Mineralogy, geochemistry, and Sr-Pb isotopic geochemistry of hydrothermal massive sulfides from the 15.2 degrees S hydrothermal field, Mid-Atlantic Ridge

摘要

The 15.2 degrees S hydrothermal field is located at 15.2 degrees S, 13.4 degrees W within the Mid-Atlantic Ridge (MAR) and was initially discovered during Cruise DY125-22 by the Chinese expedition during R/V Dayangyihao in 2011. Here, we provide detailed mineralogical, bulk geochemical, and Sr-Pb isotopic data for massive sulfides and basalts from the 15.2 degrees S hydrothermal field to improve our understanding of the mineral compositions, geochemical characteristics, type of hydrothermal field, and the source of metals present at this vent site. The samples include 14 massive sulfides and a single basalt. The massive sulfides are dominated by pyrite with minor amounts of sphalerite and chalcopyrite, although a few samples also contain minor amounts of gordaite, a sulfate mineral. The sulfides have bulk compositions that contain low concentrations of Cu + Zn (mean 7.84 wt%), Co (mean 183 ppm), Ni (mean 3 ppm), and Ba (mean 16 ppm), similar to the Normal Mid-Ocean Ridge Basalt (N-MORB) type deposits along the MAR but different to the compositions of the Enriched-MORB (E-MORB) and ultramafic type deposits along this spreading ridge. Sulfides from the study area have Pb isotopic compositions ((206)pb/(204)pb = 18.4502-18.4538, (207)pb/(204)pb = 15.4903-15.4936, (208)pb/(204)pb = 37.8936-37.9176) that are similar to those of the basalt sample ((206)pb/(204)pb = 18.3381, Pb-207/Pb-204 = 15.5041, Pb-208/Pb-204 = 37.9411), indicating that the metals within the sulfides were derived from leaching of the surrounding basaltic rocks. The sulfides also have Sr-87/Sr-86 ratios (0.708200-0.709049) that are much higher than typical MAR hydrothermal fluids (0.7028-0.7046), suggesting that the hydrothermal fluids mixed with a significant amount of seawater during massive sulfide precipitation. (C) 2017 Elsevier B.V. All rights reserved.