Modeling the Remote-Controlled Organization of Particles in a Nanodimensional Cavity: Synthesis and Properties of (Et_3NH)_3(tBuNH_3)_(2~--) Na_2[(H)20)_2,N_3~- V_(14)0_(22)(OH)_4(PhP0_3)_8] - 6H_2O-2 DMF

摘要

One of the most important aspects for the future of chemical research is the examination of the experimental conditions under which it is possible to construct arrangements of higher complexity from simple building blocks, if possible, with tailor-made structural and functionality features. The aim of such experiments is not only to improve the understanding of the extreme complexity of natural processes, but also to synthesize molecular materials with desired properties. In this context, reactions in which the organization of weakly interacting species in an isolated system are influenced "from outside" are of interest, too. These problems are current topics in the field of supramolecular chemistry.