Structural Diversification of Pillar[n]arene Macrocycles

Xu Xiaowen; Jerca Valentin Victor; Hoogenboom Richard

摘要

Abstract > Despite the fact that pillar[ n ]arenes receive major interest as building blocks for supramolecular chemistry and advanced materials, their functionalization is generally limited to the modification of the hydroxy or alkoxy units present on the rims. This limited structural freedom restricts further developments and has very recently been overcome. In this article, we highlight three very recent studies demonstrating further structural diversification of pillar[ n ]arenes by partial removal of the alkoxy substituents on the rims, which can be considered as the next generation of pillar[ n ]arenes. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 尽管柱子[ n </ i> ]竞技获得主要兴趣作为超分子化学和先进材料的构建块，它们的官能化通常限于在轮辋上存在的羟基或烷氧基单元的改性。这种有限的结构自由度限制了进一步的发展，最近被克服了。在本文中，我们突出了三项最近的研究，证明了柱子的进一步结构多样化[ n </ i> ]通过部分除去轮廓上的烷氧基取代基，这可以被认为是下一代支柱[ n </ i> ]逃亡。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-19011/'>《Angewandte Chemie》</a> <b style="margin: 0 2px;">|</b><span>2020年第16期</span><b style="margin: 0 2px;">|</b><span>共3页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Xu Xiaowen&option=202" target="_blank" rel="nofollow">Xu Xiaowen;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Jerca Valentin Victor&option=202" target="_blank" rel="nofollow">Jerca Valentin Victor;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Hoogenboom Richard&option=202" target="_blank" rel="nofollow">Hoogenboom Richard;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Supramolecular Chemistry Group Centre of Macromolecular Chemistry (CMaC)Ghent UniversityKrijgslaan 281-S4 9000 Ghent Belgium;</p> <p>Supramolecular Chemistry Group Centre of Macromolecular Chemistry (CMaC)Ghent UniversityKrijgslaan 281-S4 9000 Ghent Belgium;</p> <p>Supramolecular Chemistry Group Centre of Macromolecular Chemistry (CMaC)Ghent UniversityKrijgslaan 281-S4 9000 Ghent Belgium;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1188.html" title="应用化学">应用化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=pillarnarene&option=203" rel="nofollow">pillarnarene;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=sensors&option=203" rel="nofollow">sensors;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=separation of isomers&option=203" rel="nofollow">separation of isomers;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=structural diversification&option=203" rel="nofollow">structural diversification;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=supramolecular chemistry&option=203" rel="nofollow">supramolecular chemistry;</a> </p> <div class="translation"> 机译：柱[n] arene;传感器;分离异构体;结构多样化;超分子化学; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> 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