New Synthetic Route to CY5-Labeled 2'-Deoxycytidine-5'-Triphosphates Using Sonogashira Reaction

Guseinov T. O.; Kuznetsova V. E.; Shershov V. E.; Spitsyn M. A.; Lapa S. A.; Zasedatelev A. S.; Chudinov A. V.

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New Synthetic Route to CY5-Labeled 2'-Deoxycytidine-5'-Triphosphates Using Sonogashira Reaction

机译：使用Sonogashira反应的Cy5标记的2'-脱氧胞苷-5'-三磷酸的新的合成途径

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摘要

Herein, we present a new synthetic route to fluorescently-labeled nucleoside triphosphates via Sonogashira cross-coupling of iodinated deoxycytidine monophosphate and cyanine dye with a terminal alkyne group.

机译：在此，我们通过Sonoghashira交联偶联碘化脱氧胞苷单磷酸酯和氰基染料与炔烃基染料的交联偶联至荧光标记的核苷三磷酸新的合成途径。

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来源
《Russian journal of bioorganic chemistry》 |2018年第2期|共4页
作者
Guseinov T. O.; Kuznetsova V. E.; Shershov V. E.; Spitsyn M. A.; Lapa S. A.; Zasedatelev A. S.; Chudinov A. V.;
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作者单位

Russian Acad Sci Engelhardt Inst Mol Biol Moscow 119991 Russia;

Russian Acad Sci Engelhardt Inst Mol Biol Moscow 119991 Russia;

Russian Acad Sci Engelhardt Inst Mol Biol Moscow 119991 Russia;

Russian Acad Sci Engelhardt Inst Mol Biol Moscow 119991 Russia;

Russian Acad Sci Engelhardt Inst Mol Biol Moscow 119991 Russia;

Russian Acad Sci Engelhardt Inst Mol Biol Moscow 119991 Russia;

Russian Acad Sci Engelhardt Inst Mol Biol Moscow 119991 Russia;

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原文格式 PDF
正文语种 eng
中图分类生物化学;
关键词
alkynylated nucleoside monophosphates; fluorescently labeled nucleotides; indodicarbocyanine dyes; Sonogashira reaction;

机译：烷基化核苷一磷酸盐;荧光标记的核苷酸;吲哚辛碳菁染料;sonogashira反应;

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1. New Synthetic Route to CY5-Labeled 2'-Deoxycytidine-5'-Triphosphates Using Sonogashira Reaction [J] . Guseinov T. O., Kuznetsova V. E., Shershov V. E., Russian journal of bioorganic chemistry . 2018,第2期

机译：使用Sonogashira反应的Cy5标记的2'-脱氧胞苷-5'-三磷酸的新的合成途径
2. The Optimization of Direct Heteroarylation and Sonogashira Cross-Coupling Reactions as Efficient and Sustainable Synthetic Methods To Access π-Conjugated Materials with Near-Infrared Absorption [J] . Seth M. McAfee, Jonathan. R. Cann, Pierre Josse ACS Sustainable Chemistry & Engineering . 2016,第6期

机译：直接杂芳基化和Sonogashira交叉偶联反应的优化，作为一种有效且可持续的合成方法，以接近π吸收的材料吸收近红外
3. Post-synthetic modified MOF for Sonogashira cross-coupling and Knoevenagel condensation reactions [J] . Ezugwu Chizoba I., Mousavi Bibimaryam, Asraf Md. Ali, Journal of Catalysis . 2016,第Null期

机译：用于Sonogashira交叉偶联和Knoevenagel缩合反应的合成后修饰MOF
4. Aqueous Phase Sonogashira Cross-Coupling Reaction in Synthesis of Bile Acid Conjugates of Purine and Pyrimidine Nucleosides and Nucleoside Triphosphates; Towards Bile Acid -Functionalized Nucleic Acids [C] . Satu Ikonen, Radek Pohl, Michal Hocek European Symposium on Organic Chemistry . 2009

机译：水相Sonogashira交叉偶联反应在嘌呤和嘧啶核苷的合成中合成，嘧啶核苷和核苷三磷酸盐;朝向胆汁酸 - 官能化核酸
5. Investigation of Conjugate Addition Initiated Cyclization Reactions of Dienyl Diketones and Progress Toward a Scalable Synthetic Route to (-) -Rocaglamide. [D] . Jacob, Steven D. 2015

机译：二烯基二酮共轭加成引发的环化反应的研究以及向（-）-Rocaglamide的可扩展合成路线的进展。
6. Reactions of salicylaldehyde and enolates or their equivalents: versatile synthetic routes to chromane derivatives [O] . Ishmael B Masesane, Zelalem Yibralign Desta 2012

机译：水杨醛与烯醇盐或其等同物的反应：生成苯并二氢吡喃衍生物的通用合成路线
7. The Optimization of Direct Heteroarylation and Sonogashira Cross-Coupling Reactions as Efficient and Sustainable Synthetic Methods To Access π-Conjugated Materials with Near-Infrared Absorption [O] . S.M. McAfee, J.R. Cann, P. Josse, 2016

机译：优化直接杂芳基化和sonogashira交叉偶联反应作为高效可持续的合成方法，以近红外吸收方式获取π-共轭材料
8. New synthetic routes to cyclopentadienyluranium(IV) fluorides; redox and atom-abstraction reactions. [R] . Weydert, M., Andersen, R. A. 1993

机译：环戊二烯基芴（IV）氟化物的新合成路线;氧化还原和原子提取反应。

New Synthetic Route to CY5-Labeled 2'-Deoxycytidine-5'-Triphosphates Using Sonogashira Reaction

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