="24" style="display:none;"></span> <input type="hidden" value="4" id="sourcetype"> <input type="hidden" value="19011" id="journalid"> <input type="hidden" value="1" id="inyn_provide_service_level"> <input type="hidden" value="https://cdn.zhangqiaokeyan.com" id="imgcdn"> <input type="hidden" value="1" id="isdeatail"> <input type="hidden" value="" id="syyn_indexed_database"> <input type="hidden" value="" id="servicetype"> <input type="hidden" id="pagename" value="Unveiling Latent Photoreactivity of Imines"/> <input type="hidden" value="thesis_get_original" id="pageIdentification"> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/jquery-1.12.4.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/lwlh_ajax.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/zq.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/common.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/jquery.cookie.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/top.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/tip.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/login.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/down.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/search.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/newmail.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/searchtype.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/user/regist.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/zxs_solor/detail.js?v=5.7.8"></script> <script type="text/javascript" src="https://www.zhangqiaokeyan.com/statistics/static/pagecollection.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/tj.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/sse.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/pushbaidu.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/history.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/util/cookie.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/weipu/weipu.js?v=5.7.8"></script> </body> <script> $(function(){ var weiPuStatus = getCookie('WeiPuStatus'); if(weiPuStatus){ tipWeiPuStatus(weiPuStatus); delCookie('WeiPuStatus'); } getFacetKeywordVoInId(); var sourcetype = $("#sourcetype").val(); var inyn_provide_service_level = $("#inyn_provide_service_level").val(); if((sourcetype ==1||sourcetype==4)&&inyn_provide_service_level!=4){ getJournal(); } }) </script> </html>