Signatures of fano interferences in the electron energy loss spectroscopy and cathodoluminescence of symmetry-broken nanorod dimers

摘要

Through numerical simulation, we predict the existence of the Fano interference effect in the electron energy loss spectroscopy (EELS) and cathodoluminescence (CL) of symmetry-broken nanorod dimers that are heterogeneous in material composition and asymmetric in length. The differing selection rules of the electron probe in comparison to the photon of a plane wave allow for the simultaneous excitation of both optically bright and dark plasmons of each monomer unit, suggesting that Fano resonances will not arise in EELS and CL. Yet, interferences are manifested in the dimer's scattered near- and far-fields and are evident in EELS and CL due to the rapid π-phase offset in the polarizations between super-radiant and subradiant hybridized plasmon modes of the dimer as a function of the energy loss suffered by the impinging electron. Depending upon the location of the electron beam, we demonstrate the conditions under which Fano interferences will be present in both optical and electron spectroscopies (EELS and CL) as well as a new class of Fano interferences that are uniquely electron-driven and are absent in the optical response. Among other things, the knowledge gained from this work bears impact upon the design of some of the world's most sensitive sensors, which are currently based upon Fano resonances.