Lipase-catalyzed synthesis of biobased and biodegradable aliphatic copolyesters from short building blocks. Effect of the monomer length

摘要

Graphical abstractDisplay OmittedHighlights?Lipase-catalyzed synthesis of PBSA and PPBS copolyesters under mild conditions.?Increase of CALB activity with 1,4-butanediol compared to 1,3-propanediol.?Similar CALB activity for diethyl succinate and diethyl adipate.?Crystalline structures and thermal properties highly dependent on the architecture.?Copolyesters with an isodimorphic co-crystallization behavior.AbstractBiobased short aliphatic diols and diethyl carboxylates were enzymatically (co)polymerized in s