Surface Reorganization on Electrochemically‐Induced Zn–Ni–Co Spinel Oxides for Enhanced Oxygen Electrocatalysis

Wang Xiao‐Tong; Ouyang Ting; Wang Ling; Zhong Jia‐Huan; Liu Zhao‐Qing

摘要

Abstract > Herein, we highlight redox‐inert Zn 2+ in spinel‐type oxide (Zn <sub> X </sub> Ni <sub> 1? X </sub> Co <sub>2</sub> O <sub>4</sub> ) to synergistically optimize physical pore structure and increase the formation of active species on the catalyst surface. The presence of Zn 2+ segregation has been identified experimentally and theoretically under oxygen‐evolving condition, the newly formed V <sub>Zn</sub> ?O?Co allows more suitable binding interaction between the active center Co and the oxygenated species, resulting in superior ORR performance. Moreover, a liquid flow Zn–air battery is constituted employing the structurally optimized Zn <sub>0.4</sub> Ni <sub>0.6</sub> Co <sub>2</sub> O <sub>4</sub> nanoparticles supported on N‐doped carbon nanotube (ZNCO/NCNTs) as an efficient air cathode, which presents remarkable power density (109.1?mW?cm ?2 ), high open circuit potential (1.48?V vs. Zn), excellent durability, and high‐rate performance. This finding could elucidate the experimentally observed enhancement in the ORR activity of Zn <sub> X </sub> Ni <sub> 1? X </sub> Co <sub>2</sub> O <sub>4</sub> oxides after the OER test. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 在此，我们突出了氧化还原惰性Zn 2 + </ sup> 在尖晶石型氧化物（Zn <sub> x </ i> </ sub> 你 <sub> 1？ x </ i> </ sub> CO. <sub> 2 </ sub> O. <sub> 4 </ sub> ）为了协同优化物理孔结构并增加催化剂表面上的活性物质的形成。 Zn的存在 2 + </ sup> 在新形成的V. <sub> zn </ sub> ？O？Co允许活性中心CO和含氧物种之间更合适的结合相互作用，从而产生优异的ORR性能。此外，液体流动Zn空气电池由结构优化的Zn构成 <sub> 0.4 </ sub> 你 <sub> 0.6 </ sub> CO. <sub> 2 </ sub> O. <sub> 4 </ sub> 纳米颗粒作为高效的空气阴极支撑在N掺杂的碳纳米管（ZnCo / NCNT）上，这呈现出显着的功率密度（109.1≤mw≤cm ？2 </ sup> ），高开关电位（1.48〜Zn），优异的耐用性和高速率性能。这一发现可以阐明在Zn的ORR活性的实验观察到的增强 <sub> x </ i> </ sub> 你 <sub> 1？ x </ i> </ sub> CO. <sub> 2 </ sub> O. <sub> 4 </ sub> oer测试后的氧化物。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-19011/'>《Angewandte Chemie》</a> <b style="margin: 0 2px;">|</b><span>2020年第16期</span><b style="margin: 0 2px;">|</b><span>共8页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wang Xiao‐Tong&option=202" target="_blank" rel="nofollow">Wang Xiao‐Tong;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ouyang Ting&option=202" target="_blank" rel="nofollow">Ouyang Ting;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wang Ling&option=202" target="_blank" rel="nofollow">Wang Ling;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhong Jia‐Huan&option=202" target="_blank" rel="nofollow">Zhong Jia‐Huan;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Liu Zhao‐Qing&option=202" target="_blank" rel="nofollow">Liu Zhao‐Qing;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>School of Chemistry and Chemical Engineering/Guangzhou Key Laboratory for Clean Energy and Materials/Key Laboratory for Water Quality and Conservation of the Pearl River DeltaMinistry of EducationNo. 230 Wai Huan Xi Road Guangzhou 510006 P. R. China;</p> <p>School of Chemistry and Chemical Engineering/Guangzhou Key Laboratory for Clean Energy and Materials/Key Laboratory for Water Quality and Conservation of the Pearl River DeltaMinistry of EducationNo. 230 Wai Huan Xi Road Guangzhou 510006 P. R. China;</p> <p>School of Chemistry and Chemical Engineering/Guangzhou Key Laboratory for Clean Energy and Materials/Key Laboratory for Water Quality and Conservation of the Pearl River DeltaMinistry of EducationNo. 230 Wai Huan Xi Road Guangzhou 510006 P. R. China;</p> <p>School of Chemistry and Chemical Engineering/Guangzhou Key Laboratory for Clean Energy and Materials/Key Laboratory for Water Quality and Conservation of the Pearl River DeltaMinistry of EducationNo. 230 Wai Huan Xi Road Guangzhou 510006 P. R. China;</p> <p>School of Chemistry and Chemical Engineering/Guangzhou Key Laboratory for Clean Energy and Materials/Key Laboratory for Water Quality and Conservation of the Pearl River DeltaMinistry of EducationNo. 230 Wai Huan Xi Road Guangzhou 510006 P. R. China;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1188.html" title="应用化学">应用化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=defect chemistry&option=203" rel="nofollow">defect chemistry;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=oxygen evolution reaction&option=203" rel="nofollow">oxygen evolution reaction;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=oxygen reduction reaction&option=203" rel="nofollow">oxygen reduction reaction;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=zinc-air batteries&option=203" rel="nofollow">zinc-air batteries;</a> </p> <div class="translation"> 机译：缺陷化学;氧气进化反应;氧气还原反应;锌 - 空气电池; 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tuijian_authcolor">,冯婧</a> <span> <a href="/journal-cn-4566/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 石河子大学学报（自然科学版） </a> </span> <span> . 2021</span><span>,第001期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-22341_thesis/02022600614.html">辣根过氧化物酶在水溶性的Gemini阳离子表面活性剂-离子液体新型复合膜中的直接电化学和电催化研究</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李江文&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 李江文</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=刘丽红&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,刘丽红</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=肖菲&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,肖菲</a> <span> <a href="/conference-cn-22341/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 第十四次全国电化学会议 </a> <span> <span> . 2007</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020316291411.html">尖晶石结构氧化物的表面元素价态调控及电催化性能研究</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=朋彩玲&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 朋彩玲</a> <span> . 2021</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06120107294049.html">用于制备基于镁氧或镁氧尖晶石的耐火材料的方法和基于镁氧或镁氧尖晶石的耐火材料</a> <b>[P]</b> . <span> 中国专利： CN104797541A </span> <span> . 2015-07-22</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120111381805.html">一种具有氧缺陷的反尖晶石型钴铁氧体纳米粉体制备及电催化应用</a> <b>[P]</b> . <span> 中国专利： CN108906056A </span> <span> . 2018-11-30</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130439365687.html">METHOD CAPABLE OF IMPARTING STRONG CORROSION RESISTANCE TO SURFACE OF Mg BY FORMING PLATING LAYER OF Zn-ELECTROLYTIC Cu-ELECTROLYTIC Ni OR Zn-ELECTROLESS Ni-ELECTROLYTIC Ni ON SURFACE OF Mg ALLOY HAVING WEAK CORROSION RESISTANCE</a> <b>[P]</b> . <span> 外国专利：  KR20050014186A </span> <span> . 2005-02-07</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：通过在镁合金表面上形成具有弱耐蚀性的锌电解铜电沉积镍或锌电解镍电沉积镍的镀层，可以使镁的强腐蚀性能增强的方法 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130439363705.html">Ni-Zn FERRITE BASED LEAD-FREE FLUX FOR LOWERING SINTERING TEMPERATURE COMPRISING SILICON DIOXIDE, BORON OXIDE, ADDITIVES AND Ni-Zn FERRITE BASED RAW MATERIAL POWDER</a> <b>[P]</b> . <span> 外国专利：  KR20050016218A </span> <span> . 2005-02-21</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：用于降低烧结温度的Ni-Zn铁氧体基无铅焊剂，包括二氧化硅，氧化硼，添加剂和Ni-Zn铁氧体基原料粉末 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130409621368.html">Genetically enhanced cyanobacteria for the production of a first chemical compound harbouring Zn<Sup>2+</Sup>, Co<Sup>2+</Sup> or Ni<Sup>2+</Sup> -inducible promoters</a> <b>[P]</b> . <span> 外国专利：  US9551014B2 </span> <span> . 2017-01-24</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：遗传增强型蓝细菌用于生产第一个包含Zn <Sup> 2 + </ Sup>，Co <Sup> 2 + </ Sup>或Ni <Sup> 2 + </ Sup>诱导型启动子的化合物 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" 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