1,2-Diphenylbenzene Dianion: Alkali-Metal Salts with Drastically Spread C_6 Rings

Hans Bock; Zdenek Havlas; Katayoun Gharagozloo-Hubmann; Sven Holl; Mark Sievert

首页> 外文期刊>Angewandte Chemie >1,2-Diphenylbenzene Dianion: Alkali-Metal Salts with Drastically Spread C_6 Rings

【24h】

1,2-Diphenylbenzene Dianion: Alkali-Metal Salts with Drastically Spread C_6 Rings

机译：1,2-二苯苯双阴离子：具有大范围C_6环的碱金属盐

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The reduction of π hydrocarbons and subsequent ion-pair formation by suitably solvated alkali-metal ions (M_(solv)~+) as described by Equation (1) provides access to the C_xH_y+ne~- → [C_xH_y]~(n-) [C_xH_y]~(n-) + nM_(solv)~+ → [(M_(solv)~+)_n(C_xH_y)~(n-)] (1) magic alkali-metal-organic world of considerably distorted structures.

机译：如式（1）所述，通过适当溶剂化的碱金属离子（M_（solv）〜+）还原π碳氢化合物并随后形成离子对，可访问C_xH_y + ne〜-→[C_xH_y]〜（n- ）[C_xH_y]〜（n-）+ nM_（solv）〜+→[（M_（solv）〜+）_ n（C_xH_y）〜（n-）]（1）具有明显扭曲结构的神奇碱金属有机世界。

著录项

来源
《Angewandte Chemie》 |2003年第36期|共5页
作者
Hans Bock; Zdenek Havlas; Katayoun Gharagozloo-Hubmann; Sven Holl; Mark Sievert;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类应用化学;
关键词
alkaline metals; carbanions; density functional calculations; hydrocarbons; reduction;

机译：碱金属;碳阴离子;密度泛函计算;碳氢化合物;还原;

相似文献

外文文献
中文文献
专利

1. 1,2-Diphenylbenzene Dianion: Alkali-Metal Salts with Drastically Spread C_6 Rings [J] . Hans Bock, Zdenek Havlas, Katayoun Gharagozloo-Hubmann, Angewandte Chemie . 2003,第36期

机译：1,2-二苯苯双阴离子：具有大范围C_6环的碱金属盐
2. Time-dependent density-functional-theory calculation of the van der Waals coefficient C_6 of alkali-metal atoms Li, Na,K;alkali-metal dimers Li_2, Nat, K_2; sodium clusters Na_n; and fullerene C_(60) [J] . Arup Banerjee, Jochen Autschbach, Aparna Chakrabarti Physical Review, A. Atomic, molecular, and optical physics . 2008,第3aPta1期

机译：碱金属原子Li，Na，K;碱金属二聚体Li_2，Nat，K_2;的范德华系数C_6的时变密度泛函理论计算钠簇Na_n;和富勒烯C_（60）
3. Controlled synthesis of labelled 3-L-chlorotyrosine-[ring-~(13)C_6] and of 3,5-L-dichlorotyrosine-[ring-~(13)C_6] [J] . Pietro Allevi, Paola Olivero, Mario Anastasia Journal of Labelled Compounds and Radiopharmaceuticals . 2004,第13期

机译：标记的3-L-氯酪氨酸-[ring-〜（13）C_6]和3,5-L-二氯酪氨酸-[ring-〜（13）C_6]的受控合成
4. Cyclobutadiene Dianion and Tetrasilabicyclo1.1.0butane Dianion Alkaline Earth Metal Salts: Synthesis and Structure [C] . Kazunori Takanashi, Akira Inatomi, Vladimir Ya. Lee Symposium on Organometallic Chemistry . 2007

机译：环条丁二烯Dianion和Tetrasileabicyclo 1.1.0丁烷脱杉碱土金属盐：合成和结构
5. Cyclic Peroxide Methodologies: I. Synthesis of 10,12-Peroxycalamenene Using an SN1-type Reaction to Construct the 1,2-Dioxepane Ring. II. Cobalt-Catalyzed C-Br Bond Activation to Form 1,2-Dioxolanes [D] . Witthoft, Luke. 2018

机译：环状过氧化物方法：I.使用SN1型反应合成10,12-过氧哒甘油，以构建1,2-二氧己烯环。 II。钴催化的C-Br键活化以形成1,2-二氧戊烷
6. Recessive Resistance Derived from Tomato cv. Tyking-Limits Drastically the Spread of Tomato Yellow Leaf Curl Virus [O] . Rita C. Pereira-Carvalho, Juan A. Díaz-Pendón, Maria Esther N. Fonseca, 2015

机译：来自番茄的隐性抗性。限价措施极大地限制了番茄黄叶卷毛病毒的传播
7. Salt of Ring‐Reduced Iron(II) Octaethyltetrapyrazinoporphyrazine Containing Trimetallic Dianions with Peripherally Coordinated ZnCl 2 Units: {Fe II (TPyzPzEt 8 ) 4– (ZnCl 2 ) 2 } 2– [O] . Maxim A. Faraonov, Nikita R. Romanenko, Alexey V. Kuzmin, 2019

机译：环还原铁（II）含辛甲基四嘧嗪二吡咯吡咯哒嗪，含有外周协调的ZnCl 2单位：{Fe II（Tpyzpzet 8）4-（ZnCl 2）2} 2-
8. The Preparation of A 1,2-Disilacyclobutane and A 1,2-Disilacyclobut-3-ene by Dimethyl-Silylene Insertion into the Silacyclopropane and Slacyclopropene Ring Systems. New Silacyclopropenes. [R] . Seyferth, D., Vick, S. C. 1976

机译：二甲基硅烯基插入silacyclopropane和slacyclopropene环系统制备1,2-二硅杂环丁烷和1,2-二硅杂环丁-3-烯。新的silacyclopropenes。

1,2-Diphenylbenzene Dianion: Alkali-Metal Salts with Drastically Spread C_6 Rings

摘要

著录项

相似文献

相关主题

期刊订阅