Heterochromia in Designed Metallopeptides:Geometry-Selective Binding of Cd~(II) in a De Novo Peptide

摘要

One of the most important chemical concepts is defining how one molecule recognizes and controls the properties of another molecule or ion.Nowhere is this issue more significant than in the field of biomolecular recognition.Metalloproteins efficiently control the geometry and coordination number of metal ions as well as the types of ligands bound to them.